Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester
Cascades: An InBr3-catalyzed intermolecular polyene cyclization initiated by a Prins reaction provides a concise approach to 3-oxaterpenoid derivatives. The reaction is compatible with various aldehydes, ketones, and polyolefin–alcohol substrates. In addition, the total synthesis of (±)-moluccanic a...
| Main Authors: | , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/98455 http://hdl.handle.net/10220/12483 |
| _version_ | 1826114819467509760 |
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| author | Li, Bin Lai, Yin-Chang Zhao, Yujun Wong, Yiu-Hang Shen, Zhi-Liang Loh, Teck-Peng |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Li, Bin Lai, Yin-Chang Zhao, Yujun Wong, Yiu-Hang Shen, Zhi-Liang Loh, Teck-Peng |
| author_sort | Li, Bin |
| collection | NTU |
| description | Cascades: An InBr3-catalyzed intermolecular polyene cyclization initiated by a Prins reaction provides a concise approach to 3-oxaterpenoid derivatives. The reaction is compatible with various aldehydes, ketones, and polyolefin–alcohol substrates. In addition, the total synthesis of (±)-moluccanic acid methyl ester was achieved in seven steps by using such a Prins–polyene cyclization as the key step. |
| first_indexed | 2024-10-01T03:45:24Z |
| format | Journal Article |
| id | ntu-10356/98455 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:45:24Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/984552020-03-07T12:34:47Z Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester Li, Bin Lai, Yin-Chang Zhao, Yujun Wong, Yiu-Hang Shen, Zhi-Liang Loh, Teck-Peng School of Physical and Mathematical Sciences DRNTU::Science::Chemistry Cascades: An InBr3-catalyzed intermolecular polyene cyclization initiated by a Prins reaction provides a concise approach to 3-oxaterpenoid derivatives. The reaction is compatible with various aldehydes, ketones, and polyolefin–alcohol substrates. In addition, the total synthesis of (±)-moluccanic acid methyl ester was achieved in seven steps by using such a Prins–polyene cyclization as the key step. 2013-07-29T07:21:19Z 2019-12-06T19:55:24Z 2013-07-29T07:21:19Z 2019-12-06T19:55:24Z 2012 2012 Journal Article Li, B., Lai, Y.-C., Zhao, Y., Wong, Y.-H., Shen, Z.-L., & Loh, T.-P. (2012). Synthesis of 3-Oxaterpenoids and Its Application in the Total Synthesis of (±)-Moluccanic Acid Methyl Ester. Angewandte Chemie International Edition, 51(42), 10619-10623. 1433-7851 https://hdl.handle.net/10356/98455 http://hdl.handle.net/10220/12483 10.1002/anie.201205981 en Angewandte chemie international edition © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| spellingShingle | DRNTU::Science::Chemistry Li, Bin Lai, Yin-Chang Zhao, Yujun Wong, Yiu-Hang Shen, Zhi-Liang Loh, Teck-Peng Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester |
| title | Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester |
| title_full | Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester |
| title_fullStr | Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester |
| title_full_unstemmed | Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester |
| title_short | Synthesis of 3-Oxaterpenoids and its application in the total synthesis of (±)-moluccanic acid methyl ester |
| title_sort | synthesis of 3 oxaterpenoids and its application in the total synthesis of moluccanic acid methyl ester |
| topic | DRNTU::Science::Chemistry |
| url | https://hdl.handle.net/10356/98455 http://hdl.handle.net/10220/12483 |
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