ADSORPTION OF Mg(lI) AND Ca(lI) ON DISULFONATO-SILICA HYBRID

Adsorption of Mg(lI) and Ca(lI) on disulfonato-silicahybrid (DSSH) in the aqueous solution has been studied. The hybrid was synthesized by sol-gel process with sodium silicate solution from rice hull ash, chloroprophyltrimethoxysilane (CTS) and 4-amino-5-hydroxy-naphtalene-2, 7-disulfonic acid monos...

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Main Authors: Azmiyawati, Choiril, Nuryono, Nuryono, Narsito, Narsito
Format: Article
Published: [Yogyakarta] : Universitas Gadjah Mada 2012
Subjects:
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author Azmiyawati, Choiril
Nuryono, Nuryono
Narsito, Narsito
author_facet Azmiyawati, Choiril
Nuryono, Nuryono
Narsito, Narsito
author_sort Azmiyawati, Choiril
collection UGM
description Adsorption of Mg(lI) and Ca(lI) on disulfonato-silicahybrid (DSSH) in the aqueous solution has been studied. The hybrid was synthesized by sol-gel process with sodium silicate solution from rice hull ash, chloroprophyltrimethoxysilane (CTS) and 4-amino-5-hydroxy-naphtalene-2, 7-disulfonic acid monosodium salt (ANSNa) as silica source, cross linker and active group, respectively. Sodium silicate solution was reacted with CTS and ANSNa that were added dropwise. Adsorption of magnesium and calcium ions on DSSH was carried out in a batch system. Solution pH significantly affected magnesium and calcium adsorption and the optimum condition was ootained at pH = 6. Thesynthesized DSSH showed a high adsorption capacity of 0.0844 mmol/g and 0.1442 mmol/g for Mg(lI) and Ca(II), respectively. The adsorption isotherm obtained with Langmuir isotherm model gives the negative values of . &#916
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spelling oai:generic.eprints.org:290262016-01-25T01:33:07Z https://repository.ugm.ac.id/29026/ ADSORPTION OF Mg(lI) AND Ca(lI) ON DISULFONATO-SILICA HYBRID Azmiyawati, Choiril Nuryono, Nuryono Narsito, Narsito Analytical Chemistry Adsorption of Mg(lI) and Ca(lI) on disulfonato-silicahybrid (DSSH) in the aqueous solution has been studied. The hybrid was synthesized by sol-gel process with sodium silicate solution from rice hull ash, chloroprophyltrimethoxysilane (CTS) and 4-amino-5-hydroxy-naphtalene-2, 7-disulfonic acid monosodium salt (ANSNa) as silica source, cross linker and active group, respectively. Sodium silicate solution was reacted with CTS and ANSNa that were added dropwise. Adsorption of magnesium and calcium ions on DSSH was carried out in a batch system. Solution pH significantly affected magnesium and calcium adsorption and the optimum condition was ootained at pH = 6. Thesynthesized DSSH showed a high adsorption capacity of 0.0844 mmol/g and 0.1442 mmol/g for Mg(lI) and Ca(II), respectively. The adsorption isotherm obtained with Langmuir isotherm model gives the negative values of . &#916 [Yogyakarta] : Universitas Gadjah Mada 2012-10 Article NonPeerReviewed Azmiyawati, Choiril and Nuryono, Nuryono and Narsito, Narsito (2012) ADSORPTION OF Mg(lI) AND Ca(lI) ON DISULFONATO-SILICA HYBRID. Indonesian Journal of Chemistry, 12 (3). pp. 223-228. http://i-lib.ugm.ac.id/jurnal/download.php?dataId=12089
spellingShingle Analytical Chemistry
Azmiyawati, Choiril
Nuryono, Nuryono
Narsito, Narsito
ADSORPTION OF Mg(lI) AND Ca(lI) ON DISULFONATO-SILICA HYBRID
title ADSORPTION OF Mg(lI) AND Ca(lI) ON DISULFONATO-SILICA HYBRID
title_full ADSORPTION OF Mg(lI) AND Ca(lI) ON DISULFONATO-SILICA HYBRID
title_fullStr ADSORPTION OF Mg(lI) AND Ca(lI) ON DISULFONATO-SILICA HYBRID
title_full_unstemmed ADSORPTION OF Mg(lI) AND Ca(lI) ON DISULFONATO-SILICA HYBRID
title_short ADSORPTION OF Mg(lI) AND Ca(lI) ON DISULFONATO-SILICA HYBRID
title_sort adsorption of mg li and ca li on disulfonato silica hybrid
topic Analytical Chemistry
work_keys_str_mv AT azmiyawatichoiril adsorptionofmgliandcaliondisulfonatosilicahybrid
AT nuryononuryono adsorptionofmgliandcaliondisulfonatosilicahybrid
AT narsitonarsito adsorptionofmgliandcaliondisulfonatosilicahybrid