SYNTHESISOF POLYEUGENYLOXYACETICACID AS A CARRIER TO SEPARATE HEAVY METAL ION Fe (III), Cr(III), Cu(II), Ni(II), Co(II), AND Pb(lI) THAT USINGSOLVENT EXTRACTIONMETHOD Sintesis Polieugenil Oksiasetat sebagai Pengemban ...
ABSTRACT Polyeugenyl oxyacetic acid has been synthesized from polyeugenol and chloroacetic acid and applied to separate metal Fe(/II), Cr(lll), Cu(II), Ni(II), Co(ll), and Pb(lI) uslng solvent extraction method.pH effect, polyeugenyl oxyacetic acid ion ca"ier concentration, extraction time, and...
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| Format: | Article |
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[Yogyakarta] : Universitas Gadjah Mada
2009
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| _version_ | 1797019815132528640 |
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| author | Perpustakaan UGM, i-lib |
| author_facet | Perpustakaan UGM, i-lib |
| author_sort | Perpustakaan UGM, i-lib |
| collection | UGM |
| description | ABSTRACT
Polyeugenyl oxyacetic acid has been synthesized from polyeugenol and chloroacetic acid and applied to
separate metal Fe(/II), Cr(lll), Cu(II), Ni(II), Co(ll), and Pb(lI) uslng solvent extraction method.pH effect, polyeugenyl
oxyacetic acid ion ca"ier concentration, extraction time, and metal concentration optimized to gain optimum
condition.
The result of experiment indicated that polyeugenyl oxyacetic acid resulted the yellowed brown synthesis with
melting point 125°C and yield 68.9%. The Characterizationof spectroscopy IR attributed by absorption to the area
1735,8 em -1as carbonyl extend vibration (C=O) acid and 1H-NMRthat was attributed by chemical shift at 4.6 ppm
as carboxy proton (CHz-C=O).The metal separation optimum condition gained pH 3-6 for ion Fe(/II), pH 5 for ion
Cr(lll), Ni(II), and Co(lI) and pH 6 for ion Cu(II), and Pb(II). Optimum carrier concentraction5 mL, 10mL, and 15mL
for ion Fe(/II), and ion Cr(lll), Ni(II), Co(II),and ion Cu(II), Pb(lI) respectively.Extraction time 2.5 h for ion Fe(/II), 20 h
for ion Cr(II'lt and 36 h for ion Cu(II), Pb(II), Ni(II), and Co(II). Metal concentration that would extracted correctly
(0.75-5 x 10 M) for ion Fe(/II), (0.75-2.5x 1cr M) for ion Cr(/II), Ni(II), and Co(lI) and (0.75-1x 10'"M) for ion Cu(lI)
and Pb(II). The best polyeugenil oxyacetic acid response to separate ion Fe(/II) than other ions with selectivity order
Fe(/II» Cr(lll» Cu(II» Pb(II» Ni(II» Co(II).
Keywords: polyeugenil oxyacetic acid, pH, extraction time, metal concentraction,solvent extraction |
| first_indexed | 2024-03-13T19:05:29Z |
| format | Article |
| id | oai:generic.eprints.org:28003 |
| institution | Universiti Gadjah Mada |
| last_indexed | 2024-03-13T19:05:29Z |
| publishDate | 2009 |
| publisher | [Yogyakarta] : Universitas Gadjah Mada |
| record_format | dspace |
| spelling | oai:generic.eprints.org:280032014-06-18T00:24:41Z https://repository.ugm.ac.id/28003/ SYNTHESISOF POLYEUGENYLOXYACETICACID AS A CARRIER TO SEPARATE HEAVY METAL ION Fe (III), Cr(III), Cu(II), Ni(II), Co(II), AND Pb(lI) THAT USINGSOLVENT EXTRACTIONMETHOD Sintesis Polieugenil Oksiasetat sebagai Pengemban ... Perpustakaan UGM, i-lib Jurnal i-lib UGM ABSTRACT Polyeugenyl oxyacetic acid has been synthesized from polyeugenol and chloroacetic acid and applied to separate metal Fe(/II), Cr(lll), Cu(II), Ni(II), Co(ll), and Pb(lI) uslng solvent extraction method.pH effect, polyeugenyl oxyacetic acid ion ca"ier concentration, extraction time, and metal concentration optimized to gain optimum condition. The result of experiment indicated that polyeugenyl oxyacetic acid resulted the yellowed brown synthesis with melting point 125°C and yield 68.9%. The Characterizationof spectroscopy IR attributed by absorption to the area 1735,8 em -1as carbonyl extend vibration (C=O) acid and 1H-NMRthat was attributed by chemical shift at 4.6 ppm as carboxy proton (CHz-C=O).The metal separation optimum condition gained pH 3-6 for ion Fe(/II), pH 5 for ion Cr(lll), Ni(II), and Co(lI) and pH 6 for ion Cu(II), and Pb(II). Optimum carrier concentraction5 mL, 10mL, and 15mL for ion Fe(/II), and ion Cr(lll), Ni(II), Co(II),and ion Cu(II), Pb(lI) respectively.Extraction time 2.5 h for ion Fe(/II), 20 h for ion Cr(II'lt and 36 h for ion Cu(II), Pb(II), Ni(II), and Co(II). Metal concentration that would extracted correctly (0.75-5 x 10 M) for ion Fe(/II), (0.75-2.5x 1cr M) for ion Cr(/II), Ni(II), and Co(lI) and (0.75-1x 10'"M) for ion Cu(lI) and Pb(II). The best polyeugenil oxyacetic acid response to separate ion Fe(/II) than other ions with selectivity order Fe(/II» Cr(lll» Cu(II» Pb(II» Ni(II» Co(II). Keywords: polyeugenil oxyacetic acid, pH, extraction time, metal concentraction,solvent extraction [Yogyakarta] : Universitas Gadjah Mada 2009 Article NonPeerReviewed Perpustakaan UGM, i-lib (2009) SYNTHESISOF POLYEUGENYLOXYACETICACID AS A CARRIER TO SEPARATE HEAVY METAL ION Fe (III), Cr(III), Cu(II), Ni(II), Co(II), AND Pb(lI) THAT USINGSOLVENT EXTRACTIONMETHOD Sintesis Polieugenil Oksiasetat sebagai Pengemban ... Jurnal i-lib UGM. http://i-lib.ugm.ac.id/jurnal/download.php?dataId=11066 |
| spellingShingle | Jurnal i-lib UGM Perpustakaan UGM, i-lib SYNTHESISOF POLYEUGENYLOXYACETICACID AS A CARRIER TO SEPARATE HEAVY METAL ION Fe (III), Cr(III), Cu(II), Ni(II), Co(II), AND Pb(lI) THAT USINGSOLVENT EXTRACTIONMETHOD Sintesis Polieugenil Oksiasetat sebagai Pengemban ... |
| title | SYNTHESISOF POLYEUGENYLOXYACETICACID AS A CARRIER TO SEPARATE HEAVY METAL ION Fe (III), Cr(III), Cu(II), Ni(II), Co(II), AND Pb(lI) THAT USINGSOLVENT EXTRACTIONMETHOD Sintesis Polieugenil Oksiasetat sebagai Pengemban ... |
| title_full | SYNTHESISOF POLYEUGENYLOXYACETICACID AS A CARRIER TO SEPARATE HEAVY METAL ION Fe (III), Cr(III), Cu(II), Ni(II), Co(II), AND Pb(lI) THAT USINGSOLVENT EXTRACTIONMETHOD Sintesis Polieugenil Oksiasetat sebagai Pengemban ... |
| title_fullStr | SYNTHESISOF POLYEUGENYLOXYACETICACID AS A CARRIER TO SEPARATE HEAVY METAL ION Fe (III), Cr(III), Cu(II), Ni(II), Co(II), AND Pb(lI) THAT USINGSOLVENT EXTRACTIONMETHOD Sintesis Polieugenil Oksiasetat sebagai Pengemban ... |
| title_full_unstemmed | SYNTHESISOF POLYEUGENYLOXYACETICACID AS A CARRIER TO SEPARATE HEAVY METAL ION Fe (III), Cr(III), Cu(II), Ni(II), Co(II), AND Pb(lI) THAT USINGSOLVENT EXTRACTIONMETHOD Sintesis Polieugenil Oksiasetat sebagai Pengemban ... |
| title_short | SYNTHESISOF POLYEUGENYLOXYACETICACID AS A CARRIER TO SEPARATE HEAVY METAL ION Fe (III), Cr(III), Cu(II), Ni(II), Co(II), AND Pb(lI) THAT USINGSOLVENT EXTRACTIONMETHOD Sintesis Polieugenil Oksiasetat sebagai Pengemban ... |
| title_sort | synthesisof polyeugenyloxyaceticacid as a carrier to separate heavy metal ion fe iii cr iii cu ii ni ii co ii and pb li that usingsolvent extractionmethod sintesis polieugenil oksiasetat sebagai pengemban |
| topic | Jurnal i-lib UGM |
| work_keys_str_mv | AT perpustakaanugmilib synthesisofpolyeugenyloxyaceticacidasacarriertoseparateheavymetalionfeiiicriiicuiiniiicoiiandpblithatusingsolventextractionmethodsintesispolieugeniloksiasetatsebagaipengemban |