Enhanced photoelectrochemical performance of bridged ZnO nanorod arrays grown on V-grooved structure

Bridged ZnO nanorod arrays on a V-grooved Si(100) substrate were used as the photoanode of a photoelectrochemical (PEC) cell for water splitting. Photolithography followed by reactive ion etching was employed to create a V-grooved structure on a Si substrate. ZnO nanorod arrays were grown via a hydr...

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Main Authors: Wei, Yuefan, Ke, Lin, Leong, Eunice Sok Ping, Liu, Hong, Liew, Laura-Lynn, Teng, Jing Hua, Du, Hejun, Sun, Xiaowei
Other Authors: School of Electrical and Electronic Engineering
Format: Journal Article
Language:English
Published: 2013
Subjects:
Online Access:https://hdl.handle.net/10356/96653
http://hdl.handle.net/10220/9975
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author Wei, Yuefan
Ke, Lin
Leong, Eunice Sok Ping
Liu, Hong
Liew, Laura-Lynn
Teng, Jing Hua
Du, Hejun
Sun, Xiaowei
author2 School of Electrical and Electronic Engineering
author_facet School of Electrical and Electronic Engineering
Wei, Yuefan
Ke, Lin
Leong, Eunice Sok Ping
Liu, Hong
Liew, Laura-Lynn
Teng, Jing Hua
Du, Hejun
Sun, Xiaowei
author_sort Wei, Yuefan
collection NTU
description Bridged ZnO nanorod arrays on a V-grooved Si(100) substrate were used as the photoanode of a photoelectrochemical (PEC) cell for water splitting. Photolithography followed by reactive ion etching was employed to create a V-grooved structure on a Si substrate. ZnO nanorod arrays were grown via a hydrothermal method. The light trapping and PEC properties are greatly enhanced using the bridged ZnO nanorod arrays on a V-grooved Si substrate compared with those on a flat one. Increased short circuit photocurrent density (JSC, 0.73 mA cm−2) and half-life time (1500 s) are achieved. This improved JSC and half-life time are 4 times and 10 times, respectively, higher than those of the ZnO nanorod arrays grown on a flat substrate. The overall PEC cell performance improvement for the V-groove grown ZnO array is attributed to the reduced light reflection and enhanced light trapping effect. Moreover, V-groove ZnO showed stronger adhesion between ZnO nanorod arrays and the substrate.
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spelling ntu-10356/966532020-03-07T13:22:17Z Enhanced photoelectrochemical performance of bridged ZnO nanorod arrays grown on V-grooved structure Wei, Yuefan Ke, Lin Leong, Eunice Sok Ping Liu, Hong Liew, Laura-Lynn Teng, Jing Hua Du, Hejun Sun, Xiaowei School of Electrical and Electronic Engineering School of Mechanical and Aerospace Engineering DRNTU::Engineering::Electrical and electronic engineering Bridged ZnO nanorod arrays on a V-grooved Si(100) substrate were used as the photoanode of a photoelectrochemical (PEC) cell for water splitting. Photolithography followed by reactive ion etching was employed to create a V-grooved structure on a Si substrate. ZnO nanorod arrays were grown via a hydrothermal method. The light trapping and PEC properties are greatly enhanced using the bridged ZnO nanorod arrays on a V-grooved Si substrate compared with those on a flat one. Increased short circuit photocurrent density (JSC, 0.73 mA cm−2) and half-life time (1500 s) are achieved. This improved JSC and half-life time are 4 times and 10 times, respectively, higher than those of the ZnO nanorod arrays grown on a flat substrate. The overall PEC cell performance improvement for the V-groove grown ZnO array is attributed to the reduced light reflection and enhanced light trapping effect. Moreover, V-groove ZnO showed stronger adhesion between ZnO nanorod arrays and the substrate. Accepted Version 2013-05-22T07:34:06Z 2019-12-06T19:33:30Z 2013-05-22T07:34:06Z 2019-12-06T19:33:30Z 2012 2012 Journal Article Wei, Y., Ke, L., Leong, E. S. P., Liu, H., Liew, L. L., Teng, J. H., et al. (2012). Enhanced photoelectrochemical performance of bridged ZnO nanorod arrays grown on V-grooved structure. Nanotechnology, 23(36). https://hdl.handle.net/10356/96653 http://hdl.handle.net/10220/9975 10.1088/0957-4484/23/36/365704 167663 en Nanotechnology © 2012 IOP Publishing Ltd. This is the author created version of a work that has been peer reviewed and accepted for publication by Nanotechnology, IOP Publishing Ltd. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1088/0957-4484/23/36/365704]. application/pdf
spellingShingle DRNTU::Engineering::Electrical and electronic engineering
Wei, Yuefan
Ke, Lin
Leong, Eunice Sok Ping
Liu, Hong
Liew, Laura-Lynn
Teng, Jing Hua
Du, Hejun
Sun, Xiaowei
Enhanced photoelectrochemical performance of bridged ZnO nanorod arrays grown on V-grooved structure
title Enhanced photoelectrochemical performance of bridged ZnO nanorod arrays grown on V-grooved structure
title_full Enhanced photoelectrochemical performance of bridged ZnO nanorod arrays grown on V-grooved structure
title_fullStr Enhanced photoelectrochemical performance of bridged ZnO nanorod arrays grown on V-grooved structure
title_full_unstemmed Enhanced photoelectrochemical performance of bridged ZnO nanorod arrays grown on V-grooved structure
title_short Enhanced photoelectrochemical performance of bridged ZnO nanorod arrays grown on V-grooved structure
title_sort enhanced photoelectrochemical performance of bridged zno nanorod arrays grown on v grooved structure
topic DRNTU::Engineering::Electrical and electronic engineering
url https://hdl.handle.net/10356/96653
http://hdl.handle.net/10220/9975
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