Large-scale quantification of CVD graphene surface coverage

The extraordinary properties demonstrated for graphene and graphene-related materials can be fully exploited when a large-scale fabrication procedure is made available. Chemical vapor deposition (CVD) of graphene on Cu and Ni substrates is one of the most promising procedures to synthesize large-a...

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Main Authors: Ambrosi, Adriano, Bonanni, Alessandra, Sofer, Zdeněk, Pumera, Martin
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2013
Subjects:
Online Access:https://hdl.handle.net/10356/96089
http://hdl.handle.net/10220/10047
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author Ambrosi, Adriano
Bonanni, Alessandra
Sofer, Zdeněk
Pumera, Martin
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Ambrosi, Adriano
Bonanni, Alessandra
Sofer, Zdeněk
Pumera, Martin
author_sort Ambrosi, Adriano
collection NTU
description The extraordinary properties demonstrated for graphene and graphene-related materials can be fully exploited when a large-scale fabrication procedure is made available. Chemical vapor deposition (CVD) of graphene on Cu and Ni substrates is one of the most promising procedures to synthesize large-area and good quality graphene films. Parallel to the fabrication process, a large-scale quality monitoring technique is equally crucial. We demonstrate here a rapid and simple methodology that is able to probe the effectiveness of the growth process over a large substrate area for both Ni and Cu substrates. This method is based on inherent electrochemical signals generated by the underlying metal catalysts when fractures or discontinuities of the graphene film are present. The method can be applied immediately after the CVD growth process without the need for any graphene transfer step and represents a powerful quality monitoring technique for the assessment of large-scale fabrication of graphene by the CVD process.
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spelling ntu-10356/960892023-02-28T19:32:24Z Large-scale quantification of CVD graphene surface coverage Ambrosi, Adriano Bonanni, Alessandra Sofer, Zdeněk Pumera, Martin School of Physical and Mathematical Sciences DRNTU::Engineering::Materials::Nanostructured materials The extraordinary properties demonstrated for graphene and graphene-related materials can be fully exploited when a large-scale fabrication procedure is made available. Chemical vapor deposition (CVD) of graphene on Cu and Ni substrates is one of the most promising procedures to synthesize large-area and good quality graphene films. Parallel to the fabrication process, a large-scale quality monitoring technique is equally crucial. We demonstrate here a rapid and simple methodology that is able to probe the effectiveness of the growth process over a large substrate area for both Ni and Cu substrates. This method is based on inherent electrochemical signals generated by the underlying metal catalysts when fractures or discontinuities of the graphene film are present. The method can be applied immediately after the CVD growth process without the need for any graphene transfer step and represents a powerful quality monitoring technique for the assessment of large-scale fabrication of graphene by the CVD process. Accepted version 2013-06-04T04:31:48Z 2019-12-06T19:25:27Z 2013-06-04T04:31:48Z 2019-12-06T19:25:27Z 2013 2013 Journal Article Ambrosi, A., Bonanni, A., Sofer, Z., & Pumera, M. (2013). Large-scale quantification of CVD graphene surface coverage. Nanoscale, 5(6), 2379-2387. https://hdl.handle.net/10356/96089 http://hdl.handle.net/10220/10047 10.1039/c3nr33824j 171416 en Nanoscale © 2013 The Royal Society of Chemistry This is the author created version of a work that has been peer reviewed and accepted for publication by Nanoscale, The Royal Society of Chemistry. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1039/c3nr33824j]. application/pdf
spellingShingle DRNTU::Engineering::Materials::Nanostructured materials
Ambrosi, Adriano
Bonanni, Alessandra
Sofer, Zdeněk
Pumera, Martin
Large-scale quantification of CVD graphene surface coverage
title Large-scale quantification of CVD graphene surface coverage
title_full Large-scale quantification of CVD graphene surface coverage
title_fullStr Large-scale quantification of CVD graphene surface coverage
title_full_unstemmed Large-scale quantification of CVD graphene surface coverage
title_short Large-scale quantification of CVD graphene surface coverage
title_sort large scale quantification of cvd graphene surface coverage
topic DRNTU::Engineering::Materials::Nanostructured materials
url https://hdl.handle.net/10356/96089
http://hdl.handle.net/10220/10047
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