Synthesis, characterization, and lithium storage capability of AMoO4 (A = Ni, Co) nanorods
One-dimensional (1D) AMoO4·nH2O (A = Ni, Co) nanorods have been synthesized by a facile hydrothermal method. The effect of different synthetic conditions on the morphologies of the final products was systematically investigated. The size of the nanorods can be easily controlled by adding ethanol in...
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2012
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| Online Access: | https://hdl.handle.net/10356/95705 http://hdl.handle.net/10220/8318 |
| _version_ | 1826118795658264576 |
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| author | Xiao, Wei Chen, Jun Song Li, Chang Ming Xu, Rong Lou, David Xiong Wen |
| author2 | School of Chemical and Biomedical Engineering |
| author_facet | School of Chemical and Biomedical Engineering Xiao, Wei Chen, Jun Song Li, Chang Ming Xu, Rong Lou, David Xiong Wen |
| author_sort | Xiao, Wei |
| collection | NTU |
| description | One-dimensional (1D) AMoO4·nH2O (A = Ni, Co) nanorods have been synthesized by a facile hydrothermal method. The effect of different synthetic conditions on the morphologies of the final products was systematically investigated. The size of the nanorods can be easily controlled by adding ethanol in the synthetic solution. For the first time, the self-assembled growth of oriented NiMoO4·nH2O nanorod arrays on Ti-foil substrates was achieved. The thermal dehydration and phase transformation processes of AMoO4·nH2O nanorods were thoroughly investigated by TG-DTA and time-resolved synchrotron XRD. As-prepared hydrate nanorods can be further converted to corresponding AMoO4 nanorods by annealing at 300−600 °C for 1 h without significant alteration of 1D morphology. Electrochemical lithium storage capabilities of dehydrated AMoO4 nanorods have been investigated. The results suggest their potential use as cathode materials for lithium ion batteries. |
| first_indexed | 2024-10-01T04:49:20Z |
| format | Journal Article |
| id | ntu-10356/95705 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T04:49:20Z |
| publishDate | 2012 |
| record_format | dspace |
| spelling | ntu-10356/957052020-03-07T11:35:35Z Synthesis, characterization, and lithium storage capability of AMoO4 (A = Ni, Co) nanorods Xiao, Wei Chen, Jun Song Li, Chang Ming Xu, Rong Lou, David Xiong Wen School of Chemical and Biomedical Engineering DRNTU::Engineering::Materials::Magnetic materials One-dimensional (1D) AMoO4·nH2O (A = Ni, Co) nanorods have been synthesized by a facile hydrothermal method. The effect of different synthetic conditions on the morphologies of the final products was systematically investigated. The size of the nanorods can be easily controlled by adding ethanol in the synthetic solution. For the first time, the self-assembled growth of oriented NiMoO4·nH2O nanorod arrays on Ti-foil substrates was achieved. The thermal dehydration and phase transformation processes of AMoO4·nH2O nanorods were thoroughly investigated by TG-DTA and time-resolved synchrotron XRD. As-prepared hydrate nanorods can be further converted to corresponding AMoO4 nanorods by annealing at 300−600 °C for 1 h without significant alteration of 1D morphology. Electrochemical lithium storage capabilities of dehydrated AMoO4 nanorods have been investigated. The results suggest their potential use as cathode materials for lithium ion batteries. 2012-07-12T07:25:52Z 2019-12-06T19:20:09Z 2012-07-12T07:25:52Z 2019-12-06T19:20:09Z 2010 2010 Journal Article Xiao, W., Chen, J. S., Li, C. M., Xu, R., & Lou, D. X. W. (2010). Synthesis, characterization, and lithium storage capability of AMoO4 (A = Ni, Co) nanorods. Chemistry of materials, 22(3), 746-754. https://hdl.handle.net/10356/95705 http://hdl.handle.net/10220/8318 10.1021/cm9012014 en Chemistry of materials © 2009 American Chemical Society. |
| spellingShingle | DRNTU::Engineering::Materials::Magnetic materials Xiao, Wei Chen, Jun Song Li, Chang Ming Xu, Rong Lou, David Xiong Wen Synthesis, characterization, and lithium storage capability of AMoO4 (A = Ni, Co) nanorods |
| title | Synthesis, characterization, and lithium storage capability of AMoO4 (A = Ni, Co) nanorods |
| title_full | Synthesis, characterization, and lithium storage capability of AMoO4 (A = Ni, Co) nanorods |
| title_fullStr | Synthesis, characterization, and lithium storage capability of AMoO4 (A = Ni, Co) nanorods |
| title_full_unstemmed | Synthesis, characterization, and lithium storage capability of AMoO4 (A = Ni, Co) nanorods |
| title_short | Synthesis, characterization, and lithium storage capability of AMoO4 (A = Ni, Co) nanorods |
| title_sort | synthesis characterization and lithium storage capability of amoo4 a ni co nanorods |
| topic | DRNTU::Engineering::Materials::Magnetic materials |
| url | https://hdl.handle.net/10356/95705 http://hdl.handle.net/10220/8318 |
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