Thermally treated 3-D nanostructured graphene-supported Pd catalyst for significantly improved electrocatalytic performance towards ethanol electrooxidation
Catalyst supports are known to play a critical role in high catalytic performance. A novel nanostructured graphene was obtained by facile thermal treatment of the three-dimensional (3-D) graphene material. X-ray diffraction (XRD), scanning electron microscopy (SEM) and nitrogen adsorption results re...
| Main Authors: | , , , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
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| Online Access: | https://hdl.handle.net/10356/98172 http://hdl.handle.net/10220/17274 |
| _version_ | 1811690164392558592 |
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| author | Wu, Li Juan Wang, Yi Wang, Yan Ping Du, Xuan Wang, Fang Gao, Yi Ying Qi, Tao Li, Chang Ming |
| author2 | School of Chemical and Biomedical Engineering |
| author_facet | School of Chemical and Biomedical Engineering Wu, Li Juan Wang, Yi Wang, Yan Ping Du, Xuan Wang, Fang Gao, Yi Ying Qi, Tao Li, Chang Ming |
| author_sort | Wu, Li Juan |
| collection | NTU |
| description | Catalyst supports are known to play a critical role in high catalytic performance. A novel nanostructured graphene was obtained by facile thermal treatment of the three-dimensional (3-D) graphene material. X-ray diffraction (XRD), scanning electron microscopy (SEM) and nitrogen adsorption results reveal that the new material is composed of smaller and looser graphene nanosheets, and possesses an ultrahigh specific surface area, large pore volume and rich 3-D interconnected macropores and mesopores. The material was further used to support a Pd catalyst towards ethanol electrooxidation in alkaline media, demonstrating much better electrocatalytic activity in respect of the Pd utility ratio, onset potential and peak current density than that of pristine 3-D graphene material and carbon black, the most popular catalyst support, and thus rendering a promising catalyst support material for fuel cells. |
| first_indexed | 2024-10-01T05:59:39Z |
| format | Journal Article |
| id | ntu-10356/98172 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T05:59:39Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/981722020-03-07T11:35:38Z Thermally treated 3-D nanostructured graphene-supported Pd catalyst for significantly improved electrocatalytic performance towards ethanol electrooxidation Wu, Li Juan Wang, Yi Wang, Yan Ping Du, Xuan Wang, Fang Gao, Yi Ying Qi, Tao Li, Chang Ming School of Chemical and Biomedical Engineering Catalyst supports are known to play a critical role in high catalytic performance. A novel nanostructured graphene was obtained by facile thermal treatment of the three-dimensional (3-D) graphene material. X-ray diffraction (XRD), scanning electron microscopy (SEM) and nitrogen adsorption results reveal that the new material is composed of smaller and looser graphene nanosheets, and possesses an ultrahigh specific surface area, large pore volume and rich 3-D interconnected macropores and mesopores. The material was further used to support a Pd catalyst towards ethanol electrooxidation in alkaline media, demonstrating much better electrocatalytic activity in respect of the Pd utility ratio, onset potential and peak current density than that of pristine 3-D graphene material and carbon black, the most popular catalyst support, and thus rendering a promising catalyst support material for fuel cells. 2013-11-05T05:54:03Z 2019-12-06T19:51:45Z 2013-11-05T05:54:03Z 2019-12-06T19:51:45Z 2013 2013 Journal Article Wu, L. J., Wang, Y., Wang, Y. P., Du, X., Wang, F., Gao, Y. Y., et al. (2013). Thermally treated 3-D nanostructured graphene-supported Pd catalyst for significantly improved electrocatalytic performance towards ethanol electrooxidation. RSC Advances, 3(15), 5196-5203. https://hdl.handle.net/10356/98172 http://hdl.handle.net/10220/17274 10.1039/c3ra23091k en RSC advances |
| spellingShingle | Wu, Li Juan Wang, Yi Wang, Yan Ping Du, Xuan Wang, Fang Gao, Yi Ying Qi, Tao Li, Chang Ming Thermally treated 3-D nanostructured graphene-supported Pd catalyst for significantly improved electrocatalytic performance towards ethanol electrooxidation |
| title | Thermally treated 3-D nanostructured graphene-supported Pd catalyst for significantly improved electrocatalytic performance towards ethanol electrooxidation |
| title_full | Thermally treated 3-D nanostructured graphene-supported Pd catalyst for significantly improved electrocatalytic performance towards ethanol electrooxidation |
| title_fullStr | Thermally treated 3-D nanostructured graphene-supported Pd catalyst for significantly improved electrocatalytic performance towards ethanol electrooxidation |
| title_full_unstemmed | Thermally treated 3-D nanostructured graphene-supported Pd catalyst for significantly improved electrocatalytic performance towards ethanol electrooxidation |
| title_short | Thermally treated 3-D nanostructured graphene-supported Pd catalyst for significantly improved electrocatalytic performance towards ethanol electrooxidation |
| title_sort | thermally treated 3 d nanostructured graphene supported pd catalyst for significantly improved electrocatalytic performance towards ethanol electrooxidation |
| url | https://hdl.handle.net/10356/98172 http://hdl.handle.net/10220/17274 |
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