Switching between halogen- and hydrogen-bonding in stoichiometric variations of a cocrystal of a phosphine oxide
We describe a two-component cocrystal composition which appears in two stoichiometric variations exhibiting different supramolecular architectures: whereas one stoichiometric variation displays C–HO hydrogen bonds, the second form exhibits short IO halogen bonds alongside Iπ halogen-bonded contacts;...
| Հիմնական հեղինակներ: | , , , , |
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| Այլ հեղինակներ: | |
| Ձևաչափ: | Journal Article |
| Լեզու: | English |
| Հրապարակվել է: |
2013
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| Առցանց հասանելիություն: | https://hdl.handle.net/10356/95796 http://hdl.handle.net/10220/10826 |
| Ամփոփում: | We describe a two-component cocrystal composition which appears in two stoichiometric variations exhibiting different supramolecular architectures: whereas one stoichiometric variation displays C–HO hydrogen bonds, the second form exhibits short IO halogen bonds alongside Iπ halogen-bonded contacts; the two forms are readily prepared mechanochemically by varying the relative amounts of starting materials in a liquid-assisted grinding process. |
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