2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate
The asymmetric unit of the title compound, C22H20N2O4·H2O, comprises a substituted benzimidazole molecule and a water molecule of crystallization. The dihedral angles between the benzimidazole ring system and the two outer benzene rings are 16.54 (4) and 86.13 (4)°. The dihedral angle between the tw...
| প্রধান লেখক: | , , , , |
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| বিন্যাস: | প্রবন্ধ |
| ভাষা: | English |
| প্রকাশিত: |
International Union of Crystallography
2009
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| বিষয়গুলি: | |
| অনলাইন ব্যবহার করুন: | http://irep.iium.edu.my/10409/1/lh2793.pdf |
| _version_ | 1825645168691249152 |
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| author | Al-Douh, Mohammed Hadi Osman, Hasnah Abd Hamid, Shafida Kia, Reza Fun, Hoong-Kun |
| author_facet | Al-Douh, Mohammed Hadi Osman, Hasnah Abd Hamid, Shafida Kia, Reza Fun, Hoong-Kun |
| author_sort | Al-Douh, Mohammed Hadi |
| collection | IIUM |
| description | The asymmetric unit of the title compound, C22H20N2O4·H2O, comprises a substituted benzimidazole molecule and a water molecule of crystallization. The dihedral angles between the benzimidazole ring system and the two outer benzene rings are 16.54 (4) and 86.13 (4)°. The dihedral angle between the two hydroxy-substituted benzene rings is 82.20 (5)°. In the crystal structure, intermolecular O-H...O hydrogen bonds, involving the hydroxy groups and water molecules, form R44(8) ring motifs, and link symmetry-related molecules into extended chains along the c axis. The crystal structure is further stabilized by weak intermolecular C-H...O hydrogen bonds, weak C-H...[pi] and [pi]-[pi] stacking [centroid-centroid = 3.6495 (6)-3.7130 (6) Å] interactions. Intramolecular O-H...O and O-H...N interactions are also present. |
| first_indexed | 2024-03-05T22:43:39Z |
| format | Article |
| id | oai:generic.eprints.org:10409 |
| institution | International Islamic University Malaysia |
| language | English |
| last_indexed | 2024-03-05T22:43:39Z |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | oai:generic.eprints.org:104092020-11-18T07:47:19Z http://irep.iium.edu.my/10409/ 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate Al-Douh, Mohammed Hadi Osman, Hasnah Abd Hamid, Shafida Kia, Reza Fun, Hoong-Kun QD Chemistry The asymmetric unit of the title compound, C22H20N2O4·H2O, comprises a substituted benzimidazole molecule and a water molecule of crystallization. The dihedral angles between the benzimidazole ring system and the two outer benzene rings are 16.54 (4) and 86.13 (4)°. The dihedral angle between the two hydroxy-substituted benzene rings is 82.20 (5)°. In the crystal structure, intermolecular O-H...O hydrogen bonds, involving the hydroxy groups and water molecules, form R44(8) ring motifs, and link symmetry-related molecules into extended chains along the c axis. The crystal structure is further stabilized by weak intermolecular C-H...O hydrogen bonds, weak C-H...[pi] and [pi]-[pi] stacking [centroid-centroid = 3.6495 (6)-3.7130 (6) Å] interactions. Intramolecular O-H...O and O-H...N interactions are also present. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://irep.iium.edu.my/10409/1/lh2793.pdf Al-Douh, Mohammed Hadi and Osman, Hasnah and Abd Hamid, Shafida and Kia, Reza and Fun, Hoong-Kun (2009) 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate. Acta Crystallographica Section E Structure Reports Online, E65 (4). o913-o914. ISSN 1600-5368 http://journals.iucr.org/e/issues/2009/04/00/issconts.html 10.1107/S1600536809010769 |
| spellingShingle | QD Chemistry Al-Douh, Mohammed Hadi Osman, Hasnah Abd Hamid, Shafida Kia, Reza Fun, Hoong-Kun 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate |
| title | 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate |
| title_full | 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate |
| title_fullStr | 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate |
| title_full_unstemmed | 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate |
| title_short | 2-[1-(2-hydroxy-3-methoxybenzyl)-1H-benzimidazol-2-yl]-6-methoxyphenol monohydrate |
| title_sort | 2 1 2 hydroxy 3 methoxybenzyl 1h benzimidazol 2 yl 6 methoxyphenol monohydrate |
| topic | QD Chemistry |
| url | http://irep.iium.edu.my/10409/1/lh2793.pdf |
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