Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization

High octane: A novel and practical syntheses of 8-oxabicyclo[3.2.1]octanes using a cationic cascade cyclization reaction has been developed (see scheme; TIPS=triisopropylsilyl). The diastereomer of the cyclization product isolated depends upon whether the acetal or aldehyde substrate is used.

Bibliographic Details
Main Authors: Li, Bin, Zhao, Yu-Jun, Lai, Yin-Chang, Loh, Teck-Peng
Other Authors: School of Physical and Mathematical Sciences
Format: Journal Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/99014
http://hdl.handle.net/10220/12443
_version_ 1811695925558509568
author Li, Bin
Zhao, Yu-Jun
Lai, Yin-Chang
Loh, Teck-Peng
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Li, Bin
Zhao, Yu-Jun
Lai, Yin-Chang
Loh, Teck-Peng
author_sort Li, Bin
collection NTU
description High octane: A novel and practical syntheses of 8-oxabicyclo[3.2.1]octanes using a cationic cascade cyclization reaction has been developed (see scheme; TIPS=triisopropylsilyl). The diastereomer of the cyclization product isolated depends upon whether the acetal or aldehyde substrate is used.
first_indexed 2024-10-01T07:31:13Z
format Journal Article
id ntu-10356/99014
institution Nanyang Technological University
language English
last_indexed 2024-10-01T07:31:13Z
publishDate 2013
record_format dspace
spelling ntu-10356/990142020-03-07T12:34:45Z Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization Li, Bin Zhao, Yu-Jun Lai, Yin-Chang Loh, Teck-Peng School of Physical and Mathematical Sciences High octane: A novel and practical syntheses of 8-oxabicyclo[3.2.1]octanes using a cationic cascade cyclization reaction has been developed (see scheme; TIPS=triisopropylsilyl). The diastereomer of the cyclization product isolated depends upon whether the acetal or aldehyde substrate is used. 2013-07-29T04:41:17Z 2019-12-06T20:02:20Z 2013-07-29T04:41:17Z 2019-12-06T20:02:20Z 2012 2012 Journal Article Li, B., Zhao, Y.-J., Lai, Y.-C., & Loh, T.-P. (2012). Asymmetric Syntheses of 8-Oxabicyclo[3,2,1]octanes: A Cationic Cascade Cyclization. Angewandte Chemie International Edition, 51(32), 8041-8045. 1433-7851 https://hdl.handle.net/10356/99014 http://hdl.handle.net/10220/12443 10.1002/anie.201202699 en Angewandte chemie international edition © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
spellingShingle Li, Bin
Zhao, Yu-Jun
Lai, Yin-Chang
Loh, Teck-Peng
Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization
title Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization
title_full Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization
title_fullStr Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization
title_full_unstemmed Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization
title_short Asymmetric syntheses of 8-oxabicyclo[3,2,1]octanes : a cationic cascade cyclization
title_sort asymmetric syntheses of 8 oxabicyclo 3 2 1 octanes a cationic cascade cyclization
url https://hdl.handle.net/10356/99014
http://hdl.handle.net/10220/12443
work_keys_str_mv AT libin asymmetricsynthesesof8oxabicyclo321octanesacationiccascadecyclization
AT zhaoyujun asymmetricsynthesesof8oxabicyclo321octanesacationiccascadecyclization
AT laiyinchang asymmetricsynthesesof8oxabicyclo321octanesacationiccascadecyclization
AT lohteckpeng asymmetricsynthesesof8oxabicyclo321octanesacationiccascadecyclization