Artificial photosynthetic hydrogen evolution over g-C3N4 nanosheets coupled with cobaloxime
We report an economic and noble-metal-free artificial photosynthetic system, consisting of g-C3N4 as photosensitizer and photocatalyst, and cobaloxime as co-catalyst, for H2 generation. This system allows for effective electron transfer from excited g-C3N4 to CoIII(dmgH)2pyCl to generate reduced cob...
| Main Authors: | , , , , , , , , |
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| Other Authors: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
2013
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/99916 http://hdl.handle.net/10220/17614 |
| _version_ | 1811678620281733120 |
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| author | Cao, Shao-Wen Liu, Xin-Feng Yuan, Yu-Peng Zhang, Zhenyi Fang, Jun Loo, Say Chye Joachim Barber, James Sum, Tze Chien Xue, Can |
| author2 | School of Materials Science & Engineering |
| author_facet | School of Materials Science & Engineering Cao, Shao-Wen Liu, Xin-Feng Yuan, Yu-Peng Zhang, Zhenyi Fang, Jun Loo, Say Chye Joachim Barber, James Sum, Tze Chien Xue, Can |
| author_sort | Cao, Shao-Wen |
| collection | NTU |
| description | We report an economic and noble-metal-free artificial photosynthetic system, consisting of g-C3N4 as photosensitizer and photocatalyst, and cobaloxime as co-catalyst, for H2 generation. This system allows for effective electron transfer from excited g-C3N4 to CoIII(dmgH)2pyCl to generate reduced cobaloxime intermediate species for efficient H2 evolution. Transient fluorescence studies reveal that the presence of cobaloxime and TEOA promotes the population of excited electrons to transfer from g-C3N4, which is responsible for the high photocatalytic activity of this g-C3N4-cobaloxime conjugation system. |
| first_indexed | 2024-10-01T02:56:09Z |
| format | Journal Article |
| id | ntu-10356/99916 |
| institution | Nanyang Technological University |
| language | English |
| last_indexed | 2024-10-01T02:56:09Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | ntu-10356/999162023-02-28T19:41:57Z Artificial photosynthetic hydrogen evolution over g-C3N4 nanosheets coupled with cobaloxime Cao, Shao-Wen Liu, Xin-Feng Yuan, Yu-Peng Zhang, Zhenyi Fang, Jun Loo, Say Chye Joachim Barber, James Sum, Tze Chien Xue, Can School of Materials Science & Engineering School of Physical and Mathematical Sciences DRNTU::Science::Chemistry We report an economic and noble-metal-free artificial photosynthetic system, consisting of g-C3N4 as photosensitizer and photocatalyst, and cobaloxime as co-catalyst, for H2 generation. This system allows for effective electron transfer from excited g-C3N4 to CoIII(dmgH)2pyCl to generate reduced cobaloxime intermediate species for efficient H2 evolution. Transient fluorescence studies reveal that the presence of cobaloxime and TEOA promotes the population of excited electrons to transfer from g-C3N4, which is responsible for the high photocatalytic activity of this g-C3N4-cobaloxime conjugation system. NRF (Natl Research Foundation, S’pore) MOE (Min. of Education, S’pore) Accepted version 2013-11-12T09:05:50Z 2019-12-06T20:13:34Z 2013-11-12T09:05:50Z 2019-12-06T20:13:34Z 2013 2013 Journal Article Cao, S. W., Liu, X. F., Yuan, Y. P., Zhang, Z., Fang, J., Loo, S. C. J., et al. (2013). Artificial photosynthetic hydrogen evolution over g-C3N4 nanosheets coupled with cobaloxime. Physical chemistry chemical physics, 15, 18363-18366. https://hdl.handle.net/10356/99916 http://hdl.handle.net/10220/17614 10.1039/c3cp53350f en Physical chemistry chemical physics © 2013 Royal Society of Chemistry. This is the author created version of a work that has been peer reviewed and accepted for publication by Physical Chemistry Chemical Physics, Royal Society of Chemistry. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1039/c3cp53350f]. application/pdf |
| spellingShingle | DRNTU::Science::Chemistry Cao, Shao-Wen Liu, Xin-Feng Yuan, Yu-Peng Zhang, Zhenyi Fang, Jun Loo, Say Chye Joachim Barber, James Sum, Tze Chien Xue, Can Artificial photosynthetic hydrogen evolution over g-C3N4 nanosheets coupled with cobaloxime |
| title | Artificial photosynthetic hydrogen evolution over g-C3N4 nanosheets coupled with cobaloxime |
| title_full | Artificial photosynthetic hydrogen evolution over g-C3N4 nanosheets coupled with cobaloxime |
| title_fullStr | Artificial photosynthetic hydrogen evolution over g-C3N4 nanosheets coupled with cobaloxime |
| title_full_unstemmed | Artificial photosynthetic hydrogen evolution over g-C3N4 nanosheets coupled with cobaloxime |
| title_short | Artificial photosynthetic hydrogen evolution over g-C3N4 nanosheets coupled with cobaloxime |
| title_sort | artificial photosynthetic hydrogen evolution over g c3n4 nanosheets coupled with cobaloxime |
| topic | DRNTU::Science::Chemistry |
| url | https://hdl.handle.net/10356/99916 http://hdl.handle.net/10220/17614 |
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