GREEN CHEMISTRYAPPLICATION FOR THE SYNTHESIS OF (1)-N-4'-METHOXYBENZVL-1,1O-PHENANTHROLINIUMBROMIDE
ABSTRACT A simple, energy-efficient, and relatively quick synthetic procedure for the synthesis of (1)-N-4'- methoxybenzyJ-1,10-phenanthroliniumbromide, based on green chemistry principles has been carried out. The synthesis was started by solvent-free reduction of p-anisaldehyde with NaBH4to g...
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| Format: | Article |
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[Yogyakarta] : Universitas Gadjah Mada
2008
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| _version_ | 1797019801837633536 |
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| author | Perpustakaan UGM, i-lib |
| author_facet | Perpustakaan UGM, i-lib |
| author_sort | Perpustakaan UGM, i-lib |
| collection | UGM |
| description | ABSTRACT
A simple, energy-efficient, and relatively quick synthetic procedure for the synthesis of (1)-N-4'-
methoxybenzyJ-1,10-phenanthroliniumbromide, based on green chemistry principles has been carried out. The
synthesis was started by solvent-free reduction of p-anisaldehyde with NaBH4to give 4-methoxybenzyl alcohol in
98% yield to be followed by solvent-free treatment of the resulted alcohol with PBr3 to yield 4-methoxybenzyl
bromide (86%). Furthennore, the obtained bromide was reacted with 1,10-phenanthrolinein acetone at reflux for 12
h to give the phenanthrolinium salt target in 68%yield.
Keywords:green chemistry, p-anisaldehyde,(1)-N-4'-methoxybenzyl-1, 1Q-phenanthroliniumbromide |
| first_indexed | 2024-03-05T23:11:47Z |
| format | Article |
| id | oai:generic.eprints.org:27938 |
| institution | Universiti Gadjah Mada |
| last_indexed | 2024-03-13T19:05:17Z |
| publishDate | 2008 |
| publisher | [Yogyakarta] : Universitas Gadjah Mada |
| record_format | dspace |
| spelling | oai:generic.eprints.org:279382014-06-18T00:24:53Z https://repository.ugm.ac.id/27938/ GREEN CHEMISTRYAPPLICATION FOR THE SYNTHESIS OF (1)-N-4'-METHOXYBENZVL-1,1O-PHENANTHROLINIUMBROMIDE Perpustakaan UGM, i-lib Jurnal i-lib UGM ABSTRACT A simple, energy-efficient, and relatively quick synthetic procedure for the synthesis of (1)-N-4'- methoxybenzyJ-1,10-phenanthroliniumbromide, based on green chemistry principles has been carried out. The synthesis was started by solvent-free reduction of p-anisaldehyde with NaBH4to give 4-methoxybenzyl alcohol in 98% yield to be followed by solvent-free treatment of the resulted alcohol with PBr3 to yield 4-methoxybenzyl bromide (86%). Furthennore, the obtained bromide was reacted with 1,10-phenanthrolinein acetone at reflux for 12 h to give the phenanthrolinium salt target in 68%yield. Keywords:green chemistry, p-anisaldehyde,(1)-N-4'-methoxybenzyl-1, 1Q-phenanthroliniumbromide [Yogyakarta] : Universitas Gadjah Mada 2008 Article NonPeerReviewed Perpustakaan UGM, i-lib (2008) GREEN CHEMISTRYAPPLICATION FOR THE SYNTHESIS OF (1)-N-4'-METHOXYBENZVL-1,1O-PHENANTHROLINIUMBROMIDE. Jurnal i-lib UGM. http://i-lib.ugm.ac.id/jurnal/download.php?dataId=11001 |
| spellingShingle | Jurnal i-lib UGM Perpustakaan UGM, i-lib GREEN CHEMISTRYAPPLICATION FOR THE SYNTHESIS OF (1)-N-4'-METHOXYBENZVL-1,1O-PHENANTHROLINIUMBROMIDE |
| title | GREEN CHEMISTRYAPPLICATION FOR THE SYNTHESIS OF (1)-N-4'-METHOXYBENZVL-1,1O-PHENANTHROLINIUMBROMIDE |
| title_full | GREEN CHEMISTRYAPPLICATION FOR THE SYNTHESIS OF (1)-N-4'-METHOXYBENZVL-1,1O-PHENANTHROLINIUMBROMIDE |
| title_fullStr | GREEN CHEMISTRYAPPLICATION FOR THE SYNTHESIS OF (1)-N-4'-METHOXYBENZVL-1,1O-PHENANTHROLINIUMBROMIDE |
| title_full_unstemmed | GREEN CHEMISTRYAPPLICATION FOR THE SYNTHESIS OF (1)-N-4'-METHOXYBENZVL-1,1O-PHENANTHROLINIUMBROMIDE |
| title_short | GREEN CHEMISTRYAPPLICATION FOR THE SYNTHESIS OF (1)-N-4'-METHOXYBENZVL-1,1O-PHENANTHROLINIUMBROMIDE |
| title_sort | green chemistryapplication for the synthesis of 1 n 4 methoxybenzvl 1 1o phenanthroliniumbromide |
| topic | Jurnal i-lib UGM |
| work_keys_str_mv | AT perpustakaanugmilib greenchemistryapplicationforthesynthesisof1n4methoxybenzvl11ophenanthroliniumbromide |