Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols
Triflimide (Tf2NH) specifically catalyzed reactions of alcohols and vinyl azides, enabling efficient construction of amides with C–C bond formation through nucleophilic attack of vinyl azides onto the putative carbocation intermediates derived from alcohols are described.
| Main Authors: | , , |
|---|---|
| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2015
|
| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/98598 http://hdl.handle.net/10220/38585 |
| _version_ | 1826129116596797440 |
|---|---|
| author | Zhang, Feng-Lian Zhu, Xu Chiba, Shunsuke |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Zhang, Feng-Lian Zhu, Xu Chiba, Shunsuke |
| author_sort | Zhang, Feng-Lian |
| collection | NTU |
| description | Triflimide (Tf2NH) specifically catalyzed reactions of alcohols and vinyl azides, enabling efficient construction of amides with C–C bond formation through nucleophilic attack of vinyl azides onto the putative carbocation intermediates derived from alcohols are described. |
| first_indexed | 2024-10-01T07:35:27Z |
| format | Journal Article |
| id | ntu-10356/98598 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T07:35:27Z |
| publishDate | 2015 |
| record_format | dspace |
| spelling | ntu-10356/985982023-02-28T19:22:27Z Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols Zhang, Feng-Lian Zhu, Xu Chiba, Shunsuke School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry Triflimide (Tf2NH) specifically catalyzed reactions of alcohols and vinyl azides, enabling efficient construction of amides with C–C bond formation through nucleophilic attack of vinyl azides onto the putative carbocation intermediates derived from alcohols are described. MOE (Min. of Education, S’pore) Accepted version 2015-09-04T04:15:10Z 2019-12-06T19:57:17Z 2015-09-04T04:15:10Z 2019-12-06T19:57:17Z 2015 2015 Journal Article Zhang, F.-L., Zhu, X., & Chiba, S. (2015). Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols. Organic Letters, 17(12), 3138-3141. 1523-7060 https://hdl.handle.net/10356/98598 http://hdl.handle.net/10220/38585 10.1021/acs.orglett.5b01458 en Organic letters © 2015 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Organic Letters, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/acs.orglett.5b01458]. 4 p. application/pdf |
| spellingShingle | DRNTU::Science::Chemistry::Organic chemistry Zhang, Feng-Lian Zhu, Xu Chiba, Shunsuke Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols |
| title | Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols |
| title_full | Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols |
| title_fullStr | Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols |
| title_full_unstemmed | Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols |
| title_short | Tf 2 NH-catalyzed amide synthesis from vinyl azides and alcohols |
| title_sort | tf 2 nh catalyzed amide synthesis from vinyl azides and alcohols |
| topic | DRNTU::Science::Chemistry::Organic chemistry |
| url | https://hdl.handle.net/10356/98598 http://hdl.handle.net/10220/38585 |
| work_keys_str_mv | AT zhangfenglian tf2nhcatalyzedamidesynthesisfromvinylazidesandalcohols AT zhuxu tf2nhcatalyzedamidesynthesisfromvinylazidesandalcohols AT chibashunsuke tf2nhcatalyzedamidesynthesisfromvinylazidesandalcohols |