Ciprofloxacin Removal from Simulated Wastewater Through a Combined Process of Adsorption and Oxidation Processes Using Fe/C Adsorbent
This paper presents a novel approach to remove ciprofloxacin from an aqueous solution using Fe3O4/C material by adsorption and then followed by a degradation process using several advanced oxidation technologies, i.e., heterogeneous Fenton and catalytic ozonation. Porous carbon material was synthesi...
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Springer Science and Business Media Deutschland GmbH
2022
|
| Subjects: | |
| Online Access: | https://repository.ugm.ac.id/283294/1/Ciprofloxacin-Removal-from-Simulated-Wastewater-Through-a-Combined-Process-of-Adsorption-and-Oxidation-Processes-Using-FeC-AdsorbentWater-Air-and-Soil-Pollution.pdf |
| _version_ | 1797037670171410432 |
|---|---|
| author | Mutia, Aulia Septian Ariyanto, Teguh Prasetyo, Imam |
| author_facet | Mutia, Aulia Septian Ariyanto, Teguh Prasetyo, Imam |
| author_sort | Mutia, Aulia Septian |
| collection | UGM |
| description | This paper presents a novel approach to remove ciprofloxacin from an aqueous solution using Fe3O4/C material by adsorption and then followed by a degradation process using several advanced oxidation technologies, i.e., heterogeneous Fenton and catalytic ozonation. Porous carbon material was synthesized through several stages, i.e., polymerization of resorcinol-formaldehyde and carbonization (800 °C). The properties of porous carbon (blank carbon and Fe/C) were characterized by N2-sorption analyzer, SEM-EDX, XRD, and TGA. The adsorption isotherm data were well described by the Langmuir isotherm model with ciprofloxacin uptake up to 208.31 mg g-1 and 189.38 mg g-1 at 30°C by Fe/C and blank carbon material, respectively. The maximum uptake was influenced by adsorption temperature and mesopore volume of material. After adsorbing the ciprofloxacin, the Fe/C material was contacted with H2O2 and ozone to produce hydroxyl radicals (OH*). The result showed that ciprofloxacin was degraded about 99.7% within 120 min at 30°C through heterogeneous Fenton oxidation. The degradation performance for the other two oxidation processes: catalytic ozonation and combined ozonation-Fenton (O3/H2O2), has been explored as well. The process using O3/H2O2 could degrade ciprofloxacin quickly. In addition, Fe/C material could be reused during cyclability test without significantly reducing the catalytic activity. |
| first_indexed | 2024-03-14T00:07:28Z |
| format | Article |
| id | oai:generic.eprints.org:283294 |
| institution | Universiti Gadjah Mada |
| language | English |
| last_indexed | 2024-03-14T00:07:28Z |
| publishDate | 2022 |
| publisher | Springer Science and Business Media Deutschland GmbH |
| record_format | dspace |
| spelling | oai:generic.eprints.org:2832942023-11-20T04:13:17Z https://repository.ugm.ac.id/283294/ Ciprofloxacin Removal from Simulated Wastewater Through a Combined Process of Adsorption and Oxidation Processes Using Fe/C Adsorbent Mutia, Aulia Septian Ariyanto, Teguh Prasetyo, Imam Chemical Engineering Engineering This paper presents a novel approach to remove ciprofloxacin from an aqueous solution using Fe3O4/C material by adsorption and then followed by a degradation process using several advanced oxidation technologies, i.e., heterogeneous Fenton and catalytic ozonation. Porous carbon material was synthesized through several stages, i.e., polymerization of resorcinol-formaldehyde and carbonization (800 °C). The properties of porous carbon (blank carbon and Fe/C) were characterized by N2-sorption analyzer, SEM-EDX, XRD, and TGA. The adsorption isotherm data were well described by the Langmuir isotherm model with ciprofloxacin uptake up to 208.31 mg g-1 and 189.38 mg g-1 at 30°C by Fe/C and blank carbon material, respectively. The maximum uptake was influenced by adsorption temperature and mesopore volume of material. After adsorbing the ciprofloxacin, the Fe/C material was contacted with H2O2 and ozone to produce hydroxyl radicals (OH*). The result showed that ciprofloxacin was degraded about 99.7% within 120 min at 30°C through heterogeneous Fenton oxidation. The degradation performance for the other two oxidation processes: catalytic ozonation and combined ozonation-Fenton (O3/H2O2), has been explored as well. The process using O3/H2O2 could degrade ciprofloxacin quickly. In addition, Fe/C material could be reused during cyclability test without significantly reducing the catalytic activity. Springer Science and Business Media Deutschland GmbH 2022-04-14 Article PeerReviewed application/pdf en https://repository.ugm.ac.id/283294/1/Ciprofloxacin-Removal-from-Simulated-Wastewater-Through-a-Combined-Process-of-Adsorption-and-Oxidation-Processes-Using-FeC-AdsorbentWater-Air-and-Soil-Pollution.pdf Mutia, Aulia Septian and Ariyanto, Teguh and Prasetyo, Imam (2022) Ciprofloxacin Removal from Simulated Wastewater Through a Combined Process of Adsorption and Oxidation Processes Using Fe/C Adsorbent. Water, Air, and Soil Pollution, 233 (4). pp. 1-13. ISSN 00496979 https://link.springer.com/article/10.1007/s11270-022-05618-5 https://doi.org/10.1007/s11270-022-05618-5 |
| spellingShingle | Chemical Engineering Engineering Mutia, Aulia Septian Ariyanto, Teguh Prasetyo, Imam Ciprofloxacin Removal from Simulated Wastewater Through a Combined Process of Adsorption and Oxidation Processes Using Fe/C Adsorbent |
| title | Ciprofloxacin Removal from Simulated Wastewater Through a Combined Process of Adsorption and Oxidation Processes Using Fe/C Adsorbent |
| title_full | Ciprofloxacin Removal from Simulated Wastewater Through a Combined Process of Adsorption and Oxidation Processes Using Fe/C Adsorbent |
| title_fullStr | Ciprofloxacin Removal from Simulated Wastewater Through a Combined Process of Adsorption and Oxidation Processes Using Fe/C Adsorbent |
| title_full_unstemmed | Ciprofloxacin Removal from Simulated Wastewater Through a Combined Process of Adsorption and Oxidation Processes Using Fe/C Adsorbent |
| title_short | Ciprofloxacin Removal from Simulated Wastewater Through a Combined Process of Adsorption and Oxidation Processes Using Fe/C Adsorbent |
| title_sort | ciprofloxacin removal from simulated wastewater through a combined process of adsorption and oxidation processes using fe c adsorbent |
| topic | Chemical Engineering Engineering |
| url | https://repository.ugm.ac.id/283294/1/Ciprofloxacin-Removal-from-Simulated-Wastewater-Through-a-Combined-Process-of-Adsorption-and-Oxidation-Processes-Using-FeC-AdsorbentWater-Air-and-Soil-Pollution.pdf |
| work_keys_str_mv | AT mutiaauliaseptian ciprofloxacinremovalfromsimulatedwastewaterthroughacombinedprocessofadsorptionandoxidationprocessesusingfecadsorbent AT ariyantoteguh ciprofloxacinremovalfromsimulatedwastewaterthroughacombinedprocessofadsorptionandoxidationprocessesusingfecadsorbent AT prasetyoimam ciprofloxacinremovalfromsimulatedwastewaterthroughacombinedprocessofadsorptionandoxidationprocessesusingfecadsorbent |