Growth and characterization of bamboo-shaped carbon nanotubes using nanocluster-assembled ZnO:Co thin films as catalyst

Bamboo-shaped carbon nanotubes (CNTs) had been successfully fabricated by a plasma enhanced chemical vapor deposition method, in which nanocluster-assembled ZnO:Co thin film was used as catalyst. It was found that bamboo-shaped CNTs were generally grown in a direction perpendicularly to the substrat...

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Main Authors: Tay, Beng Kang, Zhao, Z. W., Lei, W., Zhang, X. B., Chen, J. S.
Other Authors: School of Electrical and Electronic Engineering
Format: Journal Article
Language:English
Published: 2013
Subjects:
Online Access:https://hdl.handle.net/10356/99612
http://hdl.handle.net/10220/13643
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author Tay, Beng Kang
Zhao, Z. W.
Lei, W.
Zhang, X. B.
Chen, J. S.
author2 School of Electrical and Electronic Engineering
author_facet School of Electrical and Electronic Engineering
Tay, Beng Kang
Zhao, Z. W.
Lei, W.
Zhang, X. B.
Chen, J. S.
author_sort Tay, Beng Kang
collection NTU
description Bamboo-shaped carbon nanotubes (CNTs) had been successfully fabricated by a plasma enhanced chemical vapor deposition method, in which nanocluster-assembled ZnO:Co thin film was used as catalyst. It was found that bamboo-shaped CNTs were generally grown in a direction perpendicularly to the substrate surface with the tops of CNTs dominated by the droplet-like catalyst covered by the carbon layer. The diameter of CNTs was ranged from 20–50 nm. High resolution of TEM image showed that the typical CNT had a multi-walled structure with an inner core presented. The ordered graphite layers were inclined to an axis of CNT about 18° and the interlayer space of a CNT was about 0.35 nm. Two peaks in Raman spectrum at 1586 cm−1 and 1372 cm−1 were identified as G-band and D-band for graphite, respectively. The results showed that catalyst based on ZnO:Co thin films could be used for the growth of CNTs with bamboo-shaped structure.
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spelling ntu-10356/996122020-03-07T14:00:31Z Growth and characterization of bamboo-shaped carbon nanotubes using nanocluster-assembled ZnO:Co thin films as catalyst Tay, Beng Kang Zhao, Z. W. Lei, W. Zhang, X. B. Chen, J. S. School of Electrical and Electronic Engineering DRNTU::Engineering::Electrical and electronic engineering Bamboo-shaped carbon nanotubes (CNTs) had been successfully fabricated by a plasma enhanced chemical vapor deposition method, in which nanocluster-assembled ZnO:Co thin film was used as catalyst. It was found that bamboo-shaped CNTs were generally grown in a direction perpendicularly to the substrate surface with the tops of CNTs dominated by the droplet-like catalyst covered by the carbon layer. The diameter of CNTs was ranged from 20–50 nm. High resolution of TEM image showed that the typical CNT had a multi-walled structure with an inner core presented. The ordered graphite layers were inclined to an axis of CNT about 18° and the interlayer space of a CNT was about 0.35 nm. Two peaks in Raman spectrum at 1586 cm−1 and 1372 cm−1 were identified as G-band and D-band for graphite, respectively. The results showed that catalyst based on ZnO:Co thin films could be used for the growth of CNTs with bamboo-shaped structure. 2013-09-24T06:49:13Z 2019-12-06T20:09:30Z 2013-09-24T06:49:13Z 2019-12-06T20:09:30Z 2012 2012 Journal Article Zhao, Z. W., Lei, W., Zhang, X. B., Tay, B. K., & Chen, J. S. (2012). Growth and Characterization of Bamboo-Shaped Carbon Nanotubes Using Nanocluster-Assembled ZnO:Co Thin Films as Catalyst. Journal of Nanoscience and Nanotechnology, 12(8), 6583-6587(5). https://hdl.handle.net/10356/99612 http://hdl.handle.net/10220/13643 10.1166/jnn.2012.5427 en Journal of nanoscience and nanotechnology
spellingShingle DRNTU::Engineering::Electrical and electronic engineering
Tay, Beng Kang
Zhao, Z. W.
Lei, W.
Zhang, X. B.
Chen, J. S.
Growth and characterization of bamboo-shaped carbon nanotubes using nanocluster-assembled ZnO:Co thin films as catalyst
title Growth and characterization of bamboo-shaped carbon nanotubes using nanocluster-assembled ZnO:Co thin films as catalyst
title_full Growth and characterization of bamboo-shaped carbon nanotubes using nanocluster-assembled ZnO:Co thin films as catalyst
title_fullStr Growth and characterization of bamboo-shaped carbon nanotubes using nanocluster-assembled ZnO:Co thin films as catalyst
title_full_unstemmed Growth and characterization of bamboo-shaped carbon nanotubes using nanocluster-assembled ZnO:Co thin films as catalyst
title_short Growth and characterization of bamboo-shaped carbon nanotubes using nanocluster-assembled ZnO:Co thin films as catalyst
title_sort growth and characterization of bamboo shaped carbon nanotubes using nanocluster assembled zno co thin films as catalyst
topic DRNTU::Engineering::Electrical and electronic engineering
url https://hdl.handle.net/10356/99612
http://hdl.handle.net/10220/13643
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