Graphene oxide organogel electrolyte for quasi solid dye sensitized solar cells

Low concentration, as low as 0.4 wt.% graphene oxide organogels is reported for different organic solvents. The gelation of organic solvents at exceedingly low concentrations opens the door for the implementation of graphene oxides based electrolytes in various electrochemical applications. Here we...

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Main Authors: Gun, Jenny, Kulkarni, Sneha A., Xiu, Wang, Batabyal, Sudip Kumar, Sladkevich, Sergey, Prikhodchenko, Petr V., Gutkin, Vitaly, Lev, Ovadia
Other Authors: School of Materials Science & Engineering
Format: Journal Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/96163
http://hdl.handle.net/10220/10857
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author Gun, Jenny
Kulkarni, Sneha A.
Xiu, Wang
Batabyal, Sudip Kumar
Sladkevich, Sergey
Prikhodchenko, Petr V.
Gutkin, Vitaly
Lev, Ovadia
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Gun, Jenny
Kulkarni, Sneha A.
Xiu, Wang
Batabyal, Sudip Kumar
Sladkevich, Sergey
Prikhodchenko, Petr V.
Gutkin, Vitaly
Lev, Ovadia
author_sort Gun, Jenny
collection NTU
description Low concentration, as low as 0.4 wt.% graphene oxide organogels is reported for different organic solvents. The gelation of organic solvents at exceedingly low concentrations opens the door for the implementation of graphene oxides based electrolytes in various electrochemical applications. Here we demonstrate the use of acetonitrile–graphene oxide (GO) gel containing iodide/triiodide as a quasi-solid electrolyte for dye sensitized solar cells (DSCs). Electrochemical impedance studies reveal that the mass transfer barrier is not adversely affected by the presence of the minute amount of GO gel former. The achieved energy conversion efficiency (η) for the device without GO and with 1% GO gel electrolytes is 6.9% and 7.5% respectively under one sun illumination.
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spelling ntu-10356/961632021-01-08T07:40:47Z Graphene oxide organogel electrolyte for quasi solid dye sensitized solar cells Gun, Jenny Kulkarni, Sneha A. Xiu, Wang Batabyal, Sudip Kumar Sladkevich, Sergey Prikhodchenko, Petr V. Gutkin, Vitaly Lev, Ovadia School of Materials Science & Engineering Energy Research Institute @ NTU (ERI@N) Low concentration, as low as 0.4 wt.% graphene oxide organogels is reported for different organic solvents. The gelation of organic solvents at exceedingly low concentrations opens the door for the implementation of graphene oxides based electrolytes in various electrochemical applications. Here we demonstrate the use of acetonitrile–graphene oxide (GO) gel containing iodide/triiodide as a quasi-solid electrolyte for dye sensitized solar cells (DSCs). Electrochemical impedance studies reveal that the mass transfer barrier is not adversely affected by the presence of the minute amount of GO gel former. The achieved energy conversion efficiency (η) for the device without GO and with 1% GO gel electrolytes is 6.9% and 7.5% respectively under one sun illumination. 2013-07-01T06:22:29Z 2019-12-06T19:26:29Z 2013-07-01T06:22:29Z 2019-12-06T19:26:29Z 2012 2012 Journal Article Gun, J., Kulkarni, S. A., Xiu, W., Batabyal, S. K., Sladkevich, S., Prikhodchenko, P. V., et al. (2012). Graphene oxide organogel electrolyte for quasi solid dye sensitized solar cells. Electrochemistry Communications, 19, 108-110. 1388-2481 https://hdl.handle.net/10356/96163 http://hdl.handle.net/10220/10857 10.1016/j.elecom.2012.03.025 en Electrochemistry communications © 2012 Elsevier B.V.
spellingShingle Gun, Jenny
Kulkarni, Sneha A.
Xiu, Wang
Batabyal, Sudip Kumar
Sladkevich, Sergey
Prikhodchenko, Petr V.
Gutkin, Vitaly
Lev, Ovadia
Graphene oxide organogel electrolyte for quasi solid dye sensitized solar cells
title Graphene oxide organogel electrolyte for quasi solid dye sensitized solar cells
title_full Graphene oxide organogel electrolyte for quasi solid dye sensitized solar cells
title_fullStr Graphene oxide organogel electrolyte for quasi solid dye sensitized solar cells
title_full_unstemmed Graphene oxide organogel electrolyte for quasi solid dye sensitized solar cells
title_short Graphene oxide organogel electrolyte for quasi solid dye sensitized solar cells
title_sort graphene oxide organogel electrolyte for quasi solid dye sensitized solar cells
url https://hdl.handle.net/10356/96163
http://hdl.handle.net/10220/10857
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