Adsorption Of Cr(VI) On Black Water Adsorpsi Cr(VI) pada Air Hitam
ABSTRACT The effect of initial concentration of Cr(VI) on adsorption to black water of Gambut, District of Banjar, South Borneo has been investigated, as well as interaction betwen Cr(VI) species and functional black water organic fraction. The initial work was optimization of Cr(VI) determinition u...
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| Format: | Article |
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[Yogyakarta] : Universitas Gadjah Mada
2003
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| _version_ | 1826031337794961408 |
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| author | Perpustakaan UGM, i-lib |
| author_facet | Perpustakaan UGM, i-lib |
| author_sort | Perpustakaan UGM, i-lib |
| collection | UGM |
| description | ABSTRACT
The effect of initial concentration of Cr(VI) on adsorption to black water of Gambut, District of Banjar, South Borneo has been investigated, as well as interaction betwen Cr(VI) species and functional black water organic fraction.
The initial work was optimization of Cr(VI) determinition using UV-Visible Spectrophotometry with diphenylcarbacide as complexing agent and preparation of black water using mixture of 2% HCI and 5% HF with HCI-HF ratio of 1 : 1 (v/v). The quantity of Cr(VI) species adsorbed on black water was calculated by determining the amount of Cr(VI) species in solution before and after interaction. The functional groups in interaction between Cr(VI) species and black water organic fraction was studied qualitatively using infrared spectroscopy.
The results showed that optimum condition for Cr(VI) species analysis using UV-Visible spectrophotometry with diphenylcarbacide as complexing agent was at wave length of 540 nm, pH 1,5, 15 -60 minutes at which complex remain stable, and minimum mol ratio of diphenylcarbacide : Cr(VI) 45 : 1, and has a sensitivity of 1.134 mg/L and detection limit of 0.00495 mg/L. The analysis was not affected by the presence of Cr(III) in concentration less than 40 times of Cr(VI) concentration. After treatment with HCI-HF the quantity of black water organic fraction showing humic acid properties decreased 0,1998 percent. Organic fraction of black water used adsorpted Cr(VI)with capacity of 4,050 mg/g.
Keywords: Adsorption, Cr(VI), Black Water |
| first_indexed | 2024-03-13T18:28:32Z |
| format | Article |
| id | oai:generic.eprints.org:18719 |
| institution | Universiti Gadjah Mada |
| last_indexed | 2024-03-13T18:28:32Z |
| publishDate | 2003 |
| publisher | [Yogyakarta] : Universitas Gadjah Mada |
| record_format | dspace |
| spelling | oai:generic.eprints.org:187192014-06-18T00:29:35Z https://repository.ugm.ac.id/18719/ Adsorption Of Cr(VI) On Black Water Adsorpsi Cr(VI) pada Air Hitam Perpustakaan UGM, i-lib Jurnal i-lib UGM ABSTRACT The effect of initial concentration of Cr(VI) on adsorption to black water of Gambut, District of Banjar, South Borneo has been investigated, as well as interaction betwen Cr(VI) species and functional black water organic fraction. The initial work was optimization of Cr(VI) determinition using UV-Visible Spectrophotometry with diphenylcarbacide as complexing agent and preparation of black water using mixture of 2% HCI and 5% HF with HCI-HF ratio of 1 : 1 (v/v). The quantity of Cr(VI) species adsorbed on black water was calculated by determining the amount of Cr(VI) species in solution before and after interaction. The functional groups in interaction between Cr(VI) species and black water organic fraction was studied qualitatively using infrared spectroscopy. The results showed that optimum condition for Cr(VI) species analysis using UV-Visible spectrophotometry with diphenylcarbacide as complexing agent was at wave length of 540 nm, pH 1,5, 15 -60 minutes at which complex remain stable, and minimum mol ratio of diphenylcarbacide : Cr(VI) 45 : 1, and has a sensitivity of 1.134 mg/L and detection limit of 0.00495 mg/L. The analysis was not affected by the presence of Cr(III) in concentration less than 40 times of Cr(VI) concentration. After treatment with HCI-HF the quantity of black water organic fraction showing humic acid properties decreased 0,1998 percent. Organic fraction of black water used adsorpted Cr(VI)with capacity of 4,050 mg/g. Keywords: Adsorption, Cr(VI), Black Water [Yogyakarta] : Universitas Gadjah Mada 2003 Article NonPeerReviewed Perpustakaan UGM, i-lib (2003) Adsorption Of Cr(VI) On Black Water Adsorpsi Cr(VI) pada Air Hitam. Jurnal i-lib UGM. http://i-lib.ugm.ac.id/jurnal/download.php?dataId=1521 |
| spellingShingle | Jurnal i-lib UGM Perpustakaan UGM, i-lib Adsorption Of Cr(VI) On Black Water Adsorpsi Cr(VI) pada Air Hitam |
| title | Adsorption Of Cr(VI) On Black Water Adsorpsi Cr(VI) pada Air Hitam |
| title_full | Adsorption Of Cr(VI) On Black Water Adsorpsi Cr(VI) pada Air Hitam |
| title_fullStr | Adsorption Of Cr(VI) On Black Water Adsorpsi Cr(VI) pada Air Hitam |
| title_full_unstemmed | Adsorption Of Cr(VI) On Black Water Adsorpsi Cr(VI) pada Air Hitam |
| title_short | Adsorption Of Cr(VI) On Black Water Adsorpsi Cr(VI) pada Air Hitam |
| title_sort | adsorption of cr vi on black water adsorpsi cr vi pada air hitam |
| topic | Jurnal i-lib UGM |
| work_keys_str_mv | AT perpustakaanugmilib adsorptionofcrvionblackwateradsorpsicrvipadaairhitam |