Synthesis of biodiesel from castor oil catalyzed by sodium hydroxide dispersed on bentonite

The present study describes the production of biodiesel from castor plant (Riccinus communis) using heterogeneous base catalyst of NaOH dispersed on bentonite. The catalysts were prepared via wet impregnation by loading a known amount of NaOH on natural bentonite in various NaOH-to-bentonite ratios...

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Main Authors: Utam, Maisari, Setiawan, Pandu, Falah, Iip Izul, Suheryanto, Suheryanto, Shidiq, Muhammad, Wijaya, Karna, Jarin, T., Sumathijones, C., Elkader, Omar H Abd-, Elkader, Moaaz O H Abd-, Chang, Soon Woong, Ravindran, Balasubramani
Format: Other
Language:English
Published: Sustainable Energy Technologies and Assessments 2022
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Online Access:https://repository.ugm.ac.id/284439/1/Synthesis%20of%20biodiesel%20from....pdf
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author Utam, Maisari
Setiawan, Pandu
Falah, Iip Izul
Suheryanto, Suheryanto
Shidiq, Muhammad
Wijaya, Karna
Jarin, T.
Sumathijones, C.
Elkader, Omar H Abd-
Elkader, Moaaz O H Abd-
Chang, Soon Woong
Ravindran, Balasubramani
author_facet Utam, Maisari
Setiawan, Pandu
Falah, Iip Izul
Suheryanto, Suheryanto
Shidiq, Muhammad
Wijaya, Karna
Jarin, T.
Sumathijones, C.
Elkader, Omar H Abd-
Elkader, Moaaz O H Abd-
Chang, Soon Woong
Ravindran, Balasubramani
author_sort Utam, Maisari
collection UGM
description The present study describes the production of biodiesel from castor plant (Riccinus communis) using heterogeneous base catalyst of NaOH dispersed on bentonite. The catalysts were prepared via wet impregnation by loading a known amount of NaOH on natural bentonite in various NaOH-to-bentonite ratios of 5 %, 10 %, 20 %, and 25 % (w/w). The prepared catalysts were characterized by AAS, FTIR, XRD, GSA, and SEM; and further used in a transesterification reaction at 60 ◦C for 4 h. The liquid yields were analyzed by FTIR and GC–MS, 1 H NMR, and ASTM. The modification of a larger concentration of NaOH led to decreasing the mineral structure of natural bentonite. The homogeneous distribution of NaOH on bentonite influenced the increasing pore size of catalyst compared to natural bentonite. The enhanced physicochemical properties significantly increased the catalytic activity. The transesterification reaction of castor oil into biodiesel over 25 % NaOH/bentonite catalyst showed the highest conversion of 76.94 % biodiesel yield. The obtained biodiesel properties was agreed with the ASTM standard specifications.
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spelling oai:generic.eprints.org:2844392023-12-21T03:17:34Z https://repository.ugm.ac.id/284439/ Synthesis of biodiesel from castor oil catalyzed by sodium hydroxide dispersed on bentonite Utam, Maisari Setiawan, Pandu Falah, Iip Izul Suheryanto, Suheryanto Shidiq, Muhammad Wijaya, Karna Jarin, T. Sumathijones, C. Elkader, Omar H Abd- Elkader, Moaaz O H Abd- Chang, Soon Woong Ravindran, Balasubramani Physical Chemistry The present study describes the production of biodiesel from castor plant (Riccinus communis) using heterogeneous base catalyst of NaOH dispersed on bentonite. The catalysts were prepared via wet impregnation by loading a known amount of NaOH on natural bentonite in various NaOH-to-bentonite ratios of 5 %, 10 %, 20 %, and 25 % (w/w). The prepared catalysts were characterized by AAS, FTIR, XRD, GSA, and SEM; and further used in a transesterification reaction at 60 ◦C for 4 h. The liquid yields were analyzed by FTIR and GC–MS, 1 H NMR, and ASTM. The modification of a larger concentration of NaOH led to decreasing the mineral structure of natural bentonite. The homogeneous distribution of NaOH on bentonite influenced the increasing pore size of catalyst compared to natural bentonite. The enhanced physicochemical properties significantly increased the catalytic activity. The transesterification reaction of castor oil into biodiesel over 25 % NaOH/bentonite catalyst showed the highest conversion of 76.94 % biodiesel yield. The obtained biodiesel properties was agreed with the ASTM standard specifications. Sustainable Energy Technologies and Assessments 2022 Other NonPeerReviewed application/pdf en https://repository.ugm.ac.id/284439/1/Synthesis%20of%20biodiesel%20from....pdf Utam, Maisari and Setiawan, Pandu and Falah, Iip Izul and Suheryanto, Suheryanto and Shidiq, Muhammad and Wijaya, Karna and Jarin, T. and Sumathijones, C. and Elkader, Omar H Abd- and Elkader, Moaaz O H Abd- and Chang, Soon Woong and Ravindran, Balasubramani (2022) Synthesis of biodiesel from castor oil catalyzed by sodium hydroxide dispersed on bentonite. Sustainable Energy Technologies and Assessments. https://www.sciencedirect.com/science/article/pii/S2213138822005768 10.1016/j.seta.2022.102526
spellingShingle Physical Chemistry
Utam, Maisari
Setiawan, Pandu
Falah, Iip Izul
Suheryanto, Suheryanto
Shidiq, Muhammad
Wijaya, Karna
Jarin, T.
Sumathijones, C.
Elkader, Omar H Abd-
Elkader, Moaaz O H Abd-
Chang, Soon Woong
Ravindran, Balasubramani
Synthesis of biodiesel from castor oil catalyzed by sodium hydroxide dispersed on bentonite
title Synthesis of biodiesel from castor oil catalyzed by sodium hydroxide dispersed on bentonite
title_full Synthesis of biodiesel from castor oil catalyzed by sodium hydroxide dispersed on bentonite
title_fullStr Synthesis of biodiesel from castor oil catalyzed by sodium hydroxide dispersed on bentonite
title_full_unstemmed Synthesis of biodiesel from castor oil catalyzed by sodium hydroxide dispersed on bentonite
title_short Synthesis of biodiesel from castor oil catalyzed by sodium hydroxide dispersed on bentonite
title_sort synthesis of biodiesel from castor oil catalyzed by sodium hydroxide dispersed on bentonite
topic Physical Chemistry
url https://repository.ugm.ac.id/284439/1/Synthesis%20of%20biodiesel%20from....pdf
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