Photovoltaic activity in a ZnSe/PEO-chitosan blend electrolyte junction

Abstract Thin films of ZnSe and PEO–chitosan blend polymer doped with NH4I and iodine crystals were prepared to form the two sides of a semiconductor electrolyte junction. ZnSe was electrodeposited on indium tin oxide (ITO) conducting glass. The polymer is a blend of 50 wt% chitosan and 50 wt%...

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Main Authors: Mohamad, Souad A., Ali, Moazzam H., Yahya, Rosiyah, Ibrahim, Zainol Abidin, Arof, Abdul Kariem
Format: Article
Language:English
Published: Institute for Ionics 2007
Subjects:
Online Access:http://irep.iium.edu.my/23838/1/SOUAD_Paper_ZnSe-PEO_%28Ionic%29.pdf
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author Mohamad, Souad A.
Ali, Moazzam H.
Yahya, Rosiyah
Ibrahim, Zainol Abidin
Arof, Abdul Kariem
author_facet Mohamad, Souad A.
Ali, Moazzam H.
Yahya, Rosiyah
Ibrahim, Zainol Abidin
Arof, Abdul Kariem
author_sort Mohamad, Souad A.
collection IIUM
description Abstract Thin films of ZnSe and PEO–chitosan blend polymer doped with NH4I and iodine crystals were prepared to form the two sides of a semiconductor electrolyte junction. ZnSe was electrodeposited on indium tin oxide (ITO) conducting glass. The polymer is a blend of 50 wt% chitosan and 50 wt% polyethylene oxide. The polymer blend was complexed with ammonium iodide (NH4I), and some iodine crystals were added to the polymer–NH4I solution to provide the I−/I3−redox couple. The room temperature ionic conductivity of the polymer electrolyte is 4.32×10−6 S/cm. The polymer film was sandwiched between the ZnSe semiconductor and an ITO glass to form a ZnSe/polymer electrolyte/ITO photovoltaic cell. The open circuit voltage (Voc) of the fabricated cells ranges between 200 to 400 mV and the short circuit current between 7 to 10 μA.
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spelling oai:generic.eprints.org:238382013-07-22T07:54:49Z http://irep.iium.edu.my/23838/ Photovoltaic activity in a ZnSe/PEO-chitosan blend electrolyte junction Mohamad, Souad A. Ali, Moazzam H. Yahya, Rosiyah Ibrahim, Zainol Abidin Arof, Abdul Kariem TK2896 Production of electricity by direct energy conversion Abstract Thin films of ZnSe and PEO–chitosan blend polymer doped with NH4I and iodine crystals were prepared to form the two sides of a semiconductor electrolyte junction. ZnSe was electrodeposited on indium tin oxide (ITO) conducting glass. The polymer is a blend of 50 wt% chitosan and 50 wt% polyethylene oxide. The polymer blend was complexed with ammonium iodide (NH4I), and some iodine crystals were added to the polymer–NH4I solution to provide the I−/I3−redox couple. The room temperature ionic conductivity of the polymer electrolyte is 4.32×10−6 S/cm. The polymer film was sandwiched between the ZnSe semiconductor and an ITO glass to form a ZnSe/polymer electrolyte/ITO photovoltaic cell. The open circuit voltage (Voc) of the fabricated cells ranges between 200 to 400 mV and the short circuit current between 7 to 10 μA. Institute for Ionics 2007 Article PeerReviewed application/pdf en http://irep.iium.edu.my/23838/1/SOUAD_Paper_ZnSe-PEO_%28Ionic%29.pdf Mohamad, Souad A. and Ali, Moazzam H. and Yahya, Rosiyah and Ibrahim, Zainol Abidin and Arof, Abdul Kariem (2007) Photovoltaic activity in a ZnSe/PEO-chitosan blend electrolyte junction. Ionics, 13 (4). pp. 235-240. ISSN 0947-7047 http://link.springer.com/article/10.1007/s11581-007-0099-6 10.1007/s11581-007-0099-6
spellingShingle TK2896 Production of electricity by direct energy conversion
Mohamad, Souad A.
Ali, Moazzam H.
Yahya, Rosiyah
Ibrahim, Zainol Abidin
Arof, Abdul Kariem
Photovoltaic activity in a ZnSe/PEO-chitosan blend electrolyte junction
title Photovoltaic activity in a ZnSe/PEO-chitosan blend electrolyte junction
title_full Photovoltaic activity in a ZnSe/PEO-chitosan blend electrolyte junction
title_fullStr Photovoltaic activity in a ZnSe/PEO-chitosan blend electrolyte junction
title_full_unstemmed Photovoltaic activity in a ZnSe/PEO-chitosan blend electrolyte junction
title_short Photovoltaic activity in a ZnSe/PEO-chitosan blend electrolyte junction
title_sort photovoltaic activity in a znse peo chitosan blend electrolyte junction
topic TK2896 Production of electricity by direct energy conversion
url http://irep.iium.edu.my/23838/1/SOUAD_Paper_ZnSe-PEO_%28Ionic%29.pdf
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