Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers
An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement of α-oximino ketenes derived from α-diazo oxime ethers provides 2H-azirines bearing quaternary centers and allows for subsequent rearrangement to highly substituted pyrroles in excellent yiel...
Main Authors: | Jiang, Yaojia, Chan, Wei Chuen, Park, Cheol-Min |
---|---|
Other Authors: | School of Physical and Mathematical Sciences |
Format: | Journal Article |
Language: | English |
Published: |
2013
|
Online Access: | https://hdl.handle.net/10356/95800 http://hdl.handle.net/10220/11202 |
Similar Items
-
The application of diazo oxime ethers in the synthesis of heterocycles
by: Qi, Xinxin
Published: (2013) -
Polytopal Rearrangement Governing Stereochemistry of Bicyclic Oxime Ether Synthesis
by: Zlatan Spahić, et al.
Published: (2022-10-01) -
Copper-catalyzed condensation of imines and α-diazo-β-dicarbonyl compounds : modular and regiocontrolled synthesis of multisubstituted pyrroles
by: Tan, Wei Wen, et al.
Published: (2018) -
A catalyst-controlled selective synthesis of pyridines and pyrroles
by: Jiang, Yaojia, et al.
Published: (2014) -
Synthesis and rearrangement of 2-(arylsulfinyl)- and 2-(alkylsulfinyl) pyrroles /
by: Carmona, Olga