A family of metal-organic frameworks exhibiting size-selective catalysis with encapsulated noble-metal nanoparticles
The encapsulation of noble-metal nanoparticles (NPs) in metal-organic frameworks (MOFs) with carboxylic acid ligands, the most extensive branch of the MOF family, gives NP/MOF composites that exhibit excellent shape-selective catalytic performance in olefin hydrogenation, aqueous reaction in the red...
Main Authors: | , , , , , , , , , |
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Format: | Journal Article |
Language: | English |
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2014
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Online Access: | https://hdl.handle.net/10356/98952 http://hdl.handle.net/10220/19622 |
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author | Zhang, Weina Lu, Guang Cui, Chenlong Liu, Yayuan Li, Shaozhou Yan, Wenjin Xing, Chong Chi, Robin Yonggui Yang, Yanhui Huo, Fengwei |
author2 | School of Chemical and Biomedical Engineering |
author_facet | School of Chemical and Biomedical Engineering Zhang, Weina Lu, Guang Cui, Chenlong Liu, Yayuan Li, Shaozhou Yan, Wenjin Xing, Chong Chi, Robin Yonggui Yang, Yanhui Huo, Fengwei |
author_sort | Zhang, Weina |
collection | NTU |
description | The encapsulation of noble-metal nanoparticles (NPs) in metal-organic frameworks (MOFs) with carboxylic acid ligands, the most extensive branch of the MOF family, gives NP/MOF composites that exhibit excellent shape-selective catalytic performance in olefin hydrogenation, aqueous reaction in the reduction of 4-nitrophenol, and faster molecular diffusion in CO oxidation. The strategy of using functionalized cavities of MOFs as hosts for different metal NPs looks promising for the development of high-performance heterogeneous catalysts. |
first_indexed | 2024-10-01T05:21:11Z |
format | Journal Article |
id | ntu-10356/98952 |
institution | Nanyang Technological University |
language | English |
last_indexed | 2024-10-01T05:21:11Z |
publishDate | 2014 |
record_format | dspace |
spelling | ntu-10356/989522020-06-01T10:13:35Z A family of metal-organic frameworks exhibiting size-selective catalysis with encapsulated noble-metal nanoparticles Zhang, Weina Lu, Guang Cui, Chenlong Liu, Yayuan Li, Shaozhou Yan, Wenjin Xing, Chong Chi, Robin Yonggui Yang, Yanhui Huo, Fengwei School of Chemical and Biomedical Engineering School of Materials Science & Engineering School of Physical and Mathematical Sciences DRNTU::Engineering::Chemical engineering::Chemical processes The encapsulation of noble-metal nanoparticles (NPs) in metal-organic frameworks (MOFs) with carboxylic acid ligands, the most extensive branch of the MOF family, gives NP/MOF composites that exhibit excellent shape-selective catalytic performance in olefin hydrogenation, aqueous reaction in the reduction of 4-nitrophenol, and faster molecular diffusion in CO oxidation. The strategy of using functionalized cavities of MOFs as hosts for different metal NPs looks promising for the development of high-performance heterogeneous catalysts. 2014-06-10T06:14:46Z 2019-12-06T20:01:26Z 2014-06-10T06:14:46Z 2019-12-06T20:01:26Z 2014 2014 Journal Article Zhang, W., Lu, G., Cui, C., Liu, Y., Li, S., Yan, W., et al. (2014). A Family of Metal-Organic Frameworks Exhibiting Size-Selective Catalysis with Encapsulated Noble-Metal Nanoparticles. Advanced Materials, in press. 0935-9648 https://hdl.handle.net/10356/98952 http://hdl.handle.net/10220/19622 10.1002/adma.201400620 en Advanced materials © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
spellingShingle | DRNTU::Engineering::Chemical engineering::Chemical processes Zhang, Weina Lu, Guang Cui, Chenlong Liu, Yayuan Li, Shaozhou Yan, Wenjin Xing, Chong Chi, Robin Yonggui Yang, Yanhui Huo, Fengwei A family of metal-organic frameworks exhibiting size-selective catalysis with encapsulated noble-metal nanoparticles |
title | A family of metal-organic frameworks exhibiting size-selective catalysis with encapsulated noble-metal nanoparticles |
title_full | A family of metal-organic frameworks exhibiting size-selective catalysis with encapsulated noble-metal nanoparticles |
title_fullStr | A family of metal-organic frameworks exhibiting size-selective catalysis with encapsulated noble-metal nanoparticles |
title_full_unstemmed | A family of metal-organic frameworks exhibiting size-selective catalysis with encapsulated noble-metal nanoparticles |
title_short | A family of metal-organic frameworks exhibiting size-selective catalysis with encapsulated noble-metal nanoparticles |
title_sort | family of metal organic frameworks exhibiting size selective catalysis with encapsulated noble metal nanoparticles |
topic | DRNTU::Engineering::Chemical engineering::Chemical processes |
url | https://hdl.handle.net/10356/98952 http://hdl.handle.net/10220/19622 |
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