Alignment of carbon nanotubes under the influences of nematic liquid crystals and electric fields - an analytical study

Carbon nanotubes (CNTs) have benefits in various fields, they are disadvantageous due to their tendency to form aggregates and poorly controlled alignment of the CNT molecules (characterized by order parameters). These deficiencies can be overcome by dispersing the CNTs in nematic liquid crystal (LC...

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Main Authors: Sumandra, Setia Budi, Mahendra, Bhisma, Nugroho, Fahrudin, Yusuf, Yusril
Format: Article
Published: 2022
Subjects:
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author Sumandra, Setia Budi
Mahendra, Bhisma
Nugroho, Fahrudin
Yusuf, Yusril
author_facet Sumandra, Setia Budi
Mahendra, Bhisma
Nugroho, Fahrudin
Yusuf, Yusril
author_sort Sumandra, Setia Budi
collection UGM
description Carbon nanotubes (CNTs) have benefits in various fields, they are disadvantageous due to their tendency to form aggregates and poorly controlled alignment of the CNT molecules (characterized by order parameters). These deficiencies can be overcome by dispersing the CNTs in nematic liquid crystal (LC) and placing the mixture under the influence of an electric field. In this study, Doi and Landau–de Gennes free energy density equations are used to analytically confirm that an electric field increases the order parameters of CNTs and LCs in a dispersion mixture. The anchoring strength of the nematic LC is also found to affect the order parameters of the CNTs and LC. Further, increasing the length-to-diameter ratio of the CNTs increases their alignment without affecting the LC alignment. These findings indicate that CNT molecular alignment can be controlled by adjusting the CNT length-to-diameter ratio, anchoring the LCs, and adjusting the electric field strength.
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spelling oai:generic.eprints.org:2828122023-11-16T08:29:38Z https://repository.ugm.ac.id/282812/ Alignment of carbon nanotubes under the influences of nematic liquid crystals and electric fields - an analytical study Sumandra, Setia Budi Mahendra, Bhisma Nugroho, Fahrudin Yusuf, Yusril Analytical Chemistry not elsewhere classified Chemical Sciences not elsewhere classified Analytical Chemistry Carbon nanotubes (CNTs) have benefits in various fields, they are disadvantageous due to their tendency to form aggregates and poorly controlled alignment of the CNT molecules (characterized by order parameters). These deficiencies can be overcome by dispersing the CNTs in nematic liquid crystal (LC) and placing the mixture under the influence of an electric field. In this study, Doi and Landau–de Gennes free energy density equations are used to analytically confirm that an electric field increases the order parameters of CNTs and LCs in a dispersion mixture. The anchoring strength of the nematic LC is also found to affect the order parameters of the CNTs and LC. Further, increasing the length-to-diameter ratio of the CNTs increases their alignment without affecting the LC alignment. These findings indicate that CNT molecular alignment can be controlled by adjusting the CNT length-to-diameter ratio, anchoring the LCs, and adjusting the electric field strength. 2022 Article PeerReviewed Sumandra, Setia Budi and Mahendra, Bhisma and Nugroho, Fahrudin and Yusuf, Yusril (2022) Alignment of carbon nanotubes under the influences of nematic liquid crystals and electric fields - an analytical study. Worlld Scientific, 11 (2). https://www.worldscientific.com/doi/abs/10.1142/S2047684121500330 10.1142/S2047684121500330
spellingShingle Analytical Chemistry not elsewhere classified
Chemical Sciences not elsewhere classified
Analytical Chemistry
Sumandra, Setia Budi
Mahendra, Bhisma
Nugroho, Fahrudin
Yusuf, Yusril
Alignment of carbon nanotubes under the influences of nematic liquid crystals and electric fields - an analytical study
title Alignment of carbon nanotubes under the influences of nematic liquid crystals and electric fields - an analytical study
title_full Alignment of carbon nanotubes under the influences of nematic liquid crystals and electric fields - an analytical study
title_fullStr Alignment of carbon nanotubes under the influences of nematic liquid crystals and electric fields - an analytical study
title_full_unstemmed Alignment of carbon nanotubes under the influences of nematic liquid crystals and electric fields - an analytical study
title_short Alignment of carbon nanotubes under the influences of nematic liquid crystals and electric fields - an analytical study
title_sort alignment of carbon nanotubes under the influences of nematic liquid crystals and electric fields an analytical study
topic Analytical Chemistry not elsewhere classified
Chemical Sciences not elsewhere classified
Analytical Chemistry
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AT mahendrabhisma alignmentofcarbonnanotubesundertheinfluencesofnematicliquidcrystalsandelectricfieldsananalyticalstudy
AT nugrohofahrudin alignmentofcarbonnanotubesundertheinfluencesofnematicliquidcrystalsandelectricfieldsananalyticalstudy
AT yusufyusril alignmentofcarbonnanotubesundertheinfluencesofnematicliquidcrystalsandelectricfieldsananalyticalstudy