Chemoselective photodeoxidization of graphene oxide using sterically hindered amines as catalyst : synthesis and applications
We report a green and efficient method for chemoselective deoxidization of graphene oxide via the ultraviolet irradiation catalyzed with 2,2,6,6-tetramethyl-4-piperidinol. While the sp2-hybridized oxygen functional groups are removed after the reduction, the epoxy and hydroxyl groups are retained in...
| Main Authors: | , , , , , , , , , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/97107 http://hdl.handle.net/10220/10325 |
| _version_ | 1826118972431400960 |
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| author | Wu, Shixin Ai, Wei Yi, Ming-Dong Qi, Xiaoying Xie, Linghai Wang, Junling Zhang, Hua Huang, Wei Zhao, Fei Liu, Juqing Huang, Xiao Zou, Xi Lu, Gang Sun, Pengju |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Wu, Shixin Ai, Wei Yi, Ming-Dong Qi, Xiaoying Xie, Linghai Wang, Junling Zhang, Hua Huang, Wei Zhao, Fei Liu, Juqing Huang, Xiao Zou, Xi Lu, Gang Sun, Pengju |
| author_sort | Wu, Shixin |
| collection | NTU |
| description | We report a green and efficient method for chemoselective deoxidization of graphene oxide via the ultraviolet irradiation catalyzed with 2,2,6,6-tetramethyl-4-piperidinol. While the sp2-hybridized oxygen functional groups are removed after the reduction, the epoxy and hydroxyl groups are retained in the chemoselectively reduced graphene oxide (CrGO). The obtained CrGO nanosheets exhibit the high solubility and excellent electronic stability, which allows for the fabrication of thin film devices through a solution processing. As a proof of concept, a CrGO-based write-once-read-many-times memory device with the desirable stability and long-time operation is fabricated. |
| first_indexed | 2024-10-01T04:52:19Z |
| format | Journal Article |
| id | ntu-10356/97107 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T04:52:19Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/971072020-06-01T10:01:40Z Chemoselective photodeoxidization of graphene oxide using sterically hindered amines as catalyst : synthesis and applications Wu, Shixin Ai, Wei Yi, Ming-Dong Qi, Xiaoying Xie, Linghai Wang, Junling Zhang, Hua Huang, Wei Zhao, Fei Liu, Juqing Huang, Xiao Zou, Xi Lu, Gang Sun, Pengju School of Materials Science & Engineering We report a green and efficient method for chemoselective deoxidization of graphene oxide via the ultraviolet irradiation catalyzed with 2,2,6,6-tetramethyl-4-piperidinol. While the sp2-hybridized oxygen functional groups are removed after the reduction, the epoxy and hydroxyl groups are retained in the chemoselectively reduced graphene oxide (CrGO). The obtained CrGO nanosheets exhibit the high solubility and excellent electronic stability, which allows for the fabrication of thin film devices through a solution processing. As a proof of concept, a CrGO-based write-once-read-many-times memory device with the desirable stability and long-time operation is fabricated. 2013-06-13T04:25:01Z 2019-12-06T19:39:02Z 2013-06-13T04:25:01Z 2019-12-06T19:39:02Z 2012 2012 Journal Article Zhao, F., Liu, J., Huang, X., Zou, X., Lu, G., Sun, P., et al. (2012). Chemoselective Photodeoxidization of Graphene Oxide Using Sterically Hindered Amines as Catalyst: Synthesis and Applications. ACS Nano, 6(4), 3027-3033. 1936-0851 https://hdl.handle.net/10356/97107 http://hdl.handle.net/10220/10325 10.1021/nn2047185 en ACS nano © 2012 American Chemical Society. |
| spellingShingle | Wu, Shixin Ai, Wei Yi, Ming-Dong Qi, Xiaoying Xie, Linghai Wang, Junling Zhang, Hua Huang, Wei Zhao, Fei Liu, Juqing Huang, Xiao Zou, Xi Lu, Gang Sun, Pengju Chemoselective photodeoxidization of graphene oxide using sterically hindered amines as catalyst : synthesis and applications |
| title | Chemoselective photodeoxidization of graphene oxide using sterically hindered amines as catalyst : synthesis and applications |
| title_full | Chemoselective photodeoxidization of graphene oxide using sterically hindered amines as catalyst : synthesis and applications |
| title_fullStr | Chemoselective photodeoxidization of graphene oxide using sterically hindered amines as catalyst : synthesis and applications |
| title_full_unstemmed | Chemoselective photodeoxidization of graphene oxide using sterically hindered amines as catalyst : synthesis and applications |
| title_short | Chemoselective photodeoxidization of graphene oxide using sterically hindered amines as catalyst : synthesis and applications |
| title_sort | chemoselective photodeoxidization of graphene oxide using sterically hindered amines as catalyst synthesis and applications |
| url | https://hdl.handle.net/10356/97107 http://hdl.handle.net/10220/10325 |
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