Nanostructure effect of V2O5 buffer layer on performance of polymer-fullerene devices

Nanostructure of solar cell materials is often essential for the device performance. V2O5 nanobelt structure is synthesized with a solution process and further used as an anode buffer layer in polymer solar cells, resulting insignificantly improved power conversion efficiency (PCE of 2.71%) much hig...

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Main Authors: Gong, Cheng, Yang, Hongbin, Song, Qun Liang, Li, Chang Ming
Other Authors: School of Chemical and Biomedical Engineering
Format: Journal Article
Language:English
Published: 2013
Subjects:
Online Access:https://hdl.handle.net/10356/99234
http://hdl.handle.net/10220/17175
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author Gong, Cheng
Yang, Hongbin
Song, Qun Liang
Li, Chang Ming
author2 School of Chemical and Biomedical Engineering
author_facet School of Chemical and Biomedical Engineering
Gong, Cheng
Yang, Hongbin
Song, Qun Liang
Li, Chang Ming
author_sort Gong, Cheng
collection NTU
description Nanostructure of solar cell materials is often essential for the device performance. V2O5 nanobelt structure is synthesized with a solution process and further used as an anode buffer layer in polymer solar cells, resulting insignificantly improved power conversion efficiency (PCE of 2.71%) much higher than that of devices without the buffer layer (PCE of 0.14%) or with V2O5 powder as the buffer layer (1.08%). X-ray diffraction (XRD) results indicate that the V2O5 nanobelt structure has better phase separation while providing higher surface area for the P3HT:PCBM active layer to enhance photocurrent. The measured impedance spectrums show that the V2O5 nanobelt structure has faster charge transport than the powder material. This work clearly demonstrates that V2O5 nanobelt has great potential as a substitute of the conventionally used PEDOT-PSS buffer layer for high performance devices.
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spelling ntu-10356/992342020-03-07T11:35:26Z Nanostructure effect of V2O5 buffer layer on performance of polymer-fullerene devices Gong, Cheng Yang, Hongbin Song, Qun Liang Li, Chang Ming School of Chemical and Biomedical Engineering Centre for Advanced Bionanosystems DRNTU::Engineering::Chemical engineering Nanostructure of solar cell materials is often essential for the device performance. V2O5 nanobelt structure is synthesized with a solution process and further used as an anode buffer layer in polymer solar cells, resulting insignificantly improved power conversion efficiency (PCE of 2.71%) much higher than that of devices without the buffer layer (PCE of 0.14%) or with V2O5 powder as the buffer layer (1.08%). X-ray diffraction (XRD) results indicate that the V2O5 nanobelt structure has better phase separation while providing higher surface area for the P3HT:PCBM active layer to enhance photocurrent. The measured impedance spectrums show that the V2O5 nanobelt structure has faster charge transport than the powder material. This work clearly demonstrates that V2O5 nanobelt has great potential as a substitute of the conventionally used PEDOT-PSS buffer layer for high performance devices. 2013-10-31T08:43:48Z 2019-12-06T20:04:55Z 2013-10-31T08:43:48Z 2019-12-06T20:04:55Z 2011 2011 Journal Article Gong, C., Yang, H. B., Song, Q. L., & Li, C. M. (2011). Nanostructure effect of V2O5 buffer layer on performance of polymer-fullerene devices. Organic electronics, 13(1), 7-12. 1566-1199 https://hdl.handle.net/10356/99234 http://hdl.handle.net/10220/17175 10.1016/j.orgel.2011.10.006 en Organic electronics
spellingShingle DRNTU::Engineering::Chemical engineering
Gong, Cheng
Yang, Hongbin
Song, Qun Liang
Li, Chang Ming
Nanostructure effect of V2O5 buffer layer on performance of polymer-fullerene devices
title Nanostructure effect of V2O5 buffer layer on performance of polymer-fullerene devices
title_full Nanostructure effect of V2O5 buffer layer on performance of polymer-fullerene devices
title_fullStr Nanostructure effect of V2O5 buffer layer on performance of polymer-fullerene devices
title_full_unstemmed Nanostructure effect of V2O5 buffer layer on performance of polymer-fullerene devices
title_short Nanostructure effect of V2O5 buffer layer on performance of polymer-fullerene devices
title_sort nanostructure effect of v2o5 buffer layer on performance of polymer fullerene devices
topic DRNTU::Engineering::Chemical engineering
url https://hdl.handle.net/10356/99234
http://hdl.handle.net/10220/17175
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AT yanghongbin nanostructureeffectofv2o5bufferlayeronperformanceofpolymerfullerenedevices
AT songqunliang nanostructureeffectofv2o5bufferlayeronperformanceofpolymerfullerenedevices
AT lichangming nanostructureeffectofv2o5bufferlayeronperformanceofpolymerfullerenedevices