A contribution to the direct observation of transient phosphanylidene complexes [RP=W(CO)5] (R: Me, Ph) : a revisited approach to their electronic structure by UV-photoelectron spectroscopy
An original approach involving a coupling in the gas phase between flash vacuum thermolysis (FVT) and UV-photoelectron spectroscopy (UV-PES) allowed the transient terminal electrophilic phosphanylidene complex [MeP=W(CO)5] to be characterized; this is the first direct observation of this P–Me deriva...
Main Authors: | Labat, Stéphane, Miqueu, Karinne, Sotiropoulos, Jean-Marc, Baylère, Patrick, Pfister-Guillouzo, Geneviève, Huy, Ngoc Hoa Tran, Mathey, François |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Journal Article |
Language: | English |
Published: |
2014
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/99273 http://hdl.handle.net/10220/19628 |
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