SYNTHESIS OF POLY -5,7 -DIALL YL-25,26,27,28-TETRAHYDROXYCALlX[4]ARENE
ABSTRACT The synthesis of poly-5,7-diallyl-25,26,27,28-tetrahydroxycalix[4]arenewere performed in experimental series as follows: (1) Cyclotetramerizationof p-t-butylphenol with NaOH and paraformaldehyde to p-butylcalix[4]arene, (2) Debutylation of p-butylcalix[4]arene using AICI3and phenol to tetr...
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| Formato: | Artigo |
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[Yogyakarta] : Universitas Gadjah Mada
2009
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| _version_ | 1826033154512650240 |
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| author | Perpustakaan UGM, i-lib |
| author_facet | Perpustakaan UGM, i-lib |
| author_sort | Perpustakaan UGM, i-lib |
| collection | UGM |
| description | ABSTRACT
The synthesis of poly-5,7-diallyl-25,26,27,28-tetrahydroxycalix[4]arenewere performed in experimental series as follows: (1) Cyclotetramerizationof p-t-butylphenol with NaOH and paraformaldehyde to p-butylcalix[4]arene, (2)
Debutylation of p-butylcalix[4]arene using AICI3and phenol to tetrahydroxycalix[4]arene,(3) Allylation reaction using allylbromide to diallyloxy-dihydroxycalix[4]arene,(4) Claisen rearrangement reaction, (5) Cationic polymerization to
diallylcalix[4]arenesA.ll of the synthesizedproductswere analyzedby meansof IR spectrometerand 1H-NMR
spectrometer. The result of 25,27-diallyloxy-26,28-dihydroxycalix[4]arenesynthesis was white crystals having m.p. 205-207 °C in 80.95% yield. The synthesis of 5,7-diallyl-25,26,27,28-tetrahydroxy-calix[4]arenegave light yellow crystals having m.p. 214-216 °C in 78.67% yield. The polymerization gave poly(5,7-diallyl-25,26,27,28-tetrahydroxycalix[
4]arene)having m.p. 338-340 °C, in 60% yield. Its estimated has a relative molecular weight of 18,738
glmol with the number of unit repetition about 37 monomer units.
Keywords: Diallylation, polymerization, Poly-5, 7-diallyl-25, 26, 27,28-tetrahydroxycalix[4]arene |
| first_indexed | 2024-03-05T23:11:59Z |
| format | Article |
| id | oai:generic.eprints.org:28069 |
| institution | Universiti Gadjah Mada |
| last_indexed | 2024-03-05T23:11:59Z |
| publishDate | 2009 |
| publisher | [Yogyakarta] : Universitas Gadjah Mada |
| record_format | dspace |
| spelling | oai:generic.eprints.org:280692014-06-18T00:24:41Z https://repository.ugm.ac.id/28069/ SYNTHESIS OF POLY -5,7 -DIALL YL-25,26,27,28-TETRAHYDROXYCALlX[4]ARENE Perpustakaan UGM, i-lib Jurnal i-lib UGM ABSTRACT The synthesis of poly-5,7-diallyl-25,26,27,28-tetrahydroxycalix[4]arenewere performed in experimental series as follows: (1) Cyclotetramerizationof p-t-butylphenol with NaOH and paraformaldehyde to p-butylcalix[4]arene, (2) Debutylation of p-butylcalix[4]arene using AICI3and phenol to tetrahydroxycalix[4]arene,(3) Allylation reaction using allylbromide to diallyloxy-dihydroxycalix[4]arene,(4) Claisen rearrangement reaction, (5) Cationic polymerization to diallylcalix[4]arenesA.ll of the synthesizedproductswere analyzedby meansof IR spectrometerand 1H-NMR spectrometer. The result of 25,27-diallyloxy-26,28-dihydroxycalix[4]arenesynthesis was white crystals having m.p. 205-207 °C in 80.95% yield. The synthesis of 5,7-diallyl-25,26,27,28-tetrahydroxy-calix[4]arenegave light yellow crystals having m.p. 214-216 °C in 78.67% yield. The polymerization gave poly(5,7-diallyl-25,26,27,28-tetrahydroxycalix[ 4]arene)having m.p. 338-340 °C, in 60% yield. Its estimated has a relative molecular weight of 18,738 glmol with the number of unit repetition about 37 monomer units. Keywords: Diallylation, polymerization, Poly-5, 7-diallyl-25, 26, 27,28-tetrahydroxycalix[4]arene [Yogyakarta] : Universitas Gadjah Mada 2009 Article NonPeerReviewed Perpustakaan UGM, i-lib (2009) SYNTHESIS OF POLY -5,7 -DIALL YL-25,26,27,28-TETRAHYDROXYCALlX[4]ARENE. Jurnal i-lib UGM. http://i-lib.ugm.ac.id/jurnal/download.php?dataId=11132 |
| spellingShingle | Jurnal i-lib UGM Perpustakaan UGM, i-lib SYNTHESIS OF POLY -5,7 -DIALL YL-25,26,27,28-TETRAHYDROXYCALlX[4]ARENE |
| title | SYNTHESIS OF POLY -5,7 -DIALL YL-25,26,27,28-TETRAHYDROXYCALlX[4]ARENE |
| title_full | SYNTHESIS OF POLY -5,7 -DIALL YL-25,26,27,28-TETRAHYDROXYCALlX[4]ARENE |
| title_fullStr | SYNTHESIS OF POLY -5,7 -DIALL YL-25,26,27,28-TETRAHYDROXYCALlX[4]ARENE |
| title_full_unstemmed | SYNTHESIS OF POLY -5,7 -DIALL YL-25,26,27,28-TETRAHYDROXYCALlX[4]ARENE |
| title_short | SYNTHESIS OF POLY -5,7 -DIALL YL-25,26,27,28-TETRAHYDROXYCALlX[4]ARENE |
| title_sort | synthesis of poly 5 7 diall yl 25 26 27 28 tetrahydroxycallx 4 arene |
| topic | Jurnal i-lib UGM |
| work_keys_str_mv | AT perpustakaanugmilib synthesisofpoly57diallyl25262728tetrahydroxycallx4arene |