Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains
Two novel one-dimensional coordination polymers, single helicate [Zn(SPh)2(TPyTA)(EG)]n (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh)2(BPyVB)]n (2), were synthesized under solvothermal conditions at 150 °C or room temperature by the co-assembly of Zn(SPh)2 and organic linkers such as 2,4,6...
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/95825 http://hdl.handle.net/10220/11388 |
| _version_ | 1826113288370388992 |
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| author | Blair, Richard G. Liu, Yi Yu, Lingmin Loo, Say Chye Joachim Zhang, Qichun |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Blair, Richard G. Liu, Yi Yu, Lingmin Loo, Say Chye Joachim Zhang, Qichun |
| author_sort | Blair, Richard G. |
| collection | NTU |
| description | Two novel one-dimensional coordination polymers, single helicate [Zn(SPh)2(TPyTA)(EG)]n (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh)2(BPyVB)]n (2), were synthesized under solvothermal conditions at 150 °C or room temperature by the co-assembly of Zn(SPh)2 and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl)benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P21/c of the monoclinic system. The solid-state UV–vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 °C and 210 °C. |
| first_indexed | 2024-10-01T03:21:05Z |
| format | Journal Article |
| id | ntu-10356/95825 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:21:05Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/958252020-06-01T10:01:40Z Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains Blair, Richard G. Liu, Yi Yu, Lingmin Loo, Say Chye Joachim Zhang, Qichun School of Materials Science & Engineering Two novel one-dimensional coordination polymers, single helicate [Zn(SPh)2(TPyTA)(EG)]n (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh)2(BPyVB)]n (2), were synthesized under solvothermal conditions at 150 °C or room temperature by the co-assembly of Zn(SPh)2 and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl)benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P21/c of the monoclinic system. The solid-state UV–vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 °C and 210 °C. 2013-07-15T03:44:57Z 2019-12-06T19:22:04Z 2013-07-15T03:44:57Z 2019-12-06T19:22:04Z 2012 2012 Journal Article Liu, Y., Yu, L., Loo, S. C. J., Blair, R. G., & Zhang, Q. (2012). Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains. Journal of solid state chemistry, 191, 283-286. 0022-4596 https://hdl.handle.net/10356/95825 http://hdl.handle.net/10220/11388 10.1016/j.jssc.2012.03.044 en Journal of solid state chemistry © 2012 Elsevier Inc. |
| spellingShingle | Blair, Richard G. Liu, Yi Yu, Lingmin Loo, Say Chye Joachim Zhang, Qichun Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains |
| title | Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains |
| title_full | Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains |
| title_fullStr | Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains |
| title_full_unstemmed | Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains |
| title_short | Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains |
| title_sort | co assembly of zn sph 2 and organic linkers into helical and zig zag polymer chains |
| url | https://hdl.handle.net/10356/95825 http://hdl.handle.net/10220/11388 |
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