The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes
Push–pull complexation: Transient terminal phosphinidene complexes [RP[BOND]W(CO)5] insert at 110 °C into the B[BOND]H bonds of L[BOND]BH3 (L = Et3N, Ph3P; see scheme). The reaction is probably driven by an interaction between the nucleophilic boron and the electrophilic phosphorus.
| Main Authors: | , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
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2013
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| Online Access: | https://hdl.handle.net/10356/99721 http://hdl.handle.net/10220/13020 |
| _version_ | 1826123428865769472 |
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| author | Tian, Rongqiang Mathey, François |
| author2 | School of Physical and Mathematical Sciences |
| author_facet | School of Physical and Mathematical Sciences Tian, Rongqiang Mathey, François |
| author_sort | Tian, Rongqiang |
| collection | NTU |
| description | Push–pull complexation: Transient terminal phosphinidene complexes [RP[BOND]W(CO)5] insert at 110 °C into the B[BOND]H bonds of L[BOND]BH3 (L = Et3N, Ph3P; see scheme). The reaction is probably driven by an interaction between the nucleophilic boron and the electrophilic phosphorus. |
| first_indexed | 2024-10-01T06:04:30Z |
| format | Journal Article |
| id | ntu-10356/99721 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T06:04:30Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/997212020-03-07T12:34:48Z The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes Tian, Rongqiang Mathey, François School of Physical and Mathematical Sciences Push–pull complexation: Transient terminal phosphinidene complexes [RP[BOND]W(CO)5] insert at 110 °C into the B[BOND]H bonds of L[BOND]BH3 (L = Et3N, Ph3P; see scheme). The reaction is probably driven by an interaction between the nucleophilic boron and the electrophilic phosphorus. 2013-08-05T07:08:44Z 2019-12-06T20:10:44Z 2013-08-05T07:08:44Z 2019-12-06T20:10:44Z 2012 2012 Journal Article Tian, R.,& Mathey, F. (2012). The Insertion of Terminal Phosphinidene Complexes into the B---H Bond of Amine and Phosphine Boranes. Chemistry - A European Journal, 18(36), 11210-11213. 0947-6539 https://hdl.handle.net/10356/99721 http://hdl.handle.net/10220/13020 10.1002/chem.201202277 en Chemistry - a European journal |
| spellingShingle | Tian, Rongqiang Mathey, François The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes |
| title | The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes |
| title_full | The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes |
| title_fullStr | The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes |
| title_full_unstemmed | The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes |
| title_short | The insertion of terminal phosphinidene complexes into the B---H bond of amine and phosphine boranes |
| title_sort | insertion of terminal phosphinidene complexes into the b h bond of amine and phosphine boranes |
| url | https://hdl.handle.net/10356/99721 http://hdl.handle.net/10220/13020 |
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