Dewaxing Solar Dengan Penambahan Mek Tinjauan Termodinamis

In the petroleum industries, wax precipitation is undesirable because it may cause plugging in the pipelines and process equipment. So, the amount of wax in petroleum products should be kept relatively small and it can be achieved by dewaxing. The system in dewaxing is assumed to be a ternary system...

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Main Author: Perpustakaan UGM, i-lib
Format: Article
Published: [Yogyakarta] : Universitas Gadjah Mada 2003
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author Perpustakaan UGM, i-lib
author_facet Perpustakaan UGM, i-lib
author_sort Perpustakaan UGM, i-lib
collection UGM
description In the petroleum industries, wax precipitation is undesirable because it may cause plugging in the pipelines and process equipment. So, the amount of wax in petroleum products should be kept relatively small and it can be achieved by dewaxing. The system in dewaxing is assumed to be a ternary system with the pseudo components of alifatics (wax or paraffins and naphtenes), ketones (MEK), and aromatics. Numerous activity coefficient models were used to predict the solid-liquid equilibrium in dewaxing of diesel fuel with MEK. The models were Unifac, Regular solution, and Two Suffix Margules. In one operation, 15 mL of diesel fuel was mixed with 37.5 mL of MEK (pure or mixed with benzene) and chilled to the desired temperature in a silindrical tube with 2.9 cm of inside diameter, 3.25 cm of outside diameter and 12.25 cm of length. After equilibrium condition was attained, a liquid sample was taken and its composition was analyzed using ASTM D 1319-98. Experimental results showed that pseudo ternary approximation could well predict the equilibrium. It was further observed that Uriifac model with 7.6% of error was better than Regular solution model with 12.3% of error. Two Suffix Margules model gave very good result but it used one adjustable parameter, so it could be used only in this system. Keywords : dewaxing, diesel fuel, ternzodynamic
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spelling oai:generic.eprints.org:235132014-06-18T00:29:50Z https://repository.ugm.ac.id/23513/ Dewaxing Solar Dengan Penambahan Mek Tinjauan Termodinamis Perpustakaan UGM, i-lib Jurnal i-lib UGM In the petroleum industries, wax precipitation is undesirable because it may cause plugging in the pipelines and process equipment. So, the amount of wax in petroleum products should be kept relatively small and it can be achieved by dewaxing. The system in dewaxing is assumed to be a ternary system with the pseudo components of alifatics (wax or paraffins and naphtenes), ketones (MEK), and aromatics. Numerous activity coefficient models were used to predict the solid-liquid equilibrium in dewaxing of diesel fuel with MEK. The models were Unifac, Regular solution, and Two Suffix Margules. In one operation, 15 mL of diesel fuel was mixed with 37.5 mL of MEK (pure or mixed with benzene) and chilled to the desired temperature in a silindrical tube with 2.9 cm of inside diameter, 3.25 cm of outside diameter and 12.25 cm of length. After equilibrium condition was attained, a liquid sample was taken and its composition was analyzed using ASTM D 1319-98. Experimental results showed that pseudo ternary approximation could well predict the equilibrium. It was further observed that Uriifac model with 7.6% of error was better than Regular solution model with 12.3% of error. Two Suffix Margules model gave very good result but it used one adjustable parameter, so it could be used only in this system. Keywords : dewaxing, diesel fuel, ternzodynamic [Yogyakarta] : Universitas Gadjah Mada 2003 Article NonPeerReviewed Perpustakaan UGM, i-lib (2003) Dewaxing Solar Dengan Penambahan Mek Tinjauan Termodinamis. Jurnal i-lib UGM. http://i-lib.ugm.ac.id/jurnal/download.php?dataId=6463
spellingShingle Jurnal i-lib UGM
Perpustakaan UGM, i-lib
Dewaxing Solar Dengan Penambahan Mek Tinjauan Termodinamis
title Dewaxing Solar Dengan Penambahan Mek Tinjauan Termodinamis
title_full Dewaxing Solar Dengan Penambahan Mek Tinjauan Termodinamis
title_fullStr Dewaxing Solar Dengan Penambahan Mek Tinjauan Termodinamis
title_full_unstemmed Dewaxing Solar Dengan Penambahan Mek Tinjauan Termodinamis
title_short Dewaxing Solar Dengan Penambahan Mek Tinjauan Termodinamis
title_sort dewaxing solar dengan penambahan mek tinjauan termodinamis
topic Jurnal i-lib UGM
work_keys_str_mv AT perpustakaanugmilib dewaxingsolardenganpenambahanmektinjauantermodinamis