MODIFIKASI MAGNETIK ZEOLIT ALAM BERBASIS METODE KOPRESIPITASI SERTA APLIKASINYA SEBAGAI ADSORBEN Cd(II)

Natural zeolites were modified with iron oxide by coprecipitation method and investigating the effect of temperature and pH on the type of iron oxide. To assess the effect of temperature, zeolite-magnetit composite wassynthesized ata variation ofroom temperature, 50 �C and 85 �C at pH 9. Furthermo...

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Bibliographic Details
Main Authors: , AULIA NUR RAHMAWATI, , Dr. Suyanta, Ms.Si.
Format: Thesis
Published: [Yogyakarta] : Universitas Gadjah Mada 2014
Subjects:
ETD
Description
Summary:Natural zeolites were modified with iron oxide by coprecipitation method and investigating the effect of temperature and pH on the type of iron oxide. To assess the effect of temperature, zeolite-magnetit composite wassynthesized ata variation ofroom temperature, 50 �C and 85 �C at pH 9. Furthermore, to assess the effect of pH, natural zeolit was magnetic modified at pH variations of 10, 11 and 12 of a temperature. The zeolite-magnetite at the optimal condition of temperature and pH were applied as adsorbent Cd(II) . Composite characterization was conducted using X-ray diffraction, infrared spectrophotometry, atomic absorption spectrophotometry and isothermsadsorption methods. The results showed that optimal conditions to magnetic modified of natural zeolit known at temperatures 85 � C and pH 11. Zeolite-magnetite was able to adsorbCd(II)with adsorption rate constanta(k) is greater than a that of the activated zeolite, adsorption rate constanta was 0.0160 (g/mg minute) by activated zeolite adsorben and adsorption rate constanta was 0.0648 (g/mg minute) by magnetic zeolite adsorben with following Ho second-order pseudo kinetics adsorption. By using an external magnetic field of zeolite-magnetite adsorbent recovery can be done more quickly thana that of the activated zeolite adsorbent.