IDENTIFIKASI UNSUR KADMIUM DAN BORON DALAM URANIUM OKSIDA MENGGUNAKAN ANALISIS CITRA SPEKTROGRAFI EMISI

Qualitative and quantitative analysis on emission spectrographic detector were important to identify impurities elements in nuclear fuel. In Indonesia, the process is still using a densitometer based manual method which has limitations due mechanical factors on instrument and expert chemists require...

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Bibliographic Details
Main Authors: , ITMI HIDAYAT KURNIAWAN, , Dr. Indah Susanti, S.T., M.T.
Format: Thesis
Published: [Yogyakarta] : Universitas Gadjah Mada 2013
Subjects:
ETD
Description
Summary:Qualitative and quantitative analysis on emission spectrographic detector were important to identify impurities elements in nuclear fuel. In Indonesia, the process is still using a densitometer based manual method which has limitations due mechanical factors on instrument and expert chemists requirements. To reduce measurement error on manual methods, we develops analytical methods by processing scanned digital image of a spectrogram. The aim of this research is to identify impurities on nuclear fuel elements (boron and cadmium in uranium oxide). Image processing was done by cropping digital image to separate each the spectra result of excitation processes and identify impurities, which enlarged later to refine the distribution of signal intensity of pixels. Signal processing methods for quantitative analysis conducted with pulse peaks analysis and pulse wide analysis. Results obtained then substituted into a standard curve obtained from regression analysis of sample reference to calculate concentration of the element. The results show that image processing can be used to identify and analyze the elements in the detector, element concentrations value of image processing is not different from the results of analysis of densitometer on statistically significance level of 5%. The relative deviation value of boron analysis based on extensive measurements of height and wide of the curve is 2,267% and 0,886%. While the relative deviation value in the cadmium analysis is 1,718% and 17,119%.