Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil

In this work, Lapindo mud (LM) was used as catalyst support. This is because the Lapindo mud has a high SiO2 content of 45.33 %. This research aims to produce a hydrocracking catalyst based on Lapindo mud through impregnation of Ni and Pt metals as well as grafting amine groups. Ni and Pt metals imp...

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Main Authors: Trisunaryanti, Wega, Triyono, T., Fallah, Iip Izul, Salsiah, Shafira, Alisha, Gesha Desy
Format: Article
Language:English
Published: BCREC 2022
Subjects:
Online Access:https://repository.ugm.ac.id/278881/1/Highly-Selective-Biohydrocarbon-Production-using-Sidoarjo-Mud-BasedCatalysts-in-the-Hydrocracking-of-Waste-Palm-Cooking-OilBulletin-of-Chemical-Reaction-Engineering--Catalysis.pdf
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author Trisunaryanti, Wega
Triyono, T.
Fallah, Iip Izul
Salsiah, Shafira
Alisha, Gesha Desy
author_facet Trisunaryanti, Wega
Triyono, T.
Fallah, Iip Izul
Salsiah, Shafira
Alisha, Gesha Desy
author_sort Trisunaryanti, Wega
collection UGM
description In this work, Lapindo mud (LM) was used as catalyst support. This is because the Lapindo mud has a high SiO2 content of 45.33 %. This research aims to produce a hydrocracking catalyst based on Lapindo mud through impregnation of Ni and Pt metals as well as grafting amine groups. Ni and Pt metals impregnation using wet impregnation method followed by amine group grafting. The best catalyst in this study was NiPt-NH2/LM which contained Ni and Pt metals, surface area, and pore diameters of 1.68 wt.% and 0.4 wt.%, 6.59 m2/g, 15.51 nm, respectively. The effectiveness of the catalyst was tested against temperature and catalyst: feed ratio. The catalyst with the best activity and selectivity was tested for reusability 3 times through hydrocracking process. The yield of liquid products obtained in the hydrocracking process of WPO using NiPt-NH2/LM catalyst with the optimum temperature and the weight ratio of catalyst:feed at 550 oC was 79.4 wt. % which consists of hydrocarbon compound of 55.9 wt.%. The yield of liquid products obtained in the hydrocracking WPO using the used NiPt-BH2/LM catalyst was 28.4 wt.% which consists of hydrocarbon compound of 23.6 wt.%. Copyright © 2022 by Authors, Published by BCREC Group.
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spelling oai:generic.eprints.org:2788812023-10-18T05:40:05Z https://repository.ugm.ac.id/278881/ Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil Trisunaryanti, Wega Triyono, T. Fallah, Iip Izul Salsiah, Shafira Alisha, Gesha Desy Chemical Science In this work, Lapindo mud (LM) was used as catalyst support. This is because the Lapindo mud has a high SiO2 content of 45.33 %. This research aims to produce a hydrocracking catalyst based on Lapindo mud through impregnation of Ni and Pt metals as well as grafting amine groups. Ni and Pt metals impregnation using wet impregnation method followed by amine group grafting. The best catalyst in this study was NiPt-NH2/LM which contained Ni and Pt metals, surface area, and pore diameters of 1.68 wt.% and 0.4 wt.%, 6.59 m2/g, 15.51 nm, respectively. The effectiveness of the catalyst was tested against temperature and catalyst: feed ratio. The catalyst with the best activity and selectivity was tested for reusability 3 times through hydrocracking process. The yield of liquid products obtained in the hydrocracking process of WPO using NiPt-NH2/LM catalyst with the optimum temperature and the weight ratio of catalyst:feed at 550 oC was 79.4 wt. % which consists of hydrocarbon compound of 55.9 wt.%. The yield of liquid products obtained in the hydrocracking WPO using the used NiPt-BH2/LM catalyst was 28.4 wt.% which consists of hydrocarbon compound of 23.6 wt.%. Copyright © 2022 by Authors, Published by BCREC Group. BCREC 2022-12 Article PeerReviewed application/pdf en https://repository.ugm.ac.id/278881/1/Highly-Selective-Biohydrocarbon-Production-using-Sidoarjo-Mud-BasedCatalysts-in-the-Hydrocracking-of-Waste-Palm-Cooking-OilBulletin-of-Chemical-Reaction-Engineering--Catalysis.pdf Trisunaryanti, Wega and Triyono, T. and Fallah, Iip Izul and Salsiah, Shafira and Alisha, Gesha Desy (2022) Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil. Bulletin of Chemical Reaction Engineering & Catalysis, 17 (4). pp. 712-724. ISSN 1978-2993 https://journal.bcrec.id/index.php/bcrec/article/view/15472 https://doi.org/10.9767/bcrec.17.4.15472.712-724
spellingShingle Chemical Science
Trisunaryanti, Wega
Triyono, T.
Fallah, Iip Izul
Salsiah, Shafira
Alisha, Gesha Desy
Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil
title Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil
title_full Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil
title_fullStr Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil
title_full_unstemmed Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil
title_short Highly Selective Bio-hydrocarbon Production using Sidoarjo Mud Based-Catalysts in the Hydrocracking of Waste Palm Cooking Oil
title_sort highly selective bio hydrocarbon production using sidoarjo mud based catalysts in the hydrocracking of waste palm cooking oil
topic Chemical Science
url https://repository.ugm.ac.id/278881/1/Highly-Selective-Biohydrocarbon-Production-using-Sidoarjo-Mud-BasedCatalysts-in-the-Hydrocracking-of-Waste-Palm-Cooking-OilBulletin-of-Chemical-Reaction-Engineering--Catalysis.pdf
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