PEMBUATAN SURFAKTAN METIL ESTER SULFONAT TERKATALISIS CaO DENGAN VARIASI WAKTU SULFONASI
Research of synthesis methyl ester sulfonates surfactant (MES) from palm oil has been done through two-stage reaction. The first stage was transesterification of palm oil with methanol and NaOH catalyst for 90 minutes at a temperature of 65 ºC. Second stage was methyl ester sulfonation with sodium...
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| Format: | Thesis |
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[Yogyakarta] : Universitas Gadjah Mada
2014
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| _version_ | 1797035059518111744 |
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| author | , ANANTO DWI RAHMADI , Dra. Ani Setyopratiwi, M.Si |
| author_facet | , ANANTO DWI RAHMADI , Dra. Ani Setyopratiwi, M.Si |
| author_sort | , ANANTO DWI RAHMADI |
| collection | UGM |
| description | Research of synthesis methyl ester sulfonates surfactant (MES) from palm oil has been done through two-stage reaction. The first stage was transesterification of palm oil with methanol and NaOH catalyst for 90 minutes at a temperature of 65 ºC. Second stage was methyl ester sulfonation with sodium bisulfite (NaHSO3) at a temperature of 90 ºC using CaO catalyst as much as 1% (w/w) with sulfonation time variation.
The result showed that the methyl ester of palm oil contained two dominant esters, namely methyl palmitate (46,15%) and methyl oleate (48,42%). The result of IR spectra showed that methyl ester sulfonation has been successfully achieved with NaHSO3. The sulfonation time for 4 hours produced optimum MES which has an active ingredient content of 11,73%, was able to lower the water surface tension by 34,75 dyne/cm, stabilized water-xylene emulsion up to 62,73%. |
| first_indexed | 2024-03-13T23:22:45Z |
| format | Thesis |
| id | oai:generic.eprints.org:128843 |
| institution | Universiti Gadjah Mada |
| last_indexed | 2024-03-13T23:22:45Z |
| publishDate | 2014 |
| publisher | [Yogyakarta] : Universitas Gadjah Mada |
| record_format | dspace |
| spelling | oai:generic.eprints.org:1288432016-03-04T07:52:04Z https://repository.ugm.ac.id/128843/ PEMBUATAN SURFAKTAN METIL ESTER SULFONAT TERKATALISIS CaO DENGAN VARIASI WAKTU SULFONASI , ANANTO DWI RAHMADI , Dra. Ani Setyopratiwi, M.Si ETD Research of synthesis methyl ester sulfonates surfactant (MES) from palm oil has been done through two-stage reaction. The first stage was transesterification of palm oil with methanol and NaOH catalyst for 90 minutes at a temperature of 65 ºC. Second stage was methyl ester sulfonation with sodium bisulfite (NaHSO3) at a temperature of 90 ºC using CaO catalyst as much as 1% (w/w) with sulfonation time variation. The result showed that the methyl ester of palm oil contained two dominant esters, namely methyl palmitate (46,15%) and methyl oleate (48,42%). The result of IR spectra showed that methyl ester sulfonation has been successfully achieved with NaHSO3. The sulfonation time for 4 hours produced optimum MES which has an active ingredient content of 11,73%, was able to lower the water surface tension by 34,75 dyne/cm, stabilized water-xylene emulsion up to 62,73%. [Yogyakarta] : Universitas Gadjah Mada 2014 Thesis NonPeerReviewed , ANANTO DWI RAHMADI and , Dra. Ani Setyopratiwi, M.Si (2014) PEMBUATAN SURFAKTAN METIL ESTER SULFONAT TERKATALISIS CaO DENGAN VARIASI WAKTU SULFONASI. UNSPECIFIED thesis, UNSPECIFIED. http://etd.ugm.ac.id/index.php?mod=penelitian_detail&sub=PenelitianDetail&act=view&typ=html&buku_id=69216 |
| spellingShingle | ETD , ANANTO DWI RAHMADI , Dra. Ani Setyopratiwi, M.Si PEMBUATAN SURFAKTAN METIL ESTER SULFONAT TERKATALISIS CaO DENGAN VARIASI WAKTU SULFONASI |
| title | PEMBUATAN SURFAKTAN METIL ESTER SULFONAT TERKATALISIS CaO DENGAN VARIASI WAKTU
SULFONASI |
| title_full | PEMBUATAN SURFAKTAN METIL ESTER SULFONAT TERKATALISIS CaO DENGAN VARIASI WAKTU
SULFONASI |
| title_fullStr | PEMBUATAN SURFAKTAN METIL ESTER SULFONAT TERKATALISIS CaO DENGAN VARIASI WAKTU
SULFONASI |
| title_full_unstemmed | PEMBUATAN SURFAKTAN METIL ESTER SULFONAT TERKATALISIS CaO DENGAN VARIASI WAKTU
SULFONASI |
| title_short | PEMBUATAN SURFAKTAN METIL ESTER SULFONAT TERKATALISIS CaO DENGAN VARIASI WAKTU
SULFONASI |
| title_sort | pembuatan surfaktan metil ester sulfonat terkatalisis cao dengan variasi waktu sulfonasi |
| topic | ETD |
| work_keys_str_mv | AT anantodwirahmadi pembuatansurfaktanmetilestersulfonatterkatalisiscaodenganvariasiwaktusulfonasi AT draanisetyopratiwimsi pembuatansurfaktanmetilestersulfonatterkatalisiscaodenganvariasiwaktusulfonasi |