A facile route to vertically aligned electrospun SnO2 nanowires on a transparent conducting oxide substrate for dye-sensitized solar cells

We demonstrate a large-scale production of aligned SnO2 nanofibers with a multi-nozzle electrospinning method combined with an air-shield enclosed rotating drum collector. The production rate by this multi-nozzle approach is several times higher than that of the single-nozzle electrospinning. The na...

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Main Authors: Krishnamoorthy, Thirumal, Tang, Mu Zhi, Verma, Akshara, Nair, A. Sreekumaran, Pliszka, Damian, Mhaisalkar, Subodh Gautam, Ramakrishna, Seeram
Other Authors: School of Materials Science & Engineering
Format: Journal Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/96340
http://hdl.handle.net/10220/11578
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author Krishnamoorthy, Thirumal
Tang, Mu Zhi
Verma, Akshara
Nair, A. Sreekumaran
Pliszka, Damian
Mhaisalkar, Subodh Gautam
Ramakrishna, Seeram
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Krishnamoorthy, Thirumal
Tang, Mu Zhi
Verma, Akshara
Nair, A. Sreekumaran
Pliszka, Damian
Mhaisalkar, Subodh Gautam
Ramakrishna, Seeram
author_sort Krishnamoorthy, Thirumal
collection NTU
description We demonstrate a large-scale production of aligned SnO2 nanofibers with a multi-nozzle electrospinning method combined with an air-shield enclosed rotating drum collector. The production rate by this multi-nozzle approach is several times higher than that of the single-nozzle electrospinning. The nanofibers produced were having a short range of diameters similar to the case of nanofibers produced by single nozzle electrospinning. The well-aligned nanofibers are subsequently processed into vertically oriented SnO2 nanowires on an FTO substrate. The average diameter and length of the wires were 75 ± 25 nm and 19 ± 2 μm, respectively. Dye-sensitized solar cells using this nanostructured material as the working electrode yielded a short-circuit current density (Jsc) of 9.9 mA cm−2 (which is 42% higher than that achieved by nanowires produced by other methods), an open-circuit voltage (Voc) of 0.525 V and a power conversion efficiency (η) of 2.53%. We believe that improvement of the multi-nozzle electrospinning is highly promising for commercialization due to simplicity and easiness of fabricating the spinneret, control over the diameter and spatial orientation of the fibers.
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spelling ntu-10356/963402020-06-01T10:13:34Z A facile route to vertically aligned electrospun SnO2 nanowires on a transparent conducting oxide substrate for dye-sensitized solar cells Krishnamoorthy, Thirumal Tang, Mu Zhi Verma, Akshara Nair, A. Sreekumaran Pliszka, Damian Mhaisalkar, Subodh Gautam Ramakrishna, Seeram School of Materials Science & Engineering We demonstrate a large-scale production of aligned SnO2 nanofibers with a multi-nozzle electrospinning method combined with an air-shield enclosed rotating drum collector. The production rate by this multi-nozzle approach is several times higher than that of the single-nozzle electrospinning. The nanofibers produced were having a short range of diameters similar to the case of nanofibers produced by single nozzle electrospinning. The well-aligned nanofibers are subsequently processed into vertically oriented SnO2 nanowires on an FTO substrate. The average diameter and length of the wires were 75 ± 25 nm and 19 ± 2 μm, respectively. Dye-sensitized solar cells using this nanostructured material as the working electrode yielded a short-circuit current density (Jsc) of 9.9 mA cm−2 (which is 42% higher than that achieved by nanowires produced by other methods), an open-circuit voltage (Voc) of 0.525 V and a power conversion efficiency (η) of 2.53%. We believe that improvement of the multi-nozzle electrospinning is highly promising for commercialization due to simplicity and easiness of fabricating the spinneret, control over the diameter and spatial orientation of the fibers. 2013-07-16T07:00:35Z 2019-12-06T19:29:16Z 2013-07-16T07:00:35Z 2019-12-06T19:29:16Z 2012 2012 Journal Article Krishnamoorthy, T., Tang, M. Z., Verma, A., Nair, A. S., Pliszka, D., Mhaisalkar, S. G., et al. (2012). A facile route to vertically aligned electrospun SnO2 nanowires on a transparent conducting oxide substrate for dye-sensitized solar cells. Journal of Materials Chemistry, 22(5), 2166-2172. https://hdl.handle.net/10356/96340 http://hdl.handle.net/10220/11578 10.1039/c1jm15047b en Journal of materials chemistry © 2012 Royal Society of Chemistry.
spellingShingle Krishnamoorthy, Thirumal
Tang, Mu Zhi
Verma, Akshara
Nair, A. Sreekumaran
Pliszka, Damian
Mhaisalkar, Subodh Gautam
Ramakrishna, Seeram
A facile route to vertically aligned electrospun SnO2 nanowires on a transparent conducting oxide substrate for dye-sensitized solar cells
title A facile route to vertically aligned electrospun SnO2 nanowires on a transparent conducting oxide substrate for dye-sensitized solar cells
title_full A facile route to vertically aligned electrospun SnO2 nanowires on a transparent conducting oxide substrate for dye-sensitized solar cells
title_fullStr A facile route to vertically aligned electrospun SnO2 nanowires on a transparent conducting oxide substrate for dye-sensitized solar cells
title_full_unstemmed A facile route to vertically aligned electrospun SnO2 nanowires on a transparent conducting oxide substrate for dye-sensitized solar cells
title_short A facile route to vertically aligned electrospun SnO2 nanowires on a transparent conducting oxide substrate for dye-sensitized solar cells
title_sort facile route to vertically aligned electrospun sno2 nanowires on a transparent conducting oxide substrate for dye sensitized solar cells
url https://hdl.handle.net/10356/96340
http://hdl.handle.net/10220/11578
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