In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks
Employing in situ-formed new organic ligands, two Pb(II)-based metal–organic frameworks were synthesized. Compound 1 possesses a 3D framework while compound 2 has a layered structure. Solid state UV-visible absorptions indicate that the two compounds are semiconductors with band gaps of 1.70 and 1.7...
| Main Authors: | , , , , , , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/95611 http://hdl.handle.net/10220/10822 |
| _version_ | 1826129584542711808 |
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| author | Liu, Yi Tan, Melvin Wei Jun Wei, Fengxia Tian, Yufeng Wu, Tom Huo, Fengwei Yan, Qingyu Hng, Huey Hoon Ma, Jan Zhang, Qichun Kloc, Christian |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Liu, Yi Tan, Melvin Wei Jun Wei, Fengxia Tian, Yufeng Wu, Tom Huo, Fengwei Yan, Qingyu Hng, Huey Hoon Ma, Jan Zhang, Qichun Kloc, Christian |
| author_sort | Liu, Yi |
| collection | NTU |
| description | Employing in situ-formed new organic ligands, two Pb(II)-based metal–organic frameworks were synthesized. Compound 1 possesses a 3D framework while compound 2 has a layered structure. Solid state UV-visible absorptions indicate that the two compounds are semiconductors with band gaps of 1.70 and 1.78 eV. Magnetic properties reveal that they are temperature-independent diamagnetic. |
| first_indexed | 2024-10-01T07:42:56Z |
| format | Journal Article |
| id | ntu-10356/95611 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T07:42:56Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/956112020-06-01T10:13:45Z In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks Liu, Yi Tan, Melvin Wei Jun Wei, Fengxia Tian, Yufeng Wu, Tom Huo, Fengwei Yan, Qingyu Hng, Huey Hoon Ma, Jan Zhang, Qichun Kloc, Christian School of Materials Science & Engineering School of Physical and Mathematical Sciences DRNTU::Engineering::Materials::Magnetic materials Employing in situ-formed new organic ligands, two Pb(II)-based metal–organic frameworks were synthesized. Compound 1 possesses a 3D framework while compound 2 has a layered structure. Solid state UV-visible absorptions indicate that the two compounds are semiconductors with band gaps of 1.70 and 1.78 eV. Magnetic properties reveal that they are temperature-independent diamagnetic. 2013-06-28T03:14:02Z 2019-12-06T19:18:14Z 2013-06-28T03:14:02Z 2019-12-06T19:18:14Z 2012 2012 Journal Article Liu, Y., Tan, M. J. W., Wei, F., Tian, Y., Wu, T., Kloc, C., et al. (2011). In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks. CrystEngComm, 14(1), 75-78. 1466-8033 https://hdl.handle.net/10356/95611 http://hdl.handle.net/10220/10822 10.1039/c1ce06006f en CrystEngComm © 2012 The Royal Society of Chemistry. |
| spellingShingle | DRNTU::Engineering::Materials::Magnetic materials Liu, Yi Tan, Melvin Wei Jun Wei, Fengxia Tian, Yufeng Wu, Tom Huo, Fengwei Yan, Qingyu Hng, Huey Hoon Ma, Jan Zhang, Qichun Kloc, Christian In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks |
| title | In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks |
| title_full | In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks |
| title_fullStr | In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks |
| title_full_unstemmed | In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks |
| title_short | In situ formation of new organic ligands to construct two novel self-charge-transfer Pb(ii)-based frameworks |
| title_sort | in situ formation of new organic ligands to construct two novel self charge transfer pb ii based frameworks |
| topic | DRNTU::Engineering::Materials::Magnetic materials |
| url | https://hdl.handle.net/10356/95611 http://hdl.handle.net/10220/10822 |
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