High-density metallic nanogaps fabricated on solid substrates used for surface enhanced Raman scattering

The Raman signal of adsorbed molecules can be significantly enhanced by utilizing metallic structures with high-density Raman hot spots used as surface enhanced Raman scattering (SERS) substrates. In this work, we develop a simple, convenient and tunable method to fabricate high-density Ag or Au nan...

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Main Authors: Lu, Gang, Li, Hai, Wu, Shixin, Chen, Peng, Zhang, Hua
Other Authors: School of Materials Science & Engineering
Format: Journal Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/97560
http://hdl.handle.net/10220/10687
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author Lu, Gang
Li, Hai
Wu, Shixin
Chen, Peng
Zhang, Hua
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Lu, Gang
Li, Hai
Wu, Shixin
Chen, Peng
Zhang, Hua
author_sort Lu, Gang
collection NTU
description The Raman signal of adsorbed molecules can be significantly enhanced by utilizing metallic structures with high-density Raman hot spots used as surface enhanced Raman scattering (SERS) substrates. In this work, we develop a simple, convenient and tunable method to fabricate high-density Ag or Au nanogaps on Si wafers. These nanogaps can serve as Raman hot spots, leading to dramatic enhancement of the Raman signal. The high-density nanogaps can be formed by repeating the electroless deposition of Ag NPs (or Au NPs) and coating of p-aminothiophenol (PATP, a Raman probe) on the deposited Ag NPs (or Au NPs) through the self-assembly process. After removal of PATP by O2 plasma, the as-fabricated SERS substrate can be reused for the detection of other molecules.
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spelling ntu-10356/975602020-06-01T10:13:41Z High-density metallic nanogaps fabricated on solid substrates used for surface enhanced Raman scattering Lu, Gang Li, Hai Wu, Shixin Chen, Peng Zhang, Hua School of Materials Science & Engineering Centre for Biomimetic Sensor Science The Raman signal of adsorbed molecules can be significantly enhanced by utilizing metallic structures with high-density Raman hot spots used as surface enhanced Raman scattering (SERS) substrates. In this work, we develop a simple, convenient and tunable method to fabricate high-density Ag or Au nanogaps on Si wafers. These nanogaps can serve as Raman hot spots, leading to dramatic enhancement of the Raman signal. The high-density nanogaps can be formed by repeating the electroless deposition of Ag NPs (or Au NPs) and coating of p-aminothiophenol (PATP, a Raman probe) on the deposited Ag NPs (or Au NPs) through the self-assembly process. After removal of PATP by O2 plasma, the as-fabricated SERS substrate can be reused for the detection of other molecules. 2013-06-26T02:30:48Z 2019-12-06T19:44:04Z 2013-06-26T02:30:48Z 2019-12-06T19:44:04Z 2012 2012 Journal Article Lu, G., Li, H., Wu, S., Chen, P., & Zhang, H. (2012). High-density metallic nanogaps fabricated on solid substrates used for surface enhanced Raman scattering. Nanoscale, 4(3), 860-863. 2040-3364 https://hdl.handle.net/10356/97560 http://hdl.handle.net/10220/10687 10.1039/c1nr10997a en Nanoscale © 2012 The Royal Society of Chemistry.
spellingShingle Lu, Gang
Li, Hai
Wu, Shixin
Chen, Peng
Zhang, Hua
High-density metallic nanogaps fabricated on solid substrates used for surface enhanced Raman scattering
title High-density metallic nanogaps fabricated on solid substrates used for surface enhanced Raman scattering
title_full High-density metallic nanogaps fabricated on solid substrates used for surface enhanced Raman scattering
title_fullStr High-density metallic nanogaps fabricated on solid substrates used for surface enhanced Raman scattering
title_full_unstemmed High-density metallic nanogaps fabricated on solid substrates used for surface enhanced Raman scattering
title_short High-density metallic nanogaps fabricated on solid substrates used for surface enhanced Raman scattering
title_sort high density metallic nanogaps fabricated on solid substrates used for surface enhanced raman scattering
url https://hdl.handle.net/10356/97560
http://hdl.handle.net/10220/10687
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AT chenpeng highdensitymetallicnanogapsfabricatedonsolidsubstratesusedforsurfaceenhancedramanscattering
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