Locking high energy 1D chain of dichloromethane molecules containing abnormally short Cl⋯Cl contacts of 2.524 Å inside organic crystals
1D helical channels can be created by “sticky” end-mediated formation of 1D helical stacks composed of short cavity-containing helices and are able to host 1D chains of dichloromethane molecules containing extraordinarily short intermolecular Cl⋯Cl contacts of 2.524 Å in length that computationally...
| Main Authors: | , , , , , , , , , |
|---|---|
| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
|
| Online Access: | https://hdl.handle.net/10356/99033 http://hdl.handle.net/10220/17239 |
| Summary: | 1D helical channels can be created by “sticky” end-mediated formation of 1D helical stacks composed of short cavity-containing helices and are able to host 1D chains of dichloromethane molecules containing extraordinarily short intermolecular Cl⋯Cl contacts of 2.524 Å in length that computationally destabilize the host–guest complex by 14.94 kcal mol^−1. |
|---|