Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride
In the presence of copper(I) chloride, tert-butyl 1-hydroxy-2-methyl-6-trifluoromethyl-1H-indole-3-carboxylate acted as a catalyst for the chemoselective aerobic oxidation of allylic and benzylic alcohols. A variety of primary and secondary allylic and benzylic alcohols were oxidized into the corres...
| Main Authors: | , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/96586 http://hdl.handle.net/10220/10308 |
| _version_ | 1826109747818921984 |
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| author | Shen, Shu-Su Kartika, Vita Tan, Ying Shan Webster, Richard David Narasaka, Koichi |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Shen, Shu-Su Kartika, Vita Tan, Ying Shan Webster, Richard David Narasaka, Koichi |
| author_sort | Shen, Shu-Su |
| collection | NTU |
| description | In the presence of copper(I) chloride, tert-butyl 1-hydroxy-2-methyl-6-trifluoromethyl-1H-indole-3-carboxylate acted as a catalyst for the chemoselective aerobic oxidation of allylic and benzylic alcohols. A variety of primary and secondary allylic and benzylic alcohols were oxidized into the corresponding α,β-unsaturated carbonyl compounds in good yields without affecting non-allylic alcohols. |
| first_indexed | 2024-10-01T02:23:04Z |
| format | Journal Article |
| id | ntu-10356/96586 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T02:23:04Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/965862020-03-07T12:34:43Z Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride Shen, Shu-Su Kartika, Vita Tan, Ying Shan Webster, Richard David Narasaka, Koichi School of Physical and Mathematical Sciences In the presence of copper(I) chloride, tert-butyl 1-hydroxy-2-methyl-6-trifluoromethyl-1H-indole-3-carboxylate acted as a catalyst for the chemoselective aerobic oxidation of allylic and benzylic alcohols. A variety of primary and secondary allylic and benzylic alcohols were oxidized into the corresponding α,β-unsaturated carbonyl compounds in good yields without affecting non-allylic alcohols. 2013-06-13T03:23:09Z 2019-12-06T19:32:47Z 2013-06-13T03:23:09Z 2019-12-06T19:32:47Z 2011 2011 Journal Article Shen, S.-S., Kartika, V., Tan, Y. S., Webster, R. D., & Narasaka, K. (2012). Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride. Tetrahedron Letters, 53(8), 986-990. 0040-4039 https://hdl.handle.net/10356/96586 http://hdl.handle.net/10220/10308 10.1016/j.tetlet.2011.12.058 en Tetrahedron letters © 2011 Elsevier Ltd. |
| spellingShingle | Shen, Shu-Su Kartika, Vita Tan, Ying Shan Webster, Richard David Narasaka, Koichi Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride |
| title | Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride |
| title_full | Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride |
| title_fullStr | Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride |
| title_full_unstemmed | Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride |
| title_short | Selective aerobic oxidation of allylic and benzylic alcohols catalyzed by N-hydroxyindole and copper(I) chloride |
| title_sort | selective aerobic oxidation of allylic and benzylic alcohols catalyzed by n hydroxyindole and copper i chloride |
| url | https://hdl.handle.net/10356/96586 http://hdl.handle.net/10220/10308 |
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