Electrochromic properties of nanostructured tungsten trioxide (hydrate) films and their applications in a complementary electrochromic device
Orthorhombic hydrated tungsten trioxide (3WO3·H2O) films consisted of nanosticks and nanoparticles were prepared on fluorine doped tin oxide (FTO)-coated substrate by a facile and template-free hydrothermal method using ammonium acetate (CH3COONH4) as the capping agent. Irregular nanobrick films wer...
| Main Authors: | , , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/95822 http://hdl.handle.net/10220/10841 |
| _version_ | 1826124815949365248 |
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| author | Sun, Xiaowei Jiao, Zhihui Wang, Jinmin Ke, Lin Liu, Xue-Wei Demir, Hilmi Volkan Yang, Ming Fei |
| author2 | School of Electrical and Electronic Engineering |
| author_facet | School of Electrical and Electronic Engineering Sun, Xiaowei Jiao, Zhihui Wang, Jinmin Ke, Lin Liu, Xue-Wei Demir, Hilmi Volkan Yang, Ming Fei |
| author_sort | Sun, Xiaowei |
| collection | NTU |
| description | Orthorhombic hydrated tungsten trioxide (3WO3·H2O) films consisted of nanosticks and nanoparticles were prepared on fluorine doped tin oxide (FTO)-coated substrate by a facile and template-free hydrothermal method using ammonium acetate (CH3COONH4) as the capping agent. Irregular nanobrick films were obtained without capping agent. Due to the highly rough surface, the nanostick/nanoparticle film depicts faster ion intercalation/deintercalation kinetics and a greater coloration efficiency (45.5 cm2/C) than the nanobrick film. A complementary electrochromic device based on the nanostick/nanoparticle 3WO3·H2O film and Prussian blue (PB) was assembled. As a result, the complementary device shows a higher optical modulation (54% at 754 nm), a larger coloration efficiency (151.9 cm2/C) and faster switching responses with a bleaching time of 5.7 s and a coloring time of 1.3 s than a single 3WO3·H2O layer device, making it attractive for a practical application. |
| first_indexed | 2024-10-01T06:26:51Z |
| format | Journal Article |
| id | ntu-10356/95822 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T06:26:51Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/958222020-03-07T14:02:45Z Electrochromic properties of nanostructured tungsten trioxide (hydrate) films and their applications in a complementary electrochromic device Sun, Xiaowei Jiao, Zhihui Wang, Jinmin Ke, Lin Liu, Xue-Wei Demir, Hilmi Volkan Yang, Ming Fei School of Electrical and Electronic Engineering School of Physical and Mathematical Sciences Orthorhombic hydrated tungsten trioxide (3WO3·H2O) films consisted of nanosticks and nanoparticles were prepared on fluorine doped tin oxide (FTO)-coated substrate by a facile and template-free hydrothermal method using ammonium acetate (CH3COONH4) as the capping agent. Irregular nanobrick films were obtained without capping agent. Due to the highly rough surface, the nanostick/nanoparticle film depicts faster ion intercalation/deintercalation kinetics and a greater coloration efficiency (45.5 cm2/C) than the nanobrick film. A complementary electrochromic device based on the nanostick/nanoparticle 3WO3·H2O film and Prussian blue (PB) was assembled. As a result, the complementary device shows a higher optical modulation (54% at 754 nm), a larger coloration efficiency (151.9 cm2/C) and faster switching responses with a bleaching time of 5.7 s and a coloring time of 1.3 s than a single 3WO3·H2O layer device, making it attractive for a practical application. 2013-07-01T04:27:09Z 2019-12-06T19:22:03Z 2013-07-01T04:27:09Z 2019-12-06T19:22:03Z 2011 2011 Journal Article Jiao, Z., Wang, J., Ke, L., Liu, X., Demir, H. V., Yang, M. F., et al. (2012). Electrochromic properties of nanostructured tungsten trioxide (hydrate) films and their applications in a complementary electrochromic device. Electrochimica acta, 63, 153-160. 0013-4686 https://hdl.handle.net/10356/95822 http://hdl.handle.net/10220/10841 10.1016/j.electacta.2011.12.069 en Electrochimica acta © 2011 Elsevier Ltd. |
| spellingShingle | Sun, Xiaowei Jiao, Zhihui Wang, Jinmin Ke, Lin Liu, Xue-Wei Demir, Hilmi Volkan Yang, Ming Fei Electrochromic properties of nanostructured tungsten trioxide (hydrate) films and their applications in a complementary electrochromic device |
| title | Electrochromic properties of nanostructured tungsten trioxide (hydrate) films and their applications in a complementary electrochromic device |
| title_full | Electrochromic properties of nanostructured tungsten trioxide (hydrate) films and their applications in a complementary electrochromic device |
| title_fullStr | Electrochromic properties of nanostructured tungsten trioxide (hydrate) films and their applications in a complementary electrochromic device |
| title_full_unstemmed | Electrochromic properties of nanostructured tungsten trioxide (hydrate) films and their applications in a complementary electrochromic device |
| title_short | Electrochromic properties of nanostructured tungsten trioxide (hydrate) films and their applications in a complementary electrochromic device |
| title_sort | electrochromic properties of nanostructured tungsten trioxide hydrate films and their applications in a complementary electrochromic device |
| url | https://hdl.handle.net/10356/95822 http://hdl.handle.net/10220/10841 |
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