Direct electrochemical reduction of single-layer graphene oxide and subsequent functionalization with glucose oxidase

A direct electrochemical method to reduce single-layer graphene oxide (GO) adsorbed on the 3-aminopropyltriethoxysilane (APTES)-modified conductive electrodes is proposed. The reduced GO adsorbed on glassy carbon electrode was modified with glucose oxidase (GOx) by covalent bonding via a polymer gen...

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Main Authors: Wang, Zhijuan, Zhou, Xiaozhu, Zhang, Juan, Boey, Freddy Yin Chiang, Zhang, Hua
Other Authors: School of Materials Science & Engineering
Format: Journal Article
Language:English
Published: 2012
Subjects:
Online Access:https://hdl.handle.net/10356/99644
http://hdl.handle.net/10220/8558
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author Wang, Zhijuan
Zhou, Xiaozhu
Zhang, Juan
Boey, Freddy Yin Chiang
Zhang, Hua
author2 School of Materials Science & Engineering
author_facet School of Materials Science & Engineering
Wang, Zhijuan
Zhou, Xiaozhu
Zhang, Juan
Boey, Freddy Yin Chiang
Zhang, Hua
author_sort Wang, Zhijuan
collection NTU
description A direct electrochemical method to reduce single-layer graphene oxide (GO) adsorbed on the 3-aminopropyltriethoxysilane (APTES)-modified conductive electrodes is proposed. The reduced GO adsorbed on glassy carbon electrode was modified with glucose oxidase (GOx) by covalent bonding via a polymer generated by electrografting N-succinimidyl acrylate (NSA). The direct electron transfer between the electrode and GOx molecules was realized. The bioactivity of GOx maintains very well on the electrode. The thus-prepared GOx-modified electrode was successfully used to detect glucose.
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spelling ntu-10356/996442020-06-01T10:01:49Z Direct electrochemical reduction of single-layer graphene oxide and subsequent functionalization with glucose oxidase Wang, Zhijuan Zhou, Xiaozhu Zhang, Juan Boey, Freddy Yin Chiang Zhang, Hua School of Materials Science & Engineering DRNTU::Engineering::Materials A direct electrochemical method to reduce single-layer graphene oxide (GO) adsorbed on the 3-aminopropyltriethoxysilane (APTES)-modified conductive electrodes is proposed. The reduced GO adsorbed on glassy carbon electrode was modified with glucose oxidase (GOx) by covalent bonding via a polymer generated by electrografting N-succinimidyl acrylate (NSA). The direct electron transfer between the electrode and GOx molecules was realized. The bioactivity of GOx maintains very well on the electrode. The thus-prepared GOx-modified electrode was successfully used to detect glucose. 2012-09-18T03:15:24Z 2019-12-06T20:09:48Z 2012-09-18T03:15:24Z 2019-12-06T20:09:48Z 2009 2009 Journal Article Wang, Z., Zhou, X., Zhang, J., Boey, F. Y. C., & Zhang, H. (2009). Direct electrochemical reduction of single-layer graphene oxide and subsequent functionalization with glucose oxidase. The Journal of Physical Chemistry C, 113(32), 14071-14075. 1932-7447 https://hdl.handle.net/10356/99644 http://hdl.handle.net/10220/8558 10.1021/jp906348x en The journal of physical chemistry C © 2009 American Chemical Society.
spellingShingle DRNTU::Engineering::Materials
Wang, Zhijuan
Zhou, Xiaozhu
Zhang, Juan
Boey, Freddy Yin Chiang
Zhang, Hua
Direct electrochemical reduction of single-layer graphene oxide and subsequent functionalization with glucose oxidase
title Direct electrochemical reduction of single-layer graphene oxide and subsequent functionalization with glucose oxidase
title_full Direct electrochemical reduction of single-layer graphene oxide and subsequent functionalization with glucose oxidase
title_fullStr Direct electrochemical reduction of single-layer graphene oxide and subsequent functionalization with glucose oxidase
title_full_unstemmed Direct electrochemical reduction of single-layer graphene oxide and subsequent functionalization with glucose oxidase
title_short Direct electrochemical reduction of single-layer graphene oxide and subsequent functionalization with glucose oxidase
title_sort direct electrochemical reduction of single layer graphene oxide and subsequent functionalization with glucose oxidase
topic DRNTU::Engineering::Materials
url https://hdl.handle.net/10356/99644
http://hdl.handle.net/10220/8558
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AT zhouxiaozhu directelectrochemicalreductionofsinglelayergrapheneoxideandsubsequentfunctionalizationwithglucoseoxidase
AT zhangjuan directelectrochemicalreductionofsinglelayergrapheneoxideandsubsequentfunctionalizationwithglucoseoxidase
AT boeyfreddyyinchiang directelectrochemicalreductionofsinglelayergrapheneoxideandsubsequentfunctionalizationwithglucoseoxidase
AT zhanghua directelectrochemicalreductionofsinglelayergrapheneoxideandsubsequentfunctionalizationwithglucoseoxidase