New thioether–dithiolate complexes of Cp∗Ir and some reactivity features
The reaction of [Cp∗IrCl2]2 (Cp* = η5 − C5Me5) with the tridentate 3-thiapentane-1,5-dithiolate ligand, S(CH2CH2S−)2 (tpdt), led to the formation of [Cp∗Ir(η3 − tpdt)] (1) in 81% isolated yield. Subsequent reactions of 1 with [Cp∗IrCl2]2 in 2:1 and 1:1 molar equiv ratios resulted in the formation of...
Main Authors: | Xu, Chang, Li, Yongxin, Goh, Lai Yoong, Pullarkat, Sumod A. |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Journal Article |
Language: | English |
Published: |
2013
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/98546 http://hdl.handle.net/10220/17150 |
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