Effective production of biofuel from used cooking oil over Ni–Pd loaded on amine-functionalized Lapindo Mud catalyst
In the present work, Lapindo Mud (LL) as natural-based catalyst support material without any prior chemical extraction obtained from Sidoarjo, East Java comprising SiO2 (45.49%), Al2O3 (13.82%), and Fe2O3 (21.63%) was impregnated with the combination of Ni and/or Pd metal catalyst (i.e. LL, Ni/LL, P...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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Springer Science and Business Media B.V.
2022
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| Online Access: | https://repository.ugm.ac.id/284396/1/Trisunaryanti_MIPA.pdf |
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| author | Trisunaryanti, Wega Alethiana, Afra Falah, Iip Izul Fatmawati, Dyah Ayu |
| author_facet | Trisunaryanti, Wega Alethiana, Afra Falah, Iip Izul Fatmawati, Dyah Ayu |
| author_sort | Trisunaryanti, Wega |
| collection | UGM |
| description | In the present work, Lapindo Mud (LL) as natural-based catalyst support material without any prior chemical extraction obtained from Sidoarjo, East Java comprising SiO2 (45.49%), Al2O3 (13.82%), and Fe2O3 (21.63%) was impregnated with the combination of Ni and/or Pd metal catalyst (i.e. LL, Ni/LL, Pd/LL, Ni–Pd/LL). The modification of heterogeneous catalyst (catalyst-support material) by the addition of amine-functionalized group from 3-APTMS compound (i.e. NH2/LL, Ni–NH2/LL, Pd-NH2/LL, and Ni–Pd–NH2/LL) to improve catalyst activity and selectivity towards Free Fatty Acid (FFA) in the hydro-treatment process of used cooking oil into biofuel was thoroughly compared. The result found that Ni–Pd–NH2/LL catalyst was able to generate the higher conversion of liquid product and to decrease the generation of FFA from 10.1 to 3.2% compared to the un-grafted Ni–Pd/LL catalyst. The study showed that the optimum temperature to produce hydrocarbons in hydro-treatment process using Ni–Pd–NH2/LL catalyst was at 550 °C with 1/100 catalyst-to-feed weight ratio. |
| first_indexed | 2024-03-14T00:10:12Z |
| format | Article |
| id | oai:generic.eprints.org:284396 |
| institution | Universiti Gadjah Mada |
| language | English |
| last_indexed | 2024-03-14T00:10:12Z |
| publishDate | 2022 |
| publisher | Springer Science and Business Media B.V. |
| record_format | dspace |
| spelling | oai:generic.eprints.org:2843962023-12-19T04:19:22Z https://repository.ugm.ac.id/284396/ Effective production of biofuel from used cooking oil over Ni–Pd loaded on amine-functionalized Lapindo Mud catalyst Trisunaryanti, Wega Alethiana, Afra Falah, Iip Izul Fatmawati, Dyah Ayu Chemical Science Mathematics and Applied Sciences In the present work, Lapindo Mud (LL) as natural-based catalyst support material without any prior chemical extraction obtained from Sidoarjo, East Java comprising SiO2 (45.49%), Al2O3 (13.82%), and Fe2O3 (21.63%) was impregnated with the combination of Ni and/or Pd metal catalyst (i.e. LL, Ni/LL, Pd/LL, Ni–Pd/LL). The modification of heterogeneous catalyst (catalyst-support material) by the addition of amine-functionalized group from 3-APTMS compound (i.e. NH2/LL, Ni–NH2/LL, Pd-NH2/LL, and Ni–Pd–NH2/LL) to improve catalyst activity and selectivity towards Free Fatty Acid (FFA) in the hydro-treatment process of used cooking oil into biofuel was thoroughly compared. The result found that Ni–Pd–NH2/LL catalyst was able to generate the higher conversion of liquid product and to decrease the generation of FFA from 10.1 to 3.2% compared to the un-grafted Ni–Pd/LL catalyst. The study showed that the optimum temperature to produce hydrocarbons in hydro-treatment process using Ni–Pd–NH2/LL catalyst was at 550 °C with 1/100 catalyst-to-feed weight ratio. Springer Science and Business Media B.V. 2022-03-01 Article PeerReviewed application/pdf en https://repository.ugm.ac.id/284396/1/Trisunaryanti_MIPA.pdf Trisunaryanti, Wega and Alethiana, Afra and Falah, Iip Izul and Fatmawati, Dyah Ayu (2022) Effective production of biofuel from used cooking oil over Ni–Pd loaded on amine-functionalized Lapindo Mud catalyst. Reaction Kinetics, Mechanisms and Catalysis, 135 (2). pp. 951-970. ISSN 18785190 https://link.springer.com/article/10.1007/s11144-022-02191-0 https://doi.org/10.1007/s11144-022-02191-0 |
| spellingShingle | Chemical Science Mathematics and Applied Sciences Trisunaryanti, Wega Alethiana, Afra Falah, Iip Izul Fatmawati, Dyah Ayu Effective production of biofuel from used cooking oil over Ni–Pd loaded on amine-functionalized Lapindo Mud catalyst |
| title | Effective production of biofuel from used cooking oil over Ni–Pd loaded on amine-functionalized Lapindo Mud catalyst |
| title_full | Effective production of biofuel from used cooking oil over Ni–Pd loaded on amine-functionalized Lapindo Mud catalyst |
| title_fullStr | Effective production of biofuel from used cooking oil over Ni–Pd loaded on amine-functionalized Lapindo Mud catalyst |
| title_full_unstemmed | Effective production of biofuel from used cooking oil over Ni–Pd loaded on amine-functionalized Lapindo Mud catalyst |
| title_short | Effective production of biofuel from used cooking oil over Ni–Pd loaded on amine-functionalized Lapindo Mud catalyst |
| title_sort | effective production of biofuel from used cooking oil over ni pd loaded on amine functionalized lapindo mud catalyst |
| topic | Chemical Science Mathematics and Applied Sciences |
| url | https://repository.ugm.ac.id/284396/1/Trisunaryanti_MIPA.pdf |
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