Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides

An ortho-arylation reaction of aromatic imines with aryl chlorides has been achieved using a cobalt–N-heterocyclic carbene catalyst in combination with a neopentyl Grignard reagent. The reaction takes place at room temperature to afford biaryl products in moderate to good yields.

书目详细资料
Main Authors: Gao, Ke, Lee, Pin-Sheng, Long, Chong, Yoshikai, Naohiko
其他作者: School of Physical and Mathematical Sciences
格式: Journal Article
语言:English
出版: 2013
在线阅读:https://hdl.handle.net/10356/97232
http://hdl.handle.net/10220/10610
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author Gao, Ke
Lee, Pin-Sheng
Long, Chong
Yoshikai, Naohiko
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Gao, Ke
Lee, Pin-Sheng
Long, Chong
Yoshikai, Naohiko
author_sort Gao, Ke
collection NTU
description An ortho-arylation reaction of aromatic imines with aryl chlorides has been achieved using a cobalt–N-heterocyclic carbene catalyst in combination with a neopentyl Grignard reagent. The reaction takes place at room temperature to afford biaryl products in moderate to good yields.
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spelling ntu-10356/972322020-03-07T12:34:42Z Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides Gao, Ke Lee, Pin-Sheng Long, Chong Yoshikai, Naohiko School of Physical and Mathematical Sciences An ortho-arylation reaction of aromatic imines with aryl chlorides has been achieved using a cobalt–N-heterocyclic carbene catalyst in combination with a neopentyl Grignard reagent. The reaction takes place at room temperature to afford biaryl products in moderate to good yields. 2013-06-25T04:09:56Z 2019-12-06T19:40:26Z 2013-06-25T04:09:56Z 2019-12-06T19:40:26Z 2012 2012 Journal Article Gao, K., Lee, P.-S., Long, C., & Yoshikai, N. (2012). Cobalt-Catalyzed Ortho-Arylation of Aromatic Imines with Aryl Chlorides. Organic Letters, 14(16), 4234-4237. 1523-7060 https://hdl.handle.net/10356/97232 http://hdl.handle.net/10220/10610 10.1021/ol301934y en Organic letters © 2012 American Chemical Society.
spellingShingle Gao, Ke
Lee, Pin-Sheng
Long, Chong
Yoshikai, Naohiko
Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides
title Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides
title_full Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides
title_fullStr Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides
title_full_unstemmed Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides
title_short Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides
title_sort cobalt catalyzed ortho arylation of aromatic imines with aryl chlorides
url https://hdl.handle.net/10356/97232
http://hdl.handle.net/10220/10610
work_keys_str_mv AT gaoke cobaltcatalyzedorthoarylationofaromaticimineswitharylchlorides
AT leepinsheng cobaltcatalyzedorthoarylationofaromaticimineswitharylchlorides
AT longchong cobaltcatalyzedorthoarylationofaromaticimineswitharylchlorides
AT yoshikainaohiko cobaltcatalyzedorthoarylationofaromaticimineswitharylchlorides