Preparation of SnO2/carbon composite hollow spheres and their lithium storage properties
In this work, we present a novel concept of structural design for preparing functional composite hollow spheres and derived double-shelled hollow spheres. The approach involves two main steps: preparation of porous hollow spheres of one component and deposition of the other component onto both the i...
Main Authors: | , , , |
---|---|
Other Authors: | |
Format: | Journal Article |
Language: | English |
Published: |
2012
|
Subjects: | |
Online Access: | https://hdl.handle.net/10356/95615 http://hdl.handle.net/10220/8320 |
_version_ | 1826127696444260352 |
---|---|
author | Lou, David Xiong Wen Deng, Da Lee, Jim Yang Archer, Lynden A. |
author2 | School of Chemical and Biomedical Engineering |
author_facet | School of Chemical and Biomedical Engineering Lou, David Xiong Wen Deng, Da Lee, Jim Yang Archer, Lynden A. |
author_sort | Lou, David Xiong Wen |
collection | NTU |
description | In this work, we present a novel concept of structural design for preparing functional composite hollow spheres and derived double-shelled hollow spheres. The approach involves two main steps: preparation of porous hollow spheres of one component and deposition of the other component onto both the interior and exterior surfaces of the shell as well as in the pores. We demonstrate the concept by preparing SnO2/carbon composite hollow spheres and evaluate them as potential anode materials for lithium-ion batteries. These SnO2/carbon hollow spheres are able to deliver a reversible Li storage capacity of 473 mA h g^−1 after 50 cycles. Unusual double-shelled carbon hollow spheres are obtained by selective removal of the sandwiched porous SnO2 shells. |
first_indexed | 2024-10-01T07:13:06Z |
format | Journal Article |
id | ntu-10356/95615 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T07:13:06Z |
publishDate | 2012 |
record_format | dspace |
spelling | ntu-10356/956152020-03-07T11:35:35Z Preparation of SnO2/carbon composite hollow spheres and their lithium storage properties Lou, David Xiong Wen Deng, Da Lee, Jim Yang Archer, Lynden A. School of Chemical and Biomedical Engineering DRNTU::Engineering::Chemical engineering In this work, we present a novel concept of structural design for preparing functional composite hollow spheres and derived double-shelled hollow spheres. The approach involves two main steps: preparation of porous hollow spheres of one component and deposition of the other component onto both the interior and exterior surfaces of the shell as well as in the pores. We demonstrate the concept by preparing SnO2/carbon composite hollow spheres and evaluate them as potential anode materials for lithium-ion batteries. These SnO2/carbon hollow spheres are able to deliver a reversible Li storage capacity of 473 mA h g^−1 after 50 cycles. Unusual double-shelled carbon hollow spheres are obtained by selective removal of the sandwiched porous SnO2 shells. 2012-07-12T08:34:20Z 2019-12-06T19:18:17Z 2012-07-12T08:34:20Z 2019-12-06T19:18:17Z 2008 2008 Journal Article Lou, X. W., Deng, D., Lee, J. Y., & Archer, L. A. (2008). Preparation of SnO2/Carbon Composite Hollow Spheres and Their Lithium Storage Properties. Chemistry of Materials, 20(20), 6562-6566. https://hdl.handle.net/10356/95615 http://hdl.handle.net/10220/8320 10.1021/cm801607e en Chemistry of materials © 2008 American Chemical Society. |
spellingShingle | DRNTU::Engineering::Chemical engineering Lou, David Xiong Wen Deng, Da Lee, Jim Yang Archer, Lynden A. Preparation of SnO2/carbon composite hollow spheres and their lithium storage properties |
title | Preparation of SnO2/carbon composite hollow spheres and their lithium storage properties |
title_full | Preparation of SnO2/carbon composite hollow spheres and their lithium storage properties |
title_fullStr | Preparation of SnO2/carbon composite hollow spheres and their lithium storage properties |
title_full_unstemmed | Preparation of SnO2/carbon composite hollow spheres and their lithium storage properties |
title_short | Preparation of SnO2/carbon composite hollow spheres and their lithium storage properties |
title_sort | preparation of sno2 carbon composite hollow spheres and their lithium storage properties |
topic | DRNTU::Engineering::Chemical engineering |
url | https://hdl.handle.net/10356/95615 http://hdl.handle.net/10220/8320 |
work_keys_str_mv | AT loudavidxiongwen preparationofsno2carboncompositehollowspheresandtheirlithiumstorageproperties AT dengda preparationofsno2carboncompositehollowspheresandtheirlithiumstorageproperties AT leejimyang preparationofsno2carboncompositehollowspheresandtheirlithiumstorageproperties AT archerlyndena preparationofsno2carboncompositehollowspheresandtheirlithiumstorageproperties |