6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate
The title compound, C22H20N2O4·2CHCl3, a new Schiff base compound, lies across a crystallographic inversion centre. An intramolecular O-HN hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Intermolecular bifurcated C-HO hydrogen bonds involving the two O atoms of the Schiff...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009
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| Subjects: | |
| Online Access: | http://irep.iium.edu.my/12809/1/6_6_dimethoxy_2_p_phenylenebis.pdf |
| _version_ | 1825645348289249280 |
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| author | Al-Douh, Mohammed Hadi Osman, Hasnah Abd Hamid, Shafida Kia, Reza Fun, Hoong-Kun |
| author_facet | Al-Douh, Mohammed Hadi Osman, Hasnah Abd Hamid, Shafida Kia, Reza Fun, Hoong-Kun |
| author_sort | Al-Douh, Mohammed Hadi |
| collection | IIUM |
| description | The title compound, C22H20N2O4·2CHCl3, a new Schiff base compound, lies across a crystallographic inversion centre. An intramolecular O-HN hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Intermolecular bifurcated C-HO hydrogen bonds involving the two O atoms of the Schiff base ligand and the H atom of the chloroform solvent of crystallization, generate an R21(5) ring motif. The crystal structure is stabilized by intermolecular C-H and - interactions [centroid to centroid distance = 3.6158 (10) Å]. In the crystal structure, molecules are stacked down the c axis. |
| first_indexed | 2024-03-05T22:46:23Z |
| format | Article |
| id | oai:generic.eprints.org:12809 |
| institution | International Islamic University Malaysia |
| language | English |
| last_indexed | 2024-03-05T22:46:23Z |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | oai:generic.eprints.org:128092012-05-08T12:37:01Z http://irep.iium.edu.my/12809/ 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate Al-Douh, Mohammed Hadi Osman, Hasnah Abd Hamid, Shafida Kia, Reza Fun, Hoong-Kun QD Chemistry The title compound, C22H20N2O4·2CHCl3, a new Schiff base compound, lies across a crystallographic inversion centre. An intramolecular O-HN hydrogen bond generates a six-membered ring, producing an S(6) ring motif. Intermolecular bifurcated C-HO hydrogen bonds involving the two O atoms of the Schiff base ligand and the H atom of the chloroform solvent of crystallization, generate an R21(5) ring motif. The crystal structure is stabilized by intermolecular C-H and - interactions [centroid to centroid distance = 3.6158 (10) Å]. In the crystal structure, molecules are stacked down the c axis. International Union of Crystallography 2009 Article PeerReviewed application/pdf en http://irep.iium.edu.my/12809/1/6_6_dimethoxy_2_p_phenylenebis.pdf Al-Douh, Mohammed Hadi and Osman, Hasnah and Abd Hamid, Shafida and Kia, Reza and Fun, Hoong-Kun (2009) 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate. Acta Crystallographica Section E Structure Reports Online, 65 (4). O680-O681. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536809007302 10.1107/S1600536809007302 |
| spellingShingle | QD Chemistry Al-Douh, Mohammed Hadi Osman, Hasnah Abd Hamid, Shafida Kia, Reza Fun, Hoong-Kun 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate |
| title | 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate |
| title_full | 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate |
| title_fullStr | 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate |
| title_full_unstemmed | 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate |
| title_short | 6,6′-Dimethoxy-2,2′-[p-phenylenebis(nitrilomethylidyne)]diphenol chloroform disolvate |
| title_sort | 6 6 dimethoxy 2 2 p phenylenebis nitrilomethylidyne diphenol chloroform disolvate |
| topic | QD Chemistry |
| url | http://irep.iium.edu.my/12809/1/6_6_dimethoxy_2_p_phenylenebis.pdf |
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