Synthesis of Mono-and Diacylglycerol Using High Shear Reactor
This study aimed to obtain the best characteristics of a product containing a mixture of high mono-and diacylglycerol (MDAG) from a palm olein and coconut oil blend through glycerolysis-interesterification using a high shear reactor. The most optimum reaction was performed at a relatively low temper...
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| Format: | Article |
| Language: | English |
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Department of Science and Technology
2023
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| Online Access: | https://repository.ugm.ac.id/285993/1/synthesis_of_monoand_diacylglycerol_using_high_shear_reactor_.pdf |
| _version_ | 1811138993874534400 |
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| author | Rohana, Nanda Legiasa Rabiul Tsani Millati, Ria Yanti, Rini Ardani, Aulia Safrina Hidayat, Chusnul |
| author_facet | Rohana, Nanda Legiasa Rabiul Tsani Millati, Ria Yanti, Rini Ardani, Aulia Safrina Hidayat, Chusnul |
| author_sort | Rohana, Nanda Legiasa Rabiul Tsani |
| collection | UGM |
| description | This study aimed to obtain the best characteristics of a product containing a mixture of high mono-and diacylglycerol (MDAG) from a palm olein and coconut oil blend through glycerolysis-interesterification using a high shear reactor. The most optimum reaction was performed at a relatively low temperature (120 °C), 3 NaOH as a catalyst, a 12 molecular sieve, and an agitating speed of 2000 rpm. The evaluated factors were palm olein: coconut oil ratios (70:30, 60:40, 50:50, 40:60, and 30:70) and oil: glycerol ratios (1:3, 1:4, 1:5, 1:6, and 1:7). The results showed that palm olein: coconut oil ratio had a significant effect on melting point (MP), slip melting point (SMP), hardness, and emulsion capacity and stability, but it did not have a significant effect on MDAG concentration (P > 0.05). Besides, modifying a high-shear reactor with a vacuum pump and molecular sieve caused a decrease in water content in the system, subsequently reducing free fatty acid (FFA) significantly (P < 0.05). The reaction condition at palm olein: coconut oil ratio of 50:50 and oil: glycerol ratio of 1:5 produced the highest MDAG concentration (58.28) with FFA, water content, hardness, SMP, MP, emulsion capacity, and emulsion stability about 6.75, 7.00, 3.93 N, 33.23 °C, 35.57 °C, 62.66, and 61.59, respectively. Thus, glycerolysis-interesterification of palm olein and coconut oil blend in a high shear reactor is a promising alternative to produce a product containing high MDAG with better characteristics at a relatively low temperature. The product can be used for chocolate spread based on its emulsion capacity, stability, and semi-solid hardness. |
| first_indexed | 2024-09-25T03:59:01Z |
| format | Article |
| id | oai:generic.eprints.org:285993 |
| institution | Universiti Gadjah Mada |
| language | English |
| last_indexed | 2024-09-25T03:59:01Z |
| publishDate | 2023 |
| publisher | Department of Science and Technology |
| record_format | dspace |
| spelling | oai:generic.eprints.org:2859932024-05-17T01:35:06Z https://repository.ugm.ac.id/285993/ Synthesis of Mono-and Diacylglycerol Using High Shear Reactor Rohana, Nanda Legiasa Rabiul Tsani Millati, Ria Yanti, Rini Ardani, Aulia Safrina Hidayat, Chusnul Food technology This study aimed to obtain the best characteristics of a product containing a mixture of high mono-and diacylglycerol (MDAG) from a palm olein and coconut oil blend through glycerolysis-interesterification using a high shear reactor. The most optimum reaction was performed at a relatively low temperature (120 °C), 3 NaOH as a catalyst, a 12 molecular sieve, and an agitating speed of 2000 rpm. The evaluated factors were palm olein: coconut oil ratios (70:30, 60:40, 50:50, 40:60, and 30:70) and oil: glycerol ratios (1:3, 1:4, 1:5, 1:6, and 1:7). The results showed that palm olein: coconut oil ratio had a significant effect on melting point (MP), slip melting point (SMP), hardness, and emulsion capacity and stability, but it did not have a significant effect on MDAG concentration (P > 0.05). Besides, modifying a high-shear reactor with a vacuum pump and molecular sieve caused a decrease in water content in the system, subsequently reducing free fatty acid (FFA) significantly (P < 0.05). The reaction condition at palm olein: coconut oil ratio of 50:50 and oil: glycerol ratio of 1:5 produced the highest MDAG concentration (58.28) with FFA, water content, hardness, SMP, MP, emulsion capacity, and emulsion stability about 6.75, 7.00, 3.93 N, 33.23 °C, 35.57 °C, 62.66, and 61.59, respectively. Thus, glycerolysis-interesterification of palm olein and coconut oil blend in a high shear reactor is a promising alternative to produce a product containing high MDAG with better characteristics at a relatively low temperature. The product can be used for chocolate spread based on its emulsion capacity, stability, and semi-solid hardness. Department of Science and Technology 2023-08 Article PeerReviewed application/pdf en https://repository.ugm.ac.id/285993/1/synthesis_of_monoand_diacylglycerol_using_high_shear_reactor_.pdf Rohana, Nanda Legiasa Rabiul Tsani and Millati, Ria and Yanti, Rini and Ardani, Aulia Safrina and Hidayat, Chusnul (2023) Synthesis of Mono-and Diacylglycerol Using High Shear Reactor. Philippine Journal of Science, 152 (4). 1285 -1295. ISSN ISSN 00317683 DOI 10.56899/152.04.02 |
| spellingShingle | Food technology Rohana, Nanda Legiasa Rabiul Tsani Millati, Ria Yanti, Rini Ardani, Aulia Safrina Hidayat, Chusnul Synthesis of Mono-and Diacylglycerol Using High Shear Reactor |
| title | Synthesis of Mono-and Diacylglycerol Using High Shear Reactor |
| title_full | Synthesis of Mono-and Diacylglycerol Using High Shear Reactor |
| title_fullStr | Synthesis of Mono-and Diacylglycerol Using High Shear Reactor |
| title_full_unstemmed | Synthesis of Mono-and Diacylglycerol Using High Shear Reactor |
| title_short | Synthesis of Mono-and Diacylglycerol Using High Shear Reactor |
| title_sort | synthesis of mono and diacylglycerol using high shear reactor |
| topic | Food technology |
| url | https://repository.ugm.ac.id/285993/1/synthesis_of_monoand_diacylglycerol_using_high_shear_reactor_.pdf |
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