Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides
An ortho-arylation reaction of aromatic imines with aryl chlorides has been achieved using a cobalt–N-heterocyclic carbene catalyst in combination with a neopentyl Grignard reagent. The reaction takes place at room temperature to afford biaryl products in moderate to good yields.
Main Authors: | , , , |
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其他作者: | |
格式: | Journal Article |
语言: | English |
出版: |
2013
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在线阅读: | https://hdl.handle.net/10356/97232 http://hdl.handle.net/10220/10610 |
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author | Gao, Ke Lee, Pin-Sheng Long, Chong Yoshikai, Naohiko |
author2 | School of Physical and Mathematical Sciences |
author_facet | School of Physical and Mathematical Sciences Gao, Ke Lee, Pin-Sheng Long, Chong Yoshikai, Naohiko |
author_sort | Gao, Ke |
collection | NTU |
description | An ortho-arylation reaction of aromatic imines with aryl chlorides has been achieved using a cobalt–N-heterocyclic carbene catalyst in combination with a neopentyl Grignard reagent. The reaction takes place at room temperature to afford biaryl products in moderate to good yields. |
first_indexed | 2024-10-01T07:33:10Z |
format | Journal Article |
id | ntu-10356/97232 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T07:33:10Z |
publishDate | 2013 |
record_format | dspace |
spelling | ntu-10356/972322020-03-07T12:34:42Z Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides Gao, Ke Lee, Pin-Sheng Long, Chong Yoshikai, Naohiko School of Physical and Mathematical Sciences An ortho-arylation reaction of aromatic imines with aryl chlorides has been achieved using a cobalt–N-heterocyclic carbene catalyst in combination with a neopentyl Grignard reagent. The reaction takes place at room temperature to afford biaryl products in moderate to good yields. 2013-06-25T04:09:56Z 2019-12-06T19:40:26Z 2013-06-25T04:09:56Z 2019-12-06T19:40:26Z 2012 2012 Journal Article Gao, K., Lee, P.-S., Long, C., & Yoshikai, N. (2012). Cobalt-Catalyzed Ortho-Arylation of Aromatic Imines with Aryl Chlorides. Organic Letters, 14(16), 4234-4237. 1523-7060 https://hdl.handle.net/10356/97232 http://hdl.handle.net/10220/10610 10.1021/ol301934y en Organic letters © 2012 American Chemical Society. |
spellingShingle | Gao, Ke Lee, Pin-Sheng Long, Chong Yoshikai, Naohiko Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides |
title | Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides |
title_full | Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides |
title_fullStr | Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides |
title_full_unstemmed | Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides |
title_short | Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides |
title_sort | cobalt catalyzed ortho arylation of aromatic imines with aryl chlorides |
url | https://hdl.handle.net/10356/97232 http://hdl.handle.net/10220/10610 |
work_keys_str_mv | AT gaoke cobaltcatalyzedorthoarylationofaromaticimineswitharylchlorides AT leepinsheng cobaltcatalyzedorthoarylationofaromaticimineswitharylchlorides AT longchong cobaltcatalyzedorthoarylationofaromaticimineswitharylchlorides AT yoshikainaohiko cobaltcatalyzedorthoarylationofaromaticimineswitharylchlorides |