Mesoporous Silica from Parangtritis Beach Sand Templated by CTAB as a Support of Mo Metal as a Catalyst for Hydrocracking of Waste Palm Cooking Oil into Biofuel
In this study, natural source Parangtritis beach sand was extracted into mesoporous silica (MS). Synthesis of mesoporous silica (MS) was carried out at sodium silicate: CTAB ratio of 1:0.5 (w/w). Monometallic catalyst was used to improve the performance of the catalyst. The monometallic used was M...
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| Format: | Other |
| Language: | English |
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Waste and Biomass Valorization
2022
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| Online Access: | https://repository.ugm.ac.id/284578/1/70.Mesoporous-Silica-from-Parangtritis-Beach-Sand-Templated-by-CTAB-as-a-Support-of-Mo-Metal-as-a-Catalyst-for-Hydrocracking-of-Waste-Palm-Cooking-Oil-into-BiofuelWaste-and-Biomass-Valorization.pdf |
| _version_ | 1797037875330547712 |
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| author | Alisha, Gesha Desy Trisunaryanti, Wega Syoufian, Akhmad |
| author_facet | Alisha, Gesha Desy Trisunaryanti, Wega Syoufian, Akhmad |
| author_sort | Alisha, Gesha Desy |
| collection | UGM |
| description | In this study, natural source Parangtritis beach sand was extracted into mesoporous silica (MS). Synthesis of mesoporous
silica (MS) was carried out at sodium silicate: CTAB ratio of 1:0.5 (w/w). Monometallic catalyst was used to improve the
performance of the catalyst. The monometallic used was Mo metal, which was synthesized using the wet impregnation
method. Catalysts were characterized using FTIR, XRD, Surface Area Analyzer (SAA), SEM–EDX, and TEM. MS has pore
diameters and surface area of 2.62 nm and 897.3 m2/
g, respectively. Mo/MS has pore diameters, surface area, and Mo metal
concentration of 2.46 nm, 593 m2/
g, and 4.75%, respectively. Catalytic activity and selectivity were evaluated in hydrocracking
of waste palm cooking oil at 500, 550, and 600 °C, and catalyst: waste palm cooking oil ratio of 1:100, 1:200, and 1:300.
The best catalyst will be tested for reusability 3 times through the hydrocracking process. Mo/MS produces better liquid
products and hydrocarbon compounds than MS. The results of the conversion of liquid products analyzed using GCMS. The
yield of liquid products obtained in the hydrocracking of waste palm cooking oil using Mo/MS with the optimum temperature
and the weight ratio of catalyst: feed at 550 °C and 1: 300 was 66.99 wt.% with consists of hydrocarbon compound as 62.79
wt.%. The yield of liquid products obtained in the hydrocracking waste palm cooking oil using the used Mo/MS catalyst in
the last run was 80.26 wt.% with consist of hydrocarbon compound as 74.13 wt.%. |
| first_indexed | 2024-03-14T00:10:45Z |
| format | Other |
| id | oai:generic.eprints.org:284578 |
| institution | Universiti Gadjah Mada |
| language | English |
| last_indexed | 2024-03-14T00:10:45Z |
| publishDate | 2022 |
| publisher | Waste and Biomass Valorization |
| record_format | dspace |
| spelling | oai:generic.eprints.org:2845782024-01-02T07:19:58Z https://repository.ugm.ac.id/284578/ Mesoporous Silica from Parangtritis Beach Sand Templated by CTAB as a Support of Mo Metal as a Catalyst for Hydrocracking of Waste Palm Cooking Oil into Biofuel Alisha, Gesha Desy Trisunaryanti, Wega Syoufian, Akhmad Chemical Science In this study, natural source Parangtritis beach sand was extracted into mesoporous silica (MS). Synthesis of mesoporous silica (MS) was carried out at sodium silicate: CTAB ratio of 1:0.5 (w/w). Monometallic catalyst was used to improve the performance of the catalyst. The monometallic used was Mo metal, which was synthesized using the wet impregnation method. Catalysts were characterized using FTIR, XRD, Surface Area Analyzer (SAA), SEM–EDX, and TEM. MS has pore diameters and surface area of 2.62 nm and 897.3 m2/ g, respectively. Mo/MS has pore diameters, surface area, and Mo metal concentration of 2.46 nm, 593 m2/ g, and 4.75%, respectively. Catalytic activity and selectivity were evaluated in hydrocracking of waste palm cooking oil at 500, 550, and 600 °C, and catalyst: waste palm cooking oil ratio of 1:100, 1:200, and 1:300. The best catalyst will be tested for reusability 3 times through the hydrocracking process. Mo/MS produces better liquid products and hydrocarbon compounds than MS. The results of the conversion of liquid products analyzed using GCMS. The yield of liquid products obtained in the hydrocracking of waste palm cooking oil using Mo/MS with the optimum temperature and the weight ratio of catalyst: feed at 550 °C and 1: 300 was 66.99 wt.% with consists of hydrocarbon compound as 62.79 wt.%. The yield of liquid products obtained in the hydrocracking waste palm cooking oil using the used Mo/MS catalyst in the last run was 80.26 wt.% with consist of hydrocarbon compound as 74.13 wt.%. Waste and Biomass Valorization 2022 Other NonPeerReviewed application/pdf en https://repository.ugm.ac.id/284578/1/70.Mesoporous-Silica-from-Parangtritis-Beach-Sand-Templated-by-CTAB-as-a-Support-of-Mo-Metal-as-a-Catalyst-for-Hydrocracking-of-Waste-Palm-Cooking-Oil-into-BiofuelWaste-and-Biomass-Valorization.pdf Alisha, Gesha Desy and Trisunaryanti, Wega and Syoufian, Akhmad (2022) Mesoporous Silica from Parangtritis Beach Sand Templated by CTAB as a Support of Mo Metal as a Catalyst for Hydrocracking of Waste Palm Cooking Oil into Biofuel. Waste and Biomass Valorization. https://link.springer.com/article/10.1007/s12649-021-01559-y 10.1007/s12649-021-01559-y |
| spellingShingle | Chemical Science Alisha, Gesha Desy Trisunaryanti, Wega Syoufian, Akhmad Mesoporous Silica from Parangtritis Beach Sand Templated by CTAB as a Support of Mo Metal as a Catalyst for Hydrocracking of Waste Palm Cooking Oil into Biofuel |
| title | Mesoporous Silica from Parangtritis Beach Sand Templated by CTAB
as a Support of Mo Metal as a Catalyst for Hydrocracking of Waste
Palm Cooking Oil into Biofuel |
| title_full | Mesoporous Silica from Parangtritis Beach Sand Templated by CTAB
as a Support of Mo Metal as a Catalyst for Hydrocracking of Waste
Palm Cooking Oil into Biofuel |
| title_fullStr | Mesoporous Silica from Parangtritis Beach Sand Templated by CTAB
as a Support of Mo Metal as a Catalyst for Hydrocracking of Waste
Palm Cooking Oil into Biofuel |
| title_full_unstemmed | Mesoporous Silica from Parangtritis Beach Sand Templated by CTAB
as a Support of Mo Metal as a Catalyst for Hydrocracking of Waste
Palm Cooking Oil into Biofuel |
| title_short | Mesoporous Silica from Parangtritis Beach Sand Templated by CTAB
as a Support of Mo Metal as a Catalyst for Hydrocracking of Waste
Palm Cooking Oil into Biofuel |
| title_sort | mesoporous silica from parangtritis beach sand templated by ctab as a support of mo metal as a catalyst for hydrocracking of waste palm cooking oil into biofuel |
| topic | Chemical Science |
| url | https://repository.ugm.ac.id/284578/1/70.Mesoporous-Silica-from-Parangtritis-Beach-Sand-Templated-by-CTAB-as-a-Support-of-Mo-Metal-as-a-Catalyst-for-Hydrocracking-of-Waste-Palm-Cooking-Oil-into-BiofuelWaste-and-Biomass-Valorization.pdf |
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