One stone kills four birds : a novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions
A novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one has been successfully synthesized through a one-step condensation. Single crystal X-ray analysis shows that the product is of planar structure with strong π⋯π interactions and H-bonding. Interestingly, the 12H-pyrazino[2′,3′...
| Main Authors: | , , , , , , , , , , |
|---|---|
| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
|
| Online Access: | https://hdl.handle.net/10356/96576 http://hdl.handle.net/10220/10318 |
| _version_ | 1826129440346734592 |
|---|---|
| author | Zhao, Jianfeng Liu, Yi Soh, Jiayun Bethia Li, Yongxin Ganguly, Rakesh Ye, Kaiqi Huo, Fengwei Huang, Ling Loo, Say Chye Joachim Zhang, Qichun Tok, Alfred Iing Yoong |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Zhao, Jianfeng Liu, Yi Soh, Jiayun Bethia Li, Yongxin Ganguly, Rakesh Ye, Kaiqi Huo, Fengwei Huang, Ling Loo, Say Chye Joachim Zhang, Qichun Tok, Alfred Iing Yoong |
| author_sort | Zhao, Jianfeng |
| collection | NTU |
| description | A novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one has been successfully synthesized through a one-step condensation. Single crystal X-ray analysis shows that the product is of planar structure with strong π⋯π interactions and H-bonding. Interestingly, the 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one can recognize three different metal cations Cu2+, Ag+ and Hg2+ via naked eye visualization, and shows turn-on fluorescence for Fe3+ and Ag+ among the 22 metal cations. |
| first_indexed | 2024-10-01T07:40:38Z |
| format | Journal Article |
| id | ntu-10356/96576 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T07:40:38Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/965762020-06-01T10:21:13Z One stone kills four birds : a novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions Zhao, Jianfeng Liu, Yi Soh, Jiayun Bethia Li, Yongxin Ganguly, Rakesh Ye, Kaiqi Huo, Fengwei Huang, Ling Loo, Say Chye Joachim Zhang, Qichun Tok, Alfred Iing Yoong School of Materials Science & Engineering School of Physical and Mathematical Sciences School of Chemical and Biomedical Engineering A novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one has been successfully synthesized through a one-step condensation. Single crystal X-ray analysis shows that the product is of planar structure with strong π⋯π interactions and H-bonding. Interestingly, the 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one can recognize three different metal cations Cu2+, Ag+ and Hg2+ via naked eye visualization, and shows turn-on fluorescence for Fe3+ and Ag+ among the 22 metal cations. 2013-06-13T04:02:58Z 2019-12-06T19:32:42Z 2013-06-13T04:02:58Z 2019-12-06T19:32:42Z 2012 2012 Journal Article Zhao, J.-F., Liu, Y., Soh, J. B., Li, Y.-X., Ganguly, R., Ye, K.-Q., et al. (2012). One stone kills four birds: a novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions. Tetrahedron letters, 53(45), 6044-6047. 0040-4039 https://hdl.handle.net/10356/96576 http://hdl.handle.net/10220/10318 10.1016/j.tetlet.2012.08.106 en Tetrahedron letters © 2012 Elsevier Ltd. |
| spellingShingle | Zhao, Jianfeng Liu, Yi Soh, Jiayun Bethia Li, Yongxin Ganguly, Rakesh Ye, Kaiqi Huo, Fengwei Huang, Ling Loo, Say Chye Joachim Zhang, Qichun Tok, Alfred Iing Yoong One stone kills four birds : a novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions |
| title | One stone kills four birds : a novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions |
| title_full | One stone kills four birds : a novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions |
| title_fullStr | One stone kills four birds : a novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions |
| title_full_unstemmed | One stone kills four birds : a novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions |
| title_short | One stone kills four birds : a novel diazaperinone 12H-pyrazino[2′,3′:3,4]pyrrolo[1,2-a]perimidin-12-one recognizes four different metal ions |
| title_sort | one stone kills four birds a novel diazaperinone 12h pyrazino 2 3 3 4 pyrrolo 1 2 a perimidin 12 one recognizes four different metal ions |
| url | https://hdl.handle.net/10356/96576 http://hdl.handle.net/10220/10318 |
| work_keys_str_mv | AT zhaojianfeng onestonekillsfourbirdsanoveldiazaperinone12hpyrazino2334pyrrolo12aperimidin12onerecognizesfourdifferentmetalions AT liuyi onestonekillsfourbirdsanoveldiazaperinone12hpyrazino2334pyrrolo12aperimidin12onerecognizesfourdifferentmetalions AT sohjiayunbethia onestonekillsfourbirdsanoveldiazaperinone12hpyrazino2334pyrrolo12aperimidin12onerecognizesfourdifferentmetalions AT liyongxin onestonekillsfourbirdsanoveldiazaperinone12hpyrazino2334pyrrolo12aperimidin12onerecognizesfourdifferentmetalions AT gangulyrakesh onestonekillsfourbirdsanoveldiazaperinone12hpyrazino2334pyrrolo12aperimidin12onerecognizesfourdifferentmetalions AT yekaiqi onestonekillsfourbirdsanoveldiazaperinone12hpyrazino2334pyrrolo12aperimidin12onerecognizesfourdifferentmetalions AT huofengwei onestonekillsfourbirdsanoveldiazaperinone12hpyrazino2334pyrrolo12aperimidin12onerecognizesfourdifferentmetalions AT huangling onestonekillsfourbirdsanoveldiazaperinone12hpyrazino2334pyrrolo12aperimidin12onerecognizesfourdifferentmetalions AT loosaychyejoachim onestonekillsfourbirdsanoveldiazaperinone12hpyrazino2334pyrrolo12aperimidin12onerecognizesfourdifferentmetalions AT zhangqichun onestonekillsfourbirdsanoveldiazaperinone12hpyrazino2334pyrrolo12aperimidin12onerecognizesfourdifferentmetalions AT tokalfrediingyoong onestonekillsfourbirdsanoveldiazaperinone12hpyrazino2334pyrrolo12aperimidin12onerecognizesfourdifferentmetalions |