KARAKTERISASI DAN ANALISA GUGUS FUNGSI PADA MAGNETIC NANOPARTICLES (MNPs) COBALT FERRITE (CoFe2O4) YANG DILAPISI DENGAN SILIKA (SiO2)

Magnetic nanoparticle Cobalt Ferrite (CoFe2O4) have been successfully synthesized through coprecipitation method, by mixing CoCl2.H2O and FeCl3.H2O at 80°C, mixed for 120 minutes, with spinning speed of 1000 rpm, and 5 M NaOH as coprecipitant. Silica coated Cobalt Ferrite has been modified the surf...

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Bibliographic Details
Main Authors: , ANNISA AYU ARTANTI, , Dr. Edi Suharyadi
Format: Thesis
Published: [Yogyakarta] : Universitas Gadjah Mada 2014
Subjects:
ETD
Description
Summary:Magnetic nanoparticle Cobalt Ferrite (CoFe2O4) have been successfully synthesized through coprecipitation method, by mixing CoCl2.H2O and FeCl3.H2O at 80°C, mixed for 120 minutes, with spinning speed of 1000 rpm, and 5 M NaOH as coprecipitant. Silica coated Cobalt Ferrite has been modified the surface of Cobalt Ferrite with various concentration of silica 50%, 30%, 20%, 15%, 10% and 5%. The structure and size of the particles were characterized using X-Ray Diffraction (XRD) and Transmission Electron Microscopy (TEM). XRD test results showed reduced lattice parameter values after functionalization with silica. TEM test results indicated that the particle size of CoFe2O4+ silica is greater than CoFe2O4, The results from magnetization test using a Vibrating Sample Manetometer (VSM) suggested that CoFe2O4 + silica has a higher coercivity than CoFe2O4, lower magnetic remanence and saturation than CoFe2O4. Functional group bonding test, performed using Fourier Transform Infra-Red Spectroscopy (FTIR) showed that the Fe-O absorption peak in CoFe2O4, shifted towards higher wave numbers after the functionalization with silica due to lower vibrational energy as the result of absorption by the silica