New thioether–dithiolate complexes of Cp∗Ir and some reactivity features
The reaction of [Cp∗IrCl2]2 (Cp* = η5 − C5Me5) with the tridentate 3-thiapentane-1,5-dithiolate ligand, S(CH2CH2S−)2 (tpdt), led to the formation of [Cp∗Ir(η3 − tpdt)] (1) in 81% isolated yield. Subsequent reactions of 1 with [Cp∗IrCl2]2 in 2:1 and 1:1 molar equiv ratios resulted in the formation of...
| Main Authors: | , , , |
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| Format: | Journal Article |
| Language: | English |
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2013
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| Online Access: | https://hdl.handle.net/10356/98546 http://hdl.handle.net/10220/17150 |
| _version_ | 1811682085273862144 |
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| author | Xu, Chang Li, Yongxin Goh, Lai Yoong Pullarkat, Sumod A. |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Xu, Chang Li, Yongxin Goh, Lai Yoong Pullarkat, Sumod A. |
| author_sort | Xu, Chang |
| collection | NTU |
| description | The reaction of [Cp∗IrCl2]2 (Cp* = η5 − C5Me5) with the tridentate 3-thiapentane-1,5-dithiolate ligand, S(CH2CH2S−)2 (tpdt), led to the formation of [Cp∗Ir(η3 − tpdt)] (1) in 81% isolated yield. Subsequent reactions of 1 with [Cp∗IrCl2]2 in 2:1 and 1:1 molar equiv ratios resulted in the formation of [Cp∗Ir(μ − η2:η3 − tpdt)Cp∗IrCl][PF6] (2) and [Cp∗Irμ − η2:η3 − tpdt)Cp∗IrCl][Cp∗IrCl3] (3) in 86 and 79% yields, respectively, based on 1, whereas the reactions of 1 with [(COD)IrCl]2 (COD = 1,5-cyclooctadiene) in 2:1 and 1:1 molar equiv ratios resulted in the formation of the homo-bimetallic derivatives Cp∗Ir(μ − η1:η3 − tpdt)(COD)IrCl (4) (92% yield) and [Cp∗Ir(μ − η2:η3 − tpdt)(COD)Ir] [(COD)IrCl2] (5) (82% yield). Reactions between 1 and [(COD)RhCl]2, yielded the hetero-bimetallic derivatives Cp∗Ir(μ − η1:η3 − tpdt)(COD)RhCl (6) and [Cp∗Ir(μ − η2:η3 − tpdt)(COD)Rh][(COD)RhCl2] (7), in 92 and 93% yields, respectively. The reaction of 1 with methyl iodide gave mono-methylated derivative [Cp∗Ir(η3-C4H8S3Me)]I (8) (93% yield). All these compounds have been comprehensively characterized. |
| first_indexed | 2024-10-01T03:51:14Z |
| format | Journal Article |
| id | ntu-10356/98546 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T03:51:14Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/985462020-03-07T12:34:47Z New thioether–dithiolate complexes of Cp∗Ir and some reactivity features Xu, Chang Li, Yongxin Goh, Lai Yoong Pullarkat, Sumod A. School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds The reaction of [Cp∗IrCl2]2 (Cp* = η5 − C5Me5) with the tridentate 3-thiapentane-1,5-dithiolate ligand, S(CH2CH2S−)2 (tpdt), led to the formation of [Cp∗Ir(η3 − tpdt)] (1) in 81% isolated yield. Subsequent reactions of 1 with [Cp∗IrCl2]2 in 2:1 and 1:1 molar equiv ratios resulted in the formation of [Cp∗Ir(μ − η2:η3 − tpdt)Cp∗IrCl][PF6] (2) and [Cp∗Irμ − η2:η3 − tpdt)Cp∗IrCl][Cp∗IrCl3] (3) in 86 and 79% yields, respectively, based on 1, whereas the reactions of 1 with [(COD)IrCl]2 (COD = 1,5-cyclooctadiene) in 2:1 and 1:1 molar equiv ratios resulted in the formation of the homo-bimetallic derivatives Cp∗Ir(μ − η1:η3 − tpdt)(COD)IrCl (4) (92% yield) and [Cp∗Ir(μ − η2:η3 − tpdt)(COD)Ir] [(COD)IrCl2] (5) (82% yield). Reactions between 1 and [(COD)RhCl]2, yielded the hetero-bimetallic derivatives Cp∗Ir(μ − η1:η3 − tpdt)(COD)RhCl (6) and [Cp∗Ir(μ − η2:η3 − tpdt)(COD)Rh][(COD)RhCl2] (7), in 92 and 93% yields, respectively. The reaction of 1 with methyl iodide gave mono-methylated derivative [Cp∗Ir(η3-C4H8S3Me)]I (8) (93% yield). All these compounds have been comprehensively characterized. 2013-10-31T07:31:15Z 2019-12-06T19:56:42Z 2013-10-31T07:31:15Z 2019-12-06T19:56:42Z 2012 2012 Journal Article Xu, C., Li, Y., Goh, L. Y., & Pullarkat, S. A. (2012). New thioether–dithiolate complexes of Cp∗Ir and some reactivity features. Journal of organometallic chemistry, 696(26), 4207-4214. 0022-328X https://hdl.handle.net/10356/98546 http://hdl.handle.net/10220/17150 10.1016/j.jorganchem.2011.09.012 en Journal of organometallic chemistry |
| spellingShingle | DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds Xu, Chang Li, Yongxin Goh, Lai Yoong Pullarkat, Sumod A. New thioether–dithiolate complexes of Cp∗Ir and some reactivity features |
| title | New thioether–dithiolate complexes of Cp∗Ir and some reactivity features |
| title_full | New thioether–dithiolate complexes of Cp∗Ir and some reactivity features |
| title_fullStr | New thioether–dithiolate complexes of Cp∗Ir and some reactivity features |
| title_full_unstemmed | New thioether–dithiolate complexes of Cp∗Ir and some reactivity features |
| title_short | New thioether–dithiolate complexes of Cp∗Ir and some reactivity features |
| title_sort | new thioether dithiolate complexes of cp∗ir and some reactivity features |
| topic | DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds |
| url | https://hdl.handle.net/10356/98546 http://hdl.handle.net/10220/17150 |
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